Light emitting device

ABSTRACT

A light emitting device that emits light of various colors by blending lights emitted by two or more kinds of fluorescent materials which are substantially directly excited by the light emitted by an excitation source having principal emission peak in a range from 250 nm to 500 nm. Each of the fluorescent material is of a direct-transition type.

BACKGROUND OF THE INVENTION

1. Field of the invention

The present invention relates to a light emitting device that uses a light emitting element and fluorescent material, and can be used for such applications as signal light, illumination, display, indicator and other light sources, and particularly to a light emitting device that can emit light of white and other color tones by using fluorescent material that is excited by the light emitted by a light emitting element, which emits in ultraviolet to visible light region, and emits light in the visible light region.

2. Description of the Related Art

Various light emitting diodes (LED) and laser diodes (LD) have been developed as light emitting elements. These light emitting elements are replacing part of electric bulbs and cold cathode ray tubes that are used as light sources for display, back light and indicator, etc. by taking advantage of such features as the capability to run on low voltage, compact construction, light weight, small thickness, long life, high reliability and low power consumption. What deserve attention in this context are LEDs capable of emitting blue or green light with 10 candela or higher luminous intensity that have been recently developed and commercialized by using activation (light emission) layer of quantum well structure made of nitride semiconductor (for example, mixed crystal of InGaN). It has also been made possible to emit light of various colors including white light by combining the light emitted by such LED chips and the light emitted by fluorescent materials that are excited by the light of the LED chip thereby to produce fluorescence (principle of blending light colors).

An example of such devices is a light emitting device that uses a light emitting element which emits blue light and a YAG fluorescent material which is excited by the light emitted by the light emitting element and emits yellow light, so as to generate white light. This device emits white light by blending a transmitted part of the blue light from the light emitting element and yellow light emitted by the YAG fluorescent material that is excited by a part of the blue light from the light emitting element. This light emitting device has advantages of simple structure and the ease of increasing the output power.

There is also a device that emits white light by using a light emitting element which emits ultraviolet ray and fluorescent materials capable of emitting light of RGB (red, green and blue) colors. There is also such a device that emits white light or other colors wherein a fluorescent material which emits blue light when excited by a UV light emitting element and another fluorescent material which is excited by the blue light from the former fluorescent emits yellow light (for example, refer to Patent Document 1). In this case, light color can be adjusted relatively easily since only the light emitted by the fluorescent materials is substantially used. When a light emitting element that emits ultraviolet ray is used, in particular, mass productivity can be improved since color deviation due to wavelength of the light emitted by the semiconductor light emitting element can be accommodated somewhat and the chromaticity can be determined only by the color of light emitted by the fluorescent material, unlike the case of using a light emitting element that emits visible light.

[Patent Document 1]

Japanese Unexamined Patent Publication (Kokai) No. 2003-147351

However, there are demands for further improvement in the color rendering property for the blended light emitted by the light emitting device that combines a blue light emitting element and YAG fluorescent material. There is a problem, in particular, that light emitted by such a device has insufficient red component and a low value of special color rendering index R9 that represents red component. There is also such a problem that, since the device can emit light of only such colors that lie on a line connecting blue and the color of light emitted by YAG material on the chromaticity diagram, it is difficult to obtain light of a desired color by adjusting the amounts of fluorescent materials, namely it is difficult to obtain a multi-color light emitting device.

A light emitting device that employs a light emitting element which emits ultraviolet ray such as that described in Patent Document 1 has low intensity of emitted light at wavelengths around 500 nm, resulting in low color rendering property.

It has also been attempted to improve the color rendering property by using two or more kinds of fluorescent material such as combining a light emitting element which emits ultraviolet ray and fluorescent materials capable of emitting light of RGB (red, green and blue) colors. But these attempts have been facing such a problem that difference in the excitation characteristics among the fluorescent materials results in color deviation and/or variation in the color rendering property. For example, changing the drive current density in the light emitting element causes the plurality of fluorescent materials to change the light emitting characteristic differently, thus resulting in variations in the color of emitted light.

SUMMARY OF THE INVENTION

With the background described above, an object of the present invention is to solve at least one of the problems described above and to provide a light emitting device having excellent light emitting characteristics.

The light emitting device of the present invention contains a light emitting element that emits light with principal emission wavelength in a region ranging from near ultraviolet to blue light (300-490 nm) and fluorescent material, wherein the fluorescent material comprises two or more kinds of fluorescent material each having luminescence center of direct transition type. The light emitting device of the present invention having such a constitution can easily emit light of a desired color with high color rendering property due to the use of two or more kinds of fluorescent material and has, since each of the two or more kinds of fluorescent material has luminescence center of direct transition type, short response time of excitation so that there is no difference in the color of emitted light between DC drive and pulse drive. Also because a fluorescent material of direct transition type has high linearity of light emission intensity with respect to the intensity of the excitation light, proportions of light emission intensity among the plurality of fluorescent materials can be maintained constant so as to prevent color deviation and deterioration of color rendering property from occurring even when the drive current density of the light emitting element is changed.

Thus according to the present invention, such a light emitting device can be provided that does not experience color deviation even when the intensity of light emitted by the light emitting element is changed or the light emission spectrum is altered slightly by a change in the current density supplied to the light emitting element that serves as the excitation light source or the emission spectrum is slightly changed, since the fluorescent materials having luminescence center of direct transition type are used. That the device does not experience color deviation herein means that there occurs no significant change in color tone which can be visibly recognized.

Specifically, according to the present invention, variation in the values of both chromaticity coordinates x and y (JIS Z8110) can be restricted within 0.03 when current density in the light emitting element is changed from 2.0 A/cm² to 50.0 A/cm². Also according to the light emitting device of the present invention, variations in the values of chromaticity coordinates x and y can also be restricted in a range from 0.01 to 0.02, or even below 0.1 by the selection of the florescent materials. Also because the light emitting device of the present invention uses the fluorescent materials of direct transition type that have short response time from excitation to stable light emission and short 1/10 afterglow period (for example, 200 μsec or shorter), stable emission of light is ensured even when the light emitting device is driven with pulsed power and there is no difference in the color of emitted light between DC drive and pulse drive. In other words, the light emitting device of the present invention can emit light of the same color regardless of whether operated by DC drive or pulse drive, or even when the driving condition of the light emitting device is changed from low current to high current. Moreover, light of stable color can be emitted with less changes in light color and color rendering property even when the current density in the light emitting device changes. Since the human eye has high sensitivity to recognize a slight change in the color of light in white region, such features as variations in light color and in the color rendering property are extremely small, that are characteristic of the present invention, are very advantageous when making a device that emits white light.

It goes without saying that the number of different kinds of fluorescent materials used in the light emitting device of the present invention is not limited to 2 or 3, and may be 4 (BGYR: blue, green, yellow and red) or more than 4.

In the light emitting device of the present invention, response time from excitation to stable light emission and 1/10 afterglow period of the fluorescent material is preferably 200 μsec or shorter. Response time is the period of time required for the fluorescent material to release supplied energy as light emission after absorbing the energy and undergoes transition from ground state to excited state. Specifically, the response time is the period from the time immediately after supply of energy to the fluorescent material has begun to the time when the fluorescent material emits light. Afterglow refers to the light emission that ensues after the excitation of luminescence has stopped. The 1/10 afterglow period is the period of time taken for the luminance to decrease to 1/10 after excitation of luminescence has stopped.

The fluorescent material preferably has luminescence center of direct transition type of 4f-4d. The fluorescent material preferably has luminescence center that contains at least Eu, Ce or Yb.

The light emitting device of the present invention may have such a constitution that uses a light emitting element which emits light with principal-emission-peak wavelength in a region ranging from near ultraviolet to visible light region of short wavelengths and three or more kinds of fluorescent material each having peak emission wavelength in the visible light region. Such a constitution enables it to set the color of light emission by blending the light emitted by the three or more kinds of fluorescent material that are of direct transition type and fast excitation response characteristic. Thus the light emitting device can emit light with higher color rendering property while avoiding the variation in the color of emitted light regardless of whether the device is operated by DC drive or pulse drive, and preventing color deviation and deterioration of color rendering property from occurring when the drive current density in the light emitting device changes.

The light emitting element operating in such a wavelength region preferably has a nitride semiconductor that contains Al and Ga in the light emitting layer, which enables it to make a light emitting element having high luminance. The region ranging from near ultraviolet to visible light region of short wavelengths herein means a wavelength region approximately from 300 nm to 420 nm where the light is difficult to recognize by the eye.

According to the present invention, the fluorescent material preferably comprises two or more kinds selected from among the group consisting of alkaline earth metal halogen apatite fluorescent material activated with at least Eu, alkaline earth metal boric acid halide salt fluorescent material, alkaline earth metal aluminate fluorescent material, rare earth aluminate fluorescent material having garnet structure and activated with at least Ce, alkaline earth silicon oxynitride fluorescent material, alkaline earth silicate fluorescent material and alkaline earth silicon nitride fluorescent material activated with at least Eu.

When three or more kinds of fluorescent material are used, white light of high color rendering property can be emitted by using a first fluorescent material that emits light having at least one peak emission wavelength in a region from blue-purple to blue region, a second fluorescent material that emits light having at least one peak emission wavelength in a region from blue-green to yellow-green region, and a third fluorescent material that emits light having at least one peak emission wavelength in a region from yellow to red region. Wavelengths of the blue region (=pure blue region) are from 455 nm to 485 nm, wavelengths of the blue-green region are from 485 nm to 495 nm, wavelengths of the green region are from 495 nm to 548 nm, wavelengths of the yellow-green region are from 548 nm to 573 nm, wavelengths of the yellow region are from 573 nm to 584 nm, wavelengths of the yellow-red region are from 584 nm to 610 nm, and wavelengths of the red region are from 610 nm to 780 nm. Correspondence of these color notations and chromatic coordinates is based on JIS Z8110.

According to the present invention, the first fluorescent material is preferably one or more kind selected from among the group consisting of alkaline earth metal halogen apatite fluorescent material activated with at least Eu, alkaline earth metal boric acid halide salt fluorescent material and alkaline earth metal aluminate fluorescent material.

The second fluorescent material is preferably one or more kind selected from among the group consisting of rare earth aluminate fluorescent material having garnet structure and activated with at least Ce, alkaline earth metal aluminate fluorescent material activated with at least Eu, alkaline earth silicon oxynitride fluorescent material and alkaline earth silicate fluorescent material.

The third fluorescent material is preferably one or more kind selected from among a group of alkaline earth silicon nitride fluorescent material activated with at least Eu.

The light emitting device according to the present invention can emit light of desired color with high color rendering property while preventing color deviation and deterioration of color rendering property from occurring in case the drive current density in the light emitting device changes, also when a light emitting element having principal-emission-peak wavelength in blue region (420-490 nm) is used and a YAG fluorescent material is included in the fluorescent material. Here, the term YAG fluorescent material is used to collectively represent rare earth aluminate fluorescent materials that have garnet structure and are activated with rare earth element. It is preferable that the light emitting element operating in such a wavelength region has a nitride semiconductor that contains In and Ga in a light emission layer thereof.

The light emitting device according to the present invention uses two or more kinds of fluorescent material that are substantially directly excited by the light emitted by an excitation source having principal emission peak in a range from 250 nm to 420 nm, so as to generate light of various colors through blending of the light emitted by the two or more kinds of fluorescent material. The two or more kinds of fluorescent material may include one or more kind of oxynitride-based fluorescent material or nitride-based fluorescent material having crystallinity. With this constitution, a light emitting device having fluorescent material of high light emission efficiency can be provided. Combining two or more kinds of fluorescent material enables it to provide a light emitting device having a broad range of color tones. Moreover, since the excitation light source that is difficult to recognize with the eye is used, a light emitting device that is free of color deviation with no recognizable color deviation of the excitation source can be provided.

The light emitting device according to the present invention may also have such a constitution which uses two or more kinds of fluorescent material that are substantially directly excited by the light emitted by an excitation source having principal emission peak in a range from 420 nm to 500 nm, so as to generate light of various colors through blending of the light emitted by the two or more kinds of fluorescent material, wherein the two or more kinds of fluorescent material may include one or more kind of oxynitride-based fluorescent material having crystallinity. With this constitution, a light emitting device that has less health hazard to human body and high light emission efficiency can be provided. Also combining two or more kinds of fluorescent material enables it to provide a light emitting device having a broad range of color tones.

The light emitting device according to the present invention may also use two or more kinds of direct-excitation fluorescent material (first fluorescent material) that are substantially directly excited by the light emitted from an excitation source having principal emission peak in a range from 250 nm to 420 nm and indirect-excitation fluorescent material (a second fluorescent material) that is excited by a part of light emitted by the two or more kinds of the direct-excitation fluorescent material, so as to generate light of various colors through blending of the light emitted by the two or more kinds of the direct-excitation fluorescent material and light emitted by the indirect-excitation fluorescent material, wherein the two or more kinds of the direct-excitaion fluorescent material may include one or more kind of oxynitride-based fluorescent material or nitride-based fluorescent material having crystallinity. With this constitution, a light emitting device having the direct-excitation fluorescent material of high light emission efficiency and the indirect-excitatoin fluorescent material of high light emission efficiency can be provided. Combining two or more kinds of the direct-excitation fluorescent material and the indirect-excitation fluorescent material enables it to provide a light emitting device having even broader range of color tones.

The two or more kinds of direct-excitation fluorescent material that are directly excited by the light emitted by the excitation source preferably have efficiency of converting the energy received from the excitation source not lower than 60% of the maximum light emission efficiency over the entire wavelength region. This enables it to provide a light emitting device that uses fluorescent material having high excitation efficiency. In case the indirect-exciation fluorescent material is used, intensity of light emitted by the indirect-excitation fluorescent material can be increased with high-efficiency light emission from direct-excitation fluorescent material.

The two or more kinds of fluorescent material that are directly excited by the light emitted by an excitation light source (direct-excitation fluorescent material) may be such that exhibits maximum light emission efficiency in a region from 250 nm to 550 nm when excited by light. This enables it to manufacture the light emitting device that is less harmful to the human body and has high light emission efficiency. By using two or more kinds of fluorescent material that exhibit maximum emission efficiency in the wavelength region of the excitation light source in use, it is made possible to provide the light emitting device having a broad range of color tones and high luminance of emitted light that makes maximum use of the characteristics of the fluorescent material to the highest efficiency possible.

The oxynitride-based fluorescent material having crystallinity preferably contains one or more kinds of group II element selected from among the group consisting of Be, Mg, Ca, Sr, Ba and Zn, one or more kinds of group IV element selected from among the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf and a rare earth element used as an activator R. Use of this novel fluorescent material makes it possible to provide the light emitting device having a broad range of color tones and high luminance of emitted light. When the fluorescent material is excited by means of an excitation source that emits ultraviolet ray, in particular, the light emitting device having high luminance of emitted light can be provided by using a fluorescent material of high luminance having peak emission wavelength in the region from blue-green to yellow.

The nitride-based fluorescent material preferably contains one or more kinds of group II element selected from among the group consisting of Be, Mg, Ca, Sr, Ba and Zn, one or more kinds of group IV element selected from among the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf and a rare earth element used as an activator R. Use of this novel fluorescent material makes it possible to provide the light emitting device having a broader range of color tones and high luminance of emitted light. When the fluorescent material is excited by means of an excitation source that emits ultraviolet ray, in particular, the light emitting device having high luminance of emitted light can be provided by using a fluorescent material of high luminance having emission peak wavelength in the region from yellow-red to red. The light emitting device having high color rendering property can also be provided. Especially because the nitride-based fluorescent material is excited to emit light in a region from yellow-red to red by absorbing light in short wavelength region from ultraviolet to visible light region of short wavelengths, a light emitting device having high color rendering property that has high red component by supplementing red component can also be provided.

The indirect-excitation fluorescent material is preferably aluminate-based fluorescent material that contains rare earth element as the activator R. This enables it to provide a light emitting device having high luminance of emitted light.

The excitation light source is preferably a light emitting element. This enables it to provide a light emitting device that is compact, high in power efficiency and emits light of clear color. The wavelength of light emission from excitation light source may be within the region from ultraviolet to visible light. If the excitation light source has principal emission peak in the ultraviolet region that has low visibility to human eyes, a color deviation caused by the wavelength deviation of light emitting device can be reduced. There is visual sensitivity characteristic in the sensitivity of the human eye to wavelengths of light, which dictates highest sensitivity to light of 555 nm in wavelength, the sensitivity decreasing toward shorter and longer wavelengths. For example, the human eye has lower visual sensitivity to ultraviolet rays used as the excitation source, and the color of light emitted by the light emitting device is substantially determined by the light color emitted by the fluorescent material that is employed. Also because color deviation of light emitted by fluorescent material that emits light in the visible light region is restricted to an extremely small level even when the light emitting element undergoes color deviation due to a change in the supplied current or other cause, thus a light emitting device having less variation in color tone can be provided. Here, “ultraviolet region” means the wavelength range shorter than visible light, specifically the wavelength range shorter than 400 nm. In the ultraviolet region, the wavelength range longer than 250 nm is preferable, and the near ultraviolet region (over 300 nm) is more preferable. The shorter wavelength region in the visible light (under 420 nm) has a similar effect as the above ultraviolet region.

On the other hand, if the excitation light source has principal emission peak in the visible region, the deterioration of phosphors caused by the light emitted from light emitting devices can be reduced. Also, as light emitted from light emitting devices could be utilized to form a desired emission spectrum, less kinds of phosphors are required than the case with ultraviolet light emitting elements. In the visible light region, a light having longer wavelength than 420 nm is preferable because of its high visibility to human eyes. However, as a light having too long wavelength has lower efficiency for exciting phosphors, a light of shorter wavelength than 500 nm is preferable. More preferably, “a blue region” in a broad sense (420-490 nm) is used. In this specicication, terms like “a blue region” or “a blue series region” means the blue region in a broad sense, i.e. 420-490 nm in the absence of any specific limitation.

In the light emitting device of the present invention, emission of white light can be easily achieved when the device has two or more emission peaks in the visible light region and wavelengths of at least two of the two or more emission peaks are in complementary color relation with each other. Here white color includes (purplish) white, (bluish) white, (greenish) white, (yellowish) white, (light) pink, as well as (light) violet, (light) blue violet, (light) blue, (light) blue green, (light) green, (light) yellow green, (light) yellow, (light) yellow red, (orangish) pink, pink and (purplish) pink.

In the light emitting device of the present invention, general color rendering index (Ra) can be set to 80 or higher and can be maintained at 80 or higher even when the drive current density of the light emitting element fluctuates. In the light emitting device of the present invention, general color rendering index (Ra) can be maintained at 80 or higher, for example, when the drive current density of the light emitting element changes from 2.0 A/cm² to 50.0 A/cm². Special color rendering index (R9), in particular, is preferably 50 or higher. This enables it to provide a light emitting device having broad range of color tones, as well as light emitting device of excellent color rendering property. General color rendering index (Ra) is the special color rendering index averaged over eight test color chips No.1 to No.8, specified in CIE and JIS.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a bullet-shaped light emitting device 1 according to the invention.

FIG. 2 is a graph showing the emission output power vs. current density for fluorescent material of direct transition type and fluorescent material of indirect transition type.

FIG. 3 shows normalized excitation spectra of oxynitride-based fluorescent material and nitride-based fluorescent material.

FIG. 4 is a CIE chromaticity diagram showing the range of color tones that can be achieved by using an excitation source which emits ultraviolet ray.

FIG. 5 is a CIE chromaticity diagram showing the range of color tones that can be achieved by using an excitation light source which emits blue light.

FIG. 6 shows normalized excitation spectrum of YAG fluorescent material.

FIG. 7 is a CIE chromaticity diagram showing the range of color tones that can be achieved with a light emitting device having a blue light emitting element and one kind of YAG fluorescent material.

FIG. 8 shows normalized excitation spectrum of oxynitride-based fluorescent material (SrSi₂O₂N₂:Eu).

FIG. 9 shows normalized excitation spectrum of oxynitride-based fluorescent material (CaSi₂O₂N₂:Eu).

FIG. 10 shows normalized excitation spectrum of oxynitride-based fluorescent material (BaSi₂O₂N₂:Eu).

FIG. 11 is a process diagram showing a method of manufacturing oxynitride-based fluorescent material.

FIG. 12 shows normalized excitation spectrum of nitride-based fluorescent material (Sr₂Si₅N₈:Eu).

FIG. 13 shows normalized excitation spectrum of nitride-based fluorescent material (Ca₂Si₅N₈:Eu).

FIG. 14 shows normalized excitation spectrum of nitride-based fluorescent material ((Ca, Sr)₂Si₅N₈:Eu)

FIG. 15 shows the variation of emission spectrum when current supplied to a semiconductor light emitting element is changed.

FIG. 16 shows excitation spectrum of YAG fluorescent material.

FIG. 17 shows excitation spectrum of nitride fluorescent material.

FIG. 18A is a plan view of a light emitting device of seventh embodiment.

FIG. 18B is a sectional view of the light emitting device of seventh embodiment.

FIG. 19 shows a light emitting device of eighth embodiment.

FIG. 20 shows the emission spectra of light emitting devices of examples 1 to 3.

FIG. 21 shows the emission spectra of light emitting devices of examples 11 to 13.

FIG. 22 shows the emission spectrum of a light emitting device of example 29.

FIG. 23 shows the emission spectrum of a light emitting device of example 30.

FIG. 24 shows the emission spectrum of a light emitting device of example 31.

FIG. 25 shows the emission spectrum of a light emitting device of example 32.

FIG. 26 shows the emission spectrum of a light emitting device of example 33.

FIG. 27 shows the emission spectrum of a light emitting device of Comparative Example 12.

DESCRIPTION OF REFERENCE NUMERALS

-   1. Substrate -   2. Semiconductor layer -   3. Electrode -   4. Bump -   10. Light emitting element -   11. Fluorescent material -   12. Coating member -   13. Lead frame -   13 a. Mount lead -   13 b. Inner lead -   11. Electrically conductive wire -   12. Molding member -   101 Light emitting element -   102. Lead electrode -   103. Insulating seal member -   104. Electrically conductive wire -   105. Package -   106. Lid -   107. Window -   108. Fluorescent material -   109. Coating member -   201. Substrate -   202. Base layer -   203. n-type layer -   203 a. Exposed surface -   204. Active layer -   205. p-type carrier confinement layer -   206. 1st p-type layer -   207. Current diffusion layer -   208. p-type contact layer -   209. Light emitting section -   210. p-type electrode -   210 a. Electrode branch -   210 b. p-type pad electrode -   211 a. n-type electrode -   211 b. n-type pad electrode

DESCRIPTION OF THE PREFERRED EMBODIMENTS

Now the fluorescent material and the method for manufacturing the same according to the present invention will be described by way of embodiments and examples. It is understood that the present invention is not limited by these embodiments and examples.

First Embodiment

The light emitting device according to the first embodiment of the present invention uses an excitation light source that emits light in ultraviolet to blue region and two or more kinds, preferably three or more kinds of fluorescent material that are substantially directly excited by the light emitted by the excitation light source and emit light, so as to generate light of various colors through blending of the light emitted by these fluorescent materials. The light emitting device of this embodiment is particularly characterized in that all the fluorescent materials have luminescence center of direct transition type thereby suppressing both the variation in the color of emitted light (color deviation) due to variation in the drive current of the light emitting element and the variation in the color of emitted light due to difference in the drive mode (particularly the difference between DC drive and pulse drive) to extremely low levels. A specific example of the light emitting device will now be described with reference to FIG. 1. FIG. 1 shows the light emitting device according to the present invention. In this specification, relationship between color notations and chromatic coordinates is based on JIS Z8110.

Since the fluorescent material of direct transition type used in the present invention has fast response time (response speed) taken for the intensity of the emitted light to reach the peak after being irradiated with the excitation light, proportions of light emission intensity among the plurality of fluorescent materials is not substantially caused to vary by the difference between DC drive and pulse drive, and therefore the light color does not vary regardless of the drive mode. In case a plurality of fluorescent materials are used containing both fluorescent material of direct transition type and fluorescent material of indirect transition type, in contrast, since the response speed is different between the two types of fluorescent material, proportions of light emission intensity among the plurality of fluorescent materials vary and the light color shows marked difference depending on whether the device is DC-driven or pulse-driven. Also in case a plurality of kinds of fluorescent material are used, even when all fluorescent materials in use are fluorescent materials of indirect transition type, the light color varies depending on the drive mode since the fluorescent material have nonlinear emission intensity characteristic with respect to the excitation light intensity, slow response speed and different response speeds. Also in case a plurality of kinds of fluorescent material are used, when fluorescent material of indirect transition type is included, the light color varies due to difference in pulse width and/or in duty ratio even if driven by the same pulse drive, since the fluorescent materials are different in response speed and have nonlinear emission intensity characteristic.

There is also such a problem that, in case a plurality of kinds of fluorescent material are used, when fluorescent material of indirect transition type is included, color deviation becomes conspicuous due to variations in drive voltage and current, since the fluorescent materials are different in response speed and have nonlinear emission intensity characteristic. However, if all the fluorescent materials are fluorescent materials of direct transition type as in the present invention, the fluorescent materials emit light with intensities that are proportional to the intensity of excitation light and the output power of light emission varies in proportion to the magnitude of supplied current (high linearity), and therefore the balance in the emission intensity between the different fluorescent materials is not lost when the supplied current changes, so that color deviation due to a change in the current supply can be prevented, as will be proved later by examples. As will be seen from the foregoing description, the light emitting device according to the present invention achieves light emission with extremely small variation in color by the use of fluorescent material of direct transition type.

FIG. 2 shows the relation of emission power output to the supplied current density in Ca₂Si₅N₈:Eu that is a fluorescent material of direct transition type, Gd₂O₂S:Eu and La₂O₂S:Eu that are fluorescent material of indirect transition type. As shown in FIG. 2, while emission power output of Ca₂Si₅N₈:Eu that is a fluorescent material of direct transition type increases approximately twofold when the current supply increases twofold, fluorescent material of indirect transition type do not. This shows that a fluorescent material of direct transition type has much higher linearity than a fluorescent material of indirect transition type.

According to the present invention, while the fluorescent materials emit visible light of wavelengths different from that emitted by the light emitting element, excitation source of the fluorescent materials is not limited to the light emitted by the light emitting element. For example, all of the fluorescent materials included may be excited by the light emitted only by the light emitting element or, alternatively, some of the fluorescent materials included may be excited by the light emitting element with the rest of the fluorescent materials excited either only by the light emitted by the excited fluorescent material or by the light from the excited fluorescent material and the light from the light emitting element. In case three kinds of fluorescent materials are included, for example, all of the first to third fluorescent materials may be excited by the light from the light emitting element, or the first fluorescent material may be excited by the light emitting element with the second and third fluorescent materials excited either only by the light from the first fluorescent material or by the light from the first fluorescent material and the light from the light emitting element. Constitution of the present invention works particularly effective and achieves remarkable effect when a plurality of fluorescent materials are excited in two stages.

Constitution of the light emitting device of the first embodiment will now be described in detail.

The light emitting device of the first embodiment comprises, as shown in FIG. 1, the light emitting element 10 that emits ultraviolet ray, the cathode-side lead frame 13 a having the cup for placing the light emitting element 10 therein, the anode-side lead frame 13 b provided apart from the lead frame 13 a, the coating member 12 that includes the fluorescent material 11 provided in the cup of the lead frame 13 a and the transparent molding member 15 that cover the entire device, while a plurality of fluorescent materials of indirect transition type are used for the fluorescent material 11.

The positive electrode 3 of the light emitting element 10 is connected with the electrically conductive wire 14 to the lead frame 13 b, and the negative electrode 4 of the light emitting element 10 is connected with the electrically conductive wire 14 to the lead frame 13 a, while the light emitting element 10, the electrically conductive wire 14, the cup of the lead frame 13 a, and the tip of the lead frame 13 b are covered by the transparent molding member 15.

The light emitting device of the first embodiment constituted as described above is manufactured as follows.

The light emitting element 10 is die-bonded face-up to the cup of the lead frame 13 a by a die bonder.

After die bonding, the lead frame 13 is transferred onto a wire bonder and the negative electrode 3 of the light emitting element is wire-bonded with a gold wire (electrically conductive wire) onto the upper edge of the cup of the lead frame 13 a, and the positive electrode 3 is wire-bonded to the other lead frame 13 b.

Then the assembly is transferred onto a molding apparatus, and the cup of the lead frame 13 a is filled with the fluorescent material 11 and the coating member 12 by a dispenser of the molding apparatus. The fluorescent material 11 and the coating member 12 are mixed uniformly in a predetermined proportions in advance. In the light emitting device of the first embodiment, in particular, color of light emitted by the device is determined mainly by the color of light emitted by the plurality of fluorescent materials.

After pouring in the fluorescent material 11 and the coating member 12, the lead frame 13 is immersed in a mold frame that is filled with the resin to make the molding member 15 in advance, and the mold frame is removed and the resin is cured to harden, so as to make the bullet-shaped light emitting device as shown in FIG. 1.

Now various elements of the first embodiment will be described in more detail.

(Fluorescent Material)

The fluorescent material 11 comprises three or more kinds of fluorescent material of direct transition type having luminescence center of direct transition type such as 4f-5d, that absorb light from the light emitting element 10 or light from the other fluorescent material and emit light having peak emission wavelength in the visible light region. The fluorescent material 11 has response time from excitation to stable light emission and 1/10 afterglow period preferably 700 μsec or shorter, more preferably 500 μsec or shorter, further more preferably 200 μsec or shorter and most preferably 50 μsec or shorter, but may be within 1 msec in the case of direct transition type. The fluorescent material 11 preferably contains Eu or Ce or Yb in the luminescence center.

Those which can be used as the fluorescent material 11 will be described below. In the description that follows, for the sake of convenience, a fluorescent material that emits light mainly in blue to blue-green region will be called the first fluorescent material, a fluorescent material that emits light mainly in green to orange region will be called the second fluorescent material and a fluorescent material that emits light mainly in orange to red region is called the third fluorescent material. However, these regions are not clearly divided since the color of emitted light changes when an activator or other component is added or used as substitute.

<First Fluorescent Material>

In the present invention, the first fluorescent material may be alkaline earth metal halogen apatite fluorescent material activated with at least Eu, alkaline earth metal boric acid halide salt fluorescent material activated with at least Eu, alkaline earth metal aluminate fluorescent material activated with at least Eu, alkaline earth metal silicon oxynitride fluorescent material activated with at least Eu or Ce, or alkaline earth metal silicon nitride fluorescent material, but is not limited to these materials.

More specifically, alkaline earth metal halogen apatite fluorescent material activated with at least Eu may be selected from among fluorescent materials (1) to (4) specified below.

-   (1) Fluorescent material represented by     (M1_(1−a−b)Eu_(a)L1_(b))₁₀(PO₄)₆Q₂     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, L1 represents at least one element selected from     among Mn, Fe, Cr and Sn, and Q represents at least one halogen     element selected from among F, Cl, Br and I, and 0.0001≦a≦0.5 and     0.0001≦b≦0.5. -   (2) Fluorescent material represented by (M1_(1−a)Eu_(a))₁₀(PO₄)₆Q₂     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and Q represents at least one halogen element     selected from among F, Cl, Br and I, and 0.0001≦a≦0.5. -   (3) Fluorescent material represented by     (M1_(1−a−b)Eu_(a)Mn_(b))₁₀(PO₄)₆Q₂     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and Q represents at least one halogen element     selected from among F, Cl, Br and I, and 0.0001≦a≦0.5 and     0.0001≦b≦0.5. -   (4) Fluorescent material represented by     (M2_(1−a−c)Eu_(a)Ba_(c))₁₀(PO₄)₆Q₂     wherein M2 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and Q represents at least one halogen element     selected from among F, Cl, Br and I, and 0.0001≦a≦0.5 and     0.10≦c≦0.98.

Alkaline earth metal boric acid halide salt fluorescent material activated with at least Eu may be selected from among fluorescent materials (5) and (6) specified below.

-   (5) Fluorescent material represented by (M1_(1−a)Eu_(a))₂B₅O₉Q     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and Q represents at least one halogen element     selected from among F, Cl, Br and I, and 0.0001≦a≦0.5. -   (6) Fluorescent material represented by     (M1_(1−a−b)Eu_(a)Mn_(b))₂B₅O₉Q wherein M1 represents at least one     element selected from among Mg, Ca, Ba, Sr and Zn, and Q represents     at least one halogen element selected from among F, Cl, Br and I,     and 0.0001≦a≦0.5 and 0.0001≦b≦0.5.

Alkaline earth metal aluminate fluorescent material activated with at least Eu may be selected from among fluorescent materials (7) and (8) specified below. (7) Fluorescent material represented by M3_(1−a)Eu_(a)MgAl₁₀O₁₇ wherein M3 represents at least one element selected from among Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5.

-   (8) Fluorescent material represented by     M3_(1−a)Eu_(a)Mg_(1−b)Mn_(b)Al₁₀O₁₇ wherein M3 represents at least     one element selected from among Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5     and 0.0001≦b≦0.5.     <Second Fluorescent Material>

In the present invention, the second fluorescent material may be rare earth aluminate fluorescent material having garnet structure and activated with at least cerium, alkaline earth metal aluminate fluorescent material activated with at least Eu, alkaline earth silicate fluorescent material activated with at least Eu, alkaline earth metal silicon oxynitride fluorescent material activated with at least Eu or Ce, alkaline earth metal gallium sulfide fluorescent material activated with at least Eu or Ce, ZnS: Cu, ZnS: Mn, α-sialon fluorescent material, Ca₃Sc₂Si₃O₁₂:Ce, but is not limited to these materials.

More specifically, rare earth aluminate fluorescent material having garnet structure and activated with at least cerium may be selected from among, for example, Lu₃Al₅O₁₂: Ce, (Y, Ga)₃Al₅O₁₂: Ce, Y3Al5012: Ce and Y (Al, Ga)₅O₁₂: Ce. Among these materials, aluminum garnet fluorescent material is preferably used, and yttrium aluminum garnet fluorescent material is more preferably used.

Alkaline earth metal aluminate fluorescent material activated with at least Eu may be selected from among fluorescent materials (9) to (12) specified below. (9) Fluorescent material represented by M1_(1−a)Eu_(a)Al₂O₄ wherein M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5.

-   (10) Fluorescent material represented by M1_(1−a−b)Eu_(a)Mn_(b)Al₂O₄     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5 and 0.0001≦b≦0.5. -   (11) Fluorescent material represented by (M1_(1−a)Eu_(a))₄Al₁₄O₂₅     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5. -   (12) Fluorescent material represented by     (M1_(1−a−b)Eu_(a)Mn_(b))Al₁₄O₂₅     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5 and 0.0001≦b≦0.5.

Alkaline earth metal silicate fluorescent material activated with at least Eu may be selected from among fluorescent materials (13) and (14) specified below. (13) Fluorescent material represented by (M1_(1−a)Eu_(a))₂SiO₄ wherein M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5.

-   (14) Fluorescent material represented by     (M1_(1−a−b)Eu_(a)Mn_(b))₂SiO₄ wherein M1 represents at least one     element selected from among Mg, Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5     and 0.0001≦b≦0.5.

For the alkaline earth metal silicon oxynitride fluorescent material activated with at least Eu or Ce, for example, a fluorescent material represented by (M1_(1−a)Eu_(a))Si₂O₄N₂ may be used, wherein M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5. More specifically, BaSi₂O₂N₂:Eu, (Sr,Ca)Si₂O₂N₂:Eu or the like may be used.

For alkaline earth metal gallium sulfide fluorescent material activated with at least Eu or Ce, for example, a fluorescent material represented by (M1_(1−a)Eu_(a))Ga₂S₄ may be uses, wherein M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5.

<Third Fluorescent Material>

According to the present invention, while alkaline earth metal silicon nitride fluorescent material having monoclinic or orthorhombic crystal structure activated with at least Eu is preferably used for the third fluorescent material, such as Ca₂Si₅N₈:Eu, Sr₂Si₅N₈:Eu, Ba₂Si₅N₈:Eu, (Ca, Sr)₂Si₅N₈:Eu or the like, fluorescent materials specified below in (15) to (18) may also be used.

-   (15) Alkaline earth metal gallium sulfide fluorescent material     represented by (M1_(1−a)Eu_(a))S     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5. -   (16) Alkaline earth metal sulfide fluorescent material represented     by (M1_(1−a−b)Eu_(a)Mn_(b))S     wherein M1 represents at least one element selected from among Mg,     Ca, Ba, Sr and Zn, and 0.0001≦a≦0.5 and 0.0001≦b≦0.5. -   (17) Alkaline metal tungstate fluorescent material such as LiEuW₂O₈ -   (18) Alkaline metal borate fluorescent material activated with at     least Eu

The fluorescent materials having the typical compositions described above all have short response time as will be shown later in Table 24. According to the present invention, various fluorescent materials having luminescence center of direct transition type such as those described above can be used. Other than those, fluorescent materials having similar properties and effects may also be used.

While light emitting devices that emit light of various colors can be manufactured by combining fluorescent materials described above, light emitting devices that emit white light have wide applications and are preferable. A light emitting device that emit white light may be, for example, made by using a first fluorescent material that emits blue light, a second fluorescent material that emits green light and a third fluorescent material that emits red light, which are mixed in predetermined proportions. The second and/or third fluorescent materials are not limited to those which are strongly excited by the light from the light emitting element, but may be such that is strongly excited by the light from the first fluorescent material which is excited by the light emitting element and emits blue light, and emits light of longer wavelength than the first fluorescent material. This is because some fluorescent materials have such excitation spectra that are less likely to be excited by light in near ultraviolet region but are easily excited by light in blue region.

A mixture of first fluorescent material that emits blue light, second fluorescent material that emits green light, second fluorescent material that emits yellow light and third fluorescent material that emits red light in predetermined proportions may also be used. Also a mixture of first fluorescent material that emits blue light, second fluorescent material that emits yellow light and third fluorescent material that emits red light in predetermined proportions may be used. Furthermore, a mixture of first fluorescent material that emits blue light and second fluorescent material that emits yellow light in predetermined proportions may also be used. A light emitting device that emits white light with good color rendering property can be made by using the fluorescent material 11 comprising the first fluorescent material represented by (Sr,Ca)₅(PO₄)₃Cl:Eu that emits blue light, second fluorescent material represented by CaSi₂O₂N₂:Eu or SrSi₂O₂N₂:Eu that emits light in green to yellow region and third fluorescent material represented by (Ca, Sr)₂Si₅N₈:Eu that emits red light. This is because a white light of desired hue can be generated simply by changing the proportions of the fluorescent materials due to the use of the three primary colors, red, blue and green.

Other specific examples will be described below.

<Combinations with Blue Light Emitting Element>

Light Emitting Element

Light emitting element that emits blue light (420-490 nm, for example, wavelength 450 nm)

First Fluorescent Material

At least one kind of fluorescent material selected from the group of fluorescent materials represented by (M1_(1−a)Eu_(a))₄Al₁₄O₂₅ (M1 represents at least one element selected from among the group consisting of Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5), (M1_(1−a)Eu_(a))Si₂O₂N₂ (M1 represents at least one element selected from among the group consisting of Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5), M3_(1−a)Eu_(a)Mg_(1−b)Mn_(b)Al₁₀O₁₇ (M3 represents at least one element selected from among the group consisting of Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5 and b is a number satisfying 0.0001≦b≦0.5) and M1_(1−a)Eu_(a)Al₂O₄ (M1 represents at least one element selected from among the group consisting of Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5).

Second Fluorescent Material

Fluorescent material represented by (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y)Ga_(y))₅O₁₂:Ce (Re represents at least one kind of element selected from among Y, Gd and La, x is a number satisfying 0≦x<1 and y is a number satisfying 0≦y≦1) and/or (M1_(1−a)Eu_(a))Si₂O₂N₂ (M1 represents at least one element selected from among the group consisting of Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5).

Third Fluorescent Material

A fluorescent material represented by M₂Si₅N₈:Eu (M represents at least one element selected from among the group consisting of Sr, Ca, Ba, Mg and Zn)

With such a combination, such a light emitting device can be provided that is free from variation in the color of emitted light even when the drive current density of the light emitting device is changed and has excellent temperature characteristics, excellent excitation efficiency and high color rendering property, where adverse effect that may potentially be caused by the fluorescent material on the electrodes (electrodes of the package and of the light emitting element) and wire is eliminated and gassing caused by the fluorescent material when forming the fluorescent material layer does not occur.

<Example of Combination with Light Emitting Element that Emits Near Ultraviolet to Visible Light of Short Wavelength>

Light Emitting Element

Light Emitting Element that Emits Near Ultraviolet to Visible Light of Relatively Short Wavelength (300-420 nm, for Example, Wavelength 400 nm)

First Fluorescent Material (1)

At least one kind selected from the group of fluorescent materials represented by (M1_(1−a)Eu_(a))₁₀(PO₄)₆Q₂ (M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least one element selected from among F, Cl, Br and I, and a is a number satisfying 0.0001≦a≦0.5), (M1_(1−a)Eu_(a))₂B₅O₉Q (M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least one element selected from among F, Cl, Br and I, and a is a number satisfying 0.0001≦a≦0.5) and M3_(1−a)Eu_(a)MgAl₁₀O₁₇ (M3 represents at least one element selected from among the group consisting of Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5).

First Fluorescent Material (2)

At least one kind selected from the group of fluorescent materials represented by (M1_(1−a)Eu_(a))₄Al₁₄O₂₅ (M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5 and 0.0001≦b≦0.5), (M1_(1−a)Eu_(a))Si₂O₂N₂ (M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5), M3_(1−a)Eu_(a)Mg_(1−b)MnbAl₁₀O₁₇ (M3 represents at least one element selected from among the group consisting of Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5 electrode 3 of the light emitting element 10 is connected with an electrically conductive wire 14 to the lead frame 13 b), and M1_(1−a)Eu_(a)Al₂O₄ (M1 represents at least one element selected from among Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5).

Second Fluorescent Material

Fluorescent material represented by (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y))₅O₁₂:Ce (Re represents at least one kind of element selected from among Y, Gd and La, x is a number satisfying 0≦x<1 and y is a number satisfying 0≦y≦1) and/or (M1_(1−a)Eu_(a))Si₂O₂N₂ (M1 represents at least one element selected from among the group consisting of Mg, Ca, Ba, Sr and Zn, and a is a number satisfying 0.0001≦a≦0.5).

Third Fluorescent Material

A fluorescent material represented by M₂Si₅N₈:Eu (M represents at least one element selected from among the group consisting of Sr, Ca, Ba, Mg and Zn).

With such a combination, a light emitting device can be provided that is free from variation in the color of emitted light even when the drive current density of the light emitting device is changed and has excellent temperature characteristics, excellent excitation efficiency and high color rendering property, where adverse effect that may potentially be caused by the fluorescent material on the electrodes (electrodes of the package and of the light emitting element) and wire is eliminated and gassing caused by the fluorescent material when forming the fluorescent material layer does not occur.

Proportion of the first fluorescent material content in the entire fluorescent material is preferably 5% by weight or more and is not higher than 70% by weight, with the upper limit more preferably 50% by weight or less and most preferably 30% by weight or less. Proportion of the second fluorescent material content in the entire fluorescent material is preferably 3% by weight or more and is not higher than 80% by weight, with the upper limit more preferably 50% by weight or less and most preferably 15% by weight or less. Proportion of the third fluorescent material content in the entire fluorescent material is preferably 1% by weight or more and is not higher than 70% by weight, with the upper limit more preferably 40% by weight or less and most preferably 10% by weight or less.

Particle size of the fluorescent material 11 is preferably in a range from 1 μm to 20 μm, more preferably in a range from 2 μm to 8 μm, and most preferably in a range from 5 μm to 8 μm. A fluorescent material having particle size smaller than 2 μm tends to coagulate. A fluorescent material having particle size in a range from 5 μm to 8 μm has high efficiencies of absorbing and converting light. Mass productivity of the light emitting device can be improved by using fluorescent materials of such particle sizes having better optical characteristics.

The term particle size used herein refers to the mean particle size determined by air permeation method. With this method, 1 cm³ is metered out of the sample under ambient condition of 25° C. in temperature and 70% in relative humidity and is packed in a special tubular container through which dry air is sent to flow under a constant pressure. From pressure drop of air across the sample, specific surface area is calculated and is then converted to mean particle size. The fluorescent materials used in the present invention have mean particle sizes preferably in a range from 2 μm to 8 μm. It is also preferable that the fluorescent materials having mean particle sizes in this range are included with high proportion. It is also preferable that the fluorescent materials have particle size distribution concentrated in a narrow region, and the proportion of fine particles smaller than 2 μm, in particular, is substantially lower. Use of the fluorescent material having less variability in particle sizes with narrow particle size distribution makes it possible to obtain a light emitting device having color deviation suppressed more effectively and satisfactory color tone.

With the fluorescent materials described above, chromaticity can be freely adjusted over the region of colors ranging from blue to red and adjust the excitation spectrum and excitation efficiency over relatively broad ranges, by selecting the composition and the proportions of components.

(Coating Member)

The coating member 12 (light transmitting material) is mixed with the fluorescent material 11 that converts light from the light emitting element 10, with the mixture provided in the cup of the lead frame 13. Material used to make the coating member 12 may be a transparent resin that has good temperature characteristics and high weatherability such as epoxy resin, urea resin and silicone resin, light transmitting inorganic material that is produced from metal alkoxide by sol-gel process, glass, inorganic binder or the like. Along with the fluorescent material 11, a diffusing agent, barium titanate, titanium oxide, aluminum oxide or the like may be included. An photostabilizer and/or colorant may also be included. An inorganic binder may also be used.

The coating member 12 may also include, besides the fluorescent material 11, a light transmitting filler made of silicon oxide, aluminum oxide, aluminum nitride, boron nitride, titanium oxide or the like. In case print forming process is employed when forming the fluorescent material layer consisting of the fluorescent material 11 and the coating member 12, content of the light-permeable filler is preferably from 0 to 200 parts by weight based on 100 parts by weight of the resin and the fluorescent material combined. In case dispense forming process is employed, content of the light-permeable filler is preferably from 0 to 50 parts by weight based on 100 parts by weight of the resin and the fluorescent material combined. In case resin molding in the shape of cap is employed, content of the light-permeable filler is preferably from 0 to 400 parts by weight based on 100 parts by weight of the resin and the fluorescent material combined.

(Excitation Light Source)

It is preferable to use an excitation light source that has main peak emission wavelength in a region from ultraviolet to visible light of shorter wavelengths. Emission wavelength of the excitation light source is preferably in a range from 250 to 500 nm, more preferably in a range from 290 to 470 nm and most preferably in a range from 340 to 420 nm. As long as the peak emission wavelength lies in the range described above, there is no limitation to the excitation light source, which may be semiconductor light emitting element or one that uses energy supplied by lamp, electron beam, plasma, EL or the like, while use if a semiconductor light emitting element is preferred.

The light emitting element of the first embodiment has the substrate 1 made of sapphire, the semiconductor layer 2 formed thereon, and the positive and negative electrodes formed on the same side of the semiconductor layer 2. The semiconductor layer 2 consists of a plurality of layers containing the light emitting layer (not shown), and blue light is emitted from the light emitting layer.

The semiconductor light emitting element capable of emitting light of wavelength not longer than 500 nm in ultraviolet to visible region can be made of various semiconductors such as BN, SiC, ZnSe, GaN, InGaN, InAlGaN, AlGaN, BalGaN and BinAlGaN. An impurity element such as Si or Zn may be added to these semiconductors to form luminescence center. A material suitable for forming the light emitting layer that can efficiently emit light of short wavelength in the ultraviolet to visible region, which has high efficiency in exciting fluorescent materials, is nitride semiconductor (for example, nitride semiconductor containing Al and/or Ga, nitride semiconductor that includes In and/or Ga such as In_(x)Al_(y)Ga_(1−x−y):N, 0<X<1, 0<Y<1, X+Y≦1).

Preferable structures of the light emitting element include homojunction structure that has MIS junction, PIN junction or pn junction, heterojunction structure or double heterojunction structure. Emission wavelength can be controlled by selecting the semiconductor material and adjusting the composition of mixed crystal. Output power can be increased by forming the active layer in a thin film where quantum effect can be utilized having single quantum well structure or multiple quantum well structure.

When a nitride semiconductor is used, the substrate can be made of sapphire, spinel, SiC, Si, ZnO, GaAs, GaN or the like. In order to form the nitride semiconductor with good crystallinity and characteristic suitable for mass production, it is preferable to use a sapphire substrate. The nitride semiconductor can be formed on the sapphire substrate by the HVPE process, MOCVD process or the like. In this case, it is preferable to form the nitride semiconductor that has pn junction on a buffer layer that is not a single crystal and is formed on the sapphire substrate by growing GaN, AlN, GaAlN or the like at a low temperature.

[Example of Light Emitting Element that Emits Ultraviolet Light]

An example of light emitting element that can efficiently emit ultraviolet ray made of nitride semiconductor having pn junction can be formed in such a structure as described below.

First, a SiO₂ layer is formed in stripe pattern on a buffer layer at substantially right angles to the orientation flat plane of the sapphire substrate. Then a GaN layer is formed on the stripe pattern through ELOG (Epitaxial Lateral Over Growth GaN) by the HVPE method. Then a first contact layer made of n-type gallium nitride, a first cladding layer made of n-type aluminum gallium nitride, an active layer of multiple quantum well structure consisting of a plurality of well layers made of indium aluminum gallium nitride and barrier layers made of aluminum gallium nitride formed one on another, a second cladding layer made of p-type aluminum gallium nitride and a second contact layer made of p-type gallium nitride are formed successively in this order, so as to form a double heterojunction structure. With this constitution, the active layer can be formed in a ridge stripe pattern sandwiched by guide layers with a resonator end face being provided, so as to make a semiconductor laser element that can be used in the present invention.

[Example of Light Emitting Element that Emits Blue Light]

The light emitting element 10 may also be a light emitting element that emits blue light, instead of the light emitting element that emits ultraviolet ray. The light emitting element 10 that emits blue light is preferably made of nitride of a group III element. The light emitting element 10 comprises an undoped n-type GaN layer, an n-type contact layer made of Si-doped GaN, an undoped GaN layer, a light emitting layer having multiple quantum well structure (quantum well structure comprising GaN barrier layers/InGaN well layers), a p-type cladding layer made of Mg-doped p-type GaN and a p-type contact layer made of Mg-doped p-type GaN, formed one on another on the sapphire substrate 1 via a GaN buffer layer, thereby forming the electrodes as described below. A p ohmic electrode is formed over substantially the entire surface of the p-type contact layer, and a p-pad electrode is formed on the p ohmic electrode. The n electrode is formed on an exposed portion of the n-type contact layer after removing the undoped GaN layer from the p-type contact layer by etching.

This embodiment employs the light emitting layer of multiple quantum well structure, although the present invention is not limited to this constitution and, for example, single quantum well structure formed with InGaN may be employed, or GaN doped with Si or Zn may be used. Principal peak emission wavelength of the light emitting layer of the light emitting element 10, 101 can be changed within a range from 420 nm to 490 nm. The peak emission wavelength is not limited to the range described above, and those having peak emission wavelength in a range from 360 nm to 550 nm may also be used.

While a nitride semiconductor has n-type electrical conductivity when not doped with an impurity, it is preferable to form an n-type nitride semiconductor having predetermined carrier concentration in order to improve the efficiency of light emission, in which case Si, Ge, Se, Te, C or the like is introduced as an n-type dopant. When a p-type nitride semiconductor is formed, on the other hand, Zn, Mg, Be, Ca, Sr, Ba or the like is added as a p-type dopant. Since a nitride semiconductor is difficult to turn to p-type simply by doping with a p-type dopant, it is preferable to decrease the resistance by heating in a furnace or irradiating with plasma after the introduction of the p-type dopant. In case the positive and negative electrodes are formed while leaving the sapphire substrate intact, both the p-type and n-type contact layers are exposed on the same side by partially etching on the p-type side to the surface of the first contact layer. Then after forming the electrodes on both contact layers, the wafer is diced into chips thereby by making nitride semiconductor light emitting elements (chips).

In the first embodiment, it is preferable to use a resin when attaching the fluorescent material 11 to the light emitting element 10, in order to ensure high mass productivity. In this case, when the emission wavelength of the fluorescent material 11, deterioration of the light transmitting resin and other factors are taken into consideration, it is preferable to use the light emitting element 10 that has emission spectrum in the ultraviolet region with peak emission wavelength falling in a region from 360 nm to 420 nm or in a region from 450 nm to 470 nm. While the blue light emitting element is used, it is preferable to set the peak emission wavelength in a region from 450 nm to 470 nm in consideration of by taking into consideration the excitation wavelength of the nitride fluorescent material and deterioration of the light transmitting resin, in case a light transmitting resin is used as the coating member and the molding member.

In the light emitting device according to the present invention, in case a light emitting element other than the blue light emitting element is used as in the seventh embodiment to be described later, it is preferable to set the principal emission peak wavelength of the light emitting element in a region from 360 nm to 420 nm in consideration of the excitation wavelength of the nitride fluorescent material and deterioration of the light transmitting resin.

In the semiconductor light emitting element, it is preferable to control the sheet resistance Rn of the n-type contact layer having impurity concentration of 10¹⁷ to 10²⁰/cm³ and the sheet resistance Rp of the light transmitting p electrode to satisfy the relation of Rp≧Rn. The n-type contact layer is preferably formed to thickness of 3 to 10 μm, more preferably from 4 to 6 μm. Since the sheet resistance Rn of the n-type contact layer is estimated to be in a range from 10 to 15 Ω/□, the thin film may be formed to have a sheet resistance equal to or higher than the value described above. Specifically, the light transmitting p electrode is preferably formed as thin as 150 μm or less. The p electrode may also be formed from ITO or ZnO as well as a metal. The p electrode may be replaced with an electrode having a plurality of light extracting apertures such as mesh electrode.

In case the light transmitting p electrode is formed from a multi-film layer, made of one kind of metal selected from the group consisting of gold and platinum group elements and at least one kind of other metal, or an alloy, then stability and reproductivity can be improved by controlling the content of gold or platinum group element thereby to regulate the sheet resistance of the light transmitting p electrode. Since gold or the other metal element has a high absorptivity in the wavelength region of the semiconductor light emitting element that is used in the present invention, transmissivity becomes higher when the light transmitting p electrode contains less gold or platinum group element. The semiconductor light emitting element of the prior art has the relation of Rp≦Rn for the sheet resistances. When Rp is not less than Rn, the light transmitting p electrode is formed with smaller thickness than in the prior art, the thickness can be decreased easily by reducing the content of gold or the other metal element.

In the semiconductor light emitting element used in the present invention, as described above, sheet resistance Rn Ω/□ of the n-type contact layer and sheet resistance Rp Ω/□ of the light transmitting p electrode are preferably controlled to satisfy the relationship of Rp≧Rn. It is difficult to measure the value of Rn after making the semiconductor light emitting element, and it is virtually impossible to know the relationship between Rp and Rn, although the relationship between Rp and Rn can be estimated from the light intensity distribution during emission.

When the light transmitting p electrode and the n-type contact layer have the relationship of Rp≧Rn, external quantum efficiency can be improved further by providing a p-type pedestal electrode having an extension conductor on the light transmitting p electrode. There are no limitations on the shape and direction of the extension conductor. In case the extension conductor has a shape of straight line, it is preferable since the area of blocking light is reduced, but mesh configuration may also be employed. For the shape, curved line, grating, branched tree or hook may be employed as well as straight line. Since light blocking effect increases in proportion to the total area of the p-side pedestal electrode, it is desirable to design the wire width and length of the extension conductor so that the light blocking effect does not surpass the light emission enhancing effect.

(Lead Frame)

The lead frame 13 comprises the mount lead 13 a and the inner lead 13 b.

The mount lead 13 a has the cup to house the light emitting element 10 placed therein. The mount lead 13 a can be used as a common electrode for a plurality of light emitting elements 10 with the plurality of light emitting elements 10 being placed in the cup of the mount lead 13 a. In this case, sufficient level of electrical conductivity and connectivity with the electrically conductive wire 14 are required. The light emitting elements 10 and the cup of the mount lead 13 a can be die-bonded by means of a thermosetting plastic or the like. For the thermosetting plastic, epoxy resin, acrylic resin, imide resin or the like may be used. An inorganic binder may also be used. For die-bonding and electrically connecting the light emitting elements 10 and the mount lead 13 a with each other in such a configuration as the electrodes of the light emitting elements 10 and the lead electrodes are disposed to oppose and connected with each other, Ag paste, carbon paste, metal bumps or the like may be used.

The inner lead 13b is to be electrically connected with the electrically conductive wire 14 to the other electrode 3 of the light emitting element 10 disposed on the mount lead 13 a. In order to avoid short circuiting caused by electrical contact with the mount lead 13 a, the inner lead 13 b is disposed at a position separated from the mount lead 13 a. In case a plurality of light emitting elements 10 are mounted on the mount lead 13 a, it is necessary to make such an arrangement that makes it easy to carry out wire bonding while keeping the electrically conductive wires from touching each other. The inner lead 13 b is preferably made of the same material as the mount lead 13 a, and iron, copper, iron-containing copper, gold, platinum, silver or an alloy thereof may be used.

(Electrically Conductive Wire)

The electrically conductive wire 14 is used to electrically connect the electrode 3 of the light emitting element 10 and the lead frame 13. The electrically conductive wire 14 is preferably good in ohmic contact with the electrode 3, mechanical connectivity, electrical conductivity and heat conductivity. The electrically conductive wire 14 is preferably made of a metal such as gold, copper, platinum or aluminum, or an alloy thereof.

(Molding Member)

The molding member 15 is provided for protecting the light emitting element 10, the fluorescent material 11, the coating member 12, lead frame 13 and the electrically conductive wire 14 from the environment. The molding member 15 also has, in addition to the protection from the environment, such purposes as increasing the angle of view, mitigating the directivity of the light emitted by the light emitting element 10 and converging or diffusing the emitted light. The molding member 15 may be formed in such a shape that is favorable for these purposes. The molding member 15 may be formed, for example, in such a shape as convex lens or concave lens, or in stacked structure of a plurality of layers. Specifically, the molding member 15 may be made of a material that has good temperature characteristics and high weatherability such as epoxy resin, urea resin and silicone resin, light-permeable inorganic material that is produced from metal alkoxide by sol-gel process, glass, inorganic binder or the like. The molding member 15 may include a diffusing agent, colorant, ultraviolet ray absorbing material or fluorescent material. For the diffusing agent, barium titanate, titanium oxide, aluminum oxide or the like are preferably used. The molding member 15 is preferably made of the same material as that of the coating member 12 in order to ensure affinity therewith and favorable index of refraction.

Second Embodiment

The light emitting device according to the second embodiment of the present invention is a variation of the light emitting device according to the first embodiment where a blue light emitting element is used as light emitting element and yttrium aluminum garnet fluorescent material (YAG fluorescent material) is used as the second fluorescent material. This embodiment is similar to the first embodiment with other respect.

The light emitting device of the second embodiment uses a blue light emitting element that emits blue light (for example, wavelength 460 nm) and at least two kinds of fluorescent material which are excited by the blue light and emit light of longer wavelengths, so as to generate light of desired color through blending of the blue light from the light emitting element and the light from the fluorescent materials.

The light emitting device according to the second embodiment of the present invention constituted as described above suppresses both the variation in the color of emitted light (color deviation) due to variation in the drive current of the light emitting element and the variation in the color of emitted light due to difference in the drive mode (particularly the difference between DC drive and pulse drive) to extremely low levels, since two or more kinds of fluorescent material are of direct transition type similarly to the first embodiment.

Yttrium aluminum garnet fluorescent material (YAG fluorescent material) and other components will now be described in detail below.

The yttrium aluminum garnet fluorescent material (YAG fluorescent material) used in this embodiment collectively refers to all fluorescent materials having garnet structure that include rare earth element such as Y and group III element such as Al and are activated by at least one element selected from the rare earth elements, so as to be excited by the blue light from the light emitting element 10 and emit light.

For the YAG fluorescent material, for example, (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y))₅O₁₂:Ce (0≦x<1, 0≦y≦1, wherein Re represents at least one kind of element selected from among Y, Gd and La) may be used.

The (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y))₅O₁₂:Ce fluorescent material is durable against heat, light and moisture and is particularly preferably used for extended period of operation with high luminance, because of the garnet structure. It also allows it to set the peak wavelength of excitation spectrum at around 470 nm. A broad emission spectrum that has emission peak around 530 nm and tails off to 720 nm can be obtained.

RGB components can be increased by mixing two or more kinds of (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y))₅O₁₂:Ce fluorescent material having different contents of Al, Ga, In, Y, La, Gd and Sm for the YAG fluorescent material. While some semiconductor light emitting element are subject to variations in the emission wavelength, blended light of desired white-based color can be obtained by mixing two or more kinds of fluorescent material. Specifically, by combining the fluorescent materials having different values of chromaticity to match the emission wavelength of the light emitting element, light of desired chromaticity can be emitted at any point on the chromaticity diagram in a region defined by the points corresponding to the fluorescent materials and the light emitting element.

Aluminum garnet fluorescent material contains Al, at least one element selected from among Y, Lu, Sc, La, Gd, Tb, Eu and Sm, and at least one element selected from among Ga and In, and is activated with at least one element selected from among rare earth elements, so as to be excited by visible light or ultraviolet ray and emit light.

Emission spectrum of this type of fluorescent material having garnet structure shifts toward shorter wavelengths when part of Al is substituted by Ga, and shifts toward longer wavelengths when part of Y is substituted by Gd and/or La. In this way the color of emitted light can be changed continuously by changing the composition. As a result, the fluorescent material has the ideal feature for converting the light in blue region emitted by the nitride semiconductor into white light, including continuously changing the intensity of light of longer wavelength by changing the proportion of Gd. When less than 20% of Y is substituted, green component increases and red component decreases, while red component increases but luminance shows marked decrease when 80% or more of Y is substituted.

The excitation spectrum, too, of this type of fluorescent material having garnet structure shifts toward shorter wavelengths when part of Al is substituted by Ga, and shifts toward longer wavelengths when part of Y is substituted by Gd and/or La. Peak emission wavelength of the excitation spectrum of the fluorescent material is preferably shorter than the peak wavelength of the emission spectrum of the light emitting element. With this constitution, since the peak wavelength of the excitation spectrum substantially agrees with the peak wavelength of the emission spectrum of the light emitting element, color deviation can be prevented from occurring without decreasing the excitation efficiency of the fluorescent material, when the current supply to the light emitting element is increased.

Suitable fluorescent materials include, in addition to the YAG fluorescent material described above, Tb_(2.95)Ce_(0.05)Al₅O₁₂, Y_(2.90)Ce_(0.05)Tb_(0.05)Al₅O₁₂, Y_(2.94)Ce_(0.05)Pr_(0.01)Al₅O₁₂, Y_(2.90)Ce_(0.05)Pr_(0.05)Al₅O₁₂, and those listed in Table 3. Among these, yttrium aluminum oxide fluorescent material that contains Y and is activated with Ce or Pr is particularly preferable. It is especially preferable to combine two or more kinds of fluorescent material having different compositions.

For example, yttrium aluminum oxide fluorescent material activated with cerium can emit light in green or red region. The fluorescent material capable of emitting light in green region is durable against heat, light and moisture and has peak wavelength of excitation spectrum in a range from 420 nm to 470 nm, peak emission wavelength Xp around 510 nm and has a broad emission spectrum that tails off to around 700 nm, due to the garnet structure. The fluorescent material capable of emitting light in red region, which has garnet structure, is durable against heat, light and moisture and has peak wavelength of excitation spectrum in a range from 420 nm to 470 nm, emission peak wavelength Xp around 600 nm and has a broad emission spectrum that tails off to around 750 nm.

Third Embodiment

In this embodiment, an excitation light source having principal emission peak wavelength in a range from 250 nm to 500 nm is used, and two or more kinds of fluorescent material that are directly excited by the excitation light source containing oxynitride-based fluorescent material or nitride-based fluorescent material are used. This embodiment is similar to the first embodiment, except for the difference described below.

Both oxynitride-based fluorescent material and nitride-based fluorescent material can be of the direct excitation type. As a result, in this embodiment, too, the variation in the color of emitted light (color deviation) due to variation in the drive current of the light emitting element and the variation in the color of emitted light due to difference in the drive mode (particularly the difference between DC drive and pulse drive) can be suppressed to extremely low levels, by using two or more kinds of fluorescent material of direct transition type similarly to the first embodiment.

Excitation spectra of oxynitride-based fluorescent material and nitride-based fluorescent material are shown in FIG. 3. FIG. 3 shows normalized excitation spectra of oxynitride-based fluorescent material and nitride-based fluorescent material. In FIG. 3, 31 to 33 denote spectra of oxynitride-based fluorescents and 34 to 36 denote spectra of nitride-based fluorescents. Specifically, 31 denotes CaSi₂O₂N₂:Eu, 32 denotes SrSi₂O₂N₂:Eu, 33 denotes BaSi₂O₂N₂:Eu, 34 denotes Ca₂Si₅N₈:Eu, 35 denotes Sr₂Si₅N₈:Eu, and 36 denotes (Ca,Sr)₂Si₅N₈:Eu. As can be seen from FIG. 3, both the oxynitride-based fluorescent material and the nitride-based fluorescent material can more efficiently convert the wavelength of the light of relatively long wavelength emitted by the excitation light source. Specifically, the oxynitride-based fluorescent material and the nitride-based fluorescent material can be directly excited in a wide wavelength from 250 nm to 500 nm. The expression that a fluorescent material can be directly excited by an excitation light source herein means that the emission efficiency of the fluorescent material at a wavelength corresponding to the principal emission peak of the excitation light source is 60% or higher. Specifically, if the intensity of the excitation spectrum at the principal emission peak wavelength of the excitation light source is not less than 60% of the maximum value of the excitation spectrum, fluorescent material can be directly excited by the excitation light source. The oxynitride-based fluorescent material and the nitride-based fluorescent material can be excited by using various light sources including an excitation light source that emits ultraviolet ray, a light emitting element that emits visible light of short wavelength and a light emitting element that emits blue light (420-490 nm).

Various light emitting elements having high performance can be made by making use of the characteristics described above.

For example, when oxynitride-based fluorescent material or nitride-based fluorescent material is combined with a fluorescent material that emits light in blue region (420-490 nm), excitation with blue light (420-490 nm) from other fluorescent material can be achieved in addition to the direct excitation of the oxynitride-based fluorescent material or the nitride-based fluorescent material by means of the excitation light source. Thus such a light emitting device can be provided that emits light over a wide range of color tones, by using a fluorescent material that emits light in blue region (for example, alkaline earth metal halogen apatite fluorescent material, alkaline earth metal aluminate fluorescent material or the like) as the excitation light source so as to excite the oxynitride-based fluorescent material or nitride-based fluorescent material with the blue light. As the fluorescent material that emits light in blue region, those used as the first fluorescent material in the first embodiment may be used.

It is preferable to excite phosphors with blue light emitting elements (main peak emission at 420-490 nm) as an excitation light source, the phosphors including:

-   -   (a) oxynitride-based fluorescent material or nitride-based         fluorescent material and     -   (b) at least one phosphor selected from the group consisting of         (M1_(1−a)Eu_(a))₄Al₁₄O₂₅ (M1 represents at least one element         selected from among the group consisting of Mg, Ca, Ba, Sr and         Zn, and a is a number satisfying 0.0001≦a≦0.5),     -   M3_(1−a)Eu_(a)Mg_(1−b)Mn_(b)Al₁₀O₁₇ (M3 represents at least one         element selected from among the group consisting of Ca, Ba, Sr         and Zn, and a is a number satisfying 0.0001≦a≦0.5 and b is a         number satisfying 0.0001≦b≦0.5),     -   M1_(1−a)Eu_(a)Al₂O₄ (M1 represents at least one element selected         from among the group consisting of Mg, Ca, Ba, Sr and Zn, and a         is a number satisfying 0.0001≦a≦0.5),     -   (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y))₅O₁₂:Ce (Re represents at least         one kind of element selected from among Y, Gd and La, x is a         number satisfying 0≦x<1 and y is a number satisfying 0≦y≦1) and     -   MGa₂S₄:Eu (M is at least one kind selected from among Sr, Ca,         Ba, Mg and Zn; X is at least one kind selected from among F, Cl,         Br and I).

By constructing a light emitting device with these fluorescent material and light source, light emitting device with superior temperature characteristics and excitation efficiency is provided. Also, this device shows a reduced color deviation even if the driving current density of light emitting element varies. Further, life property is also improved.

It is more preferable to excite phosphors with blue light emitting elements (main peak emission at 420-490 nm) as an excitation light source, the phosphors including:

-   -   (a) oxynitride-based fluorescent material and     -   (b) (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y))₅O₁₂:Ce (Re represents at         least one kind of element selected from among Y, Gd and La, x is         a number satisfying 0≦x<1 and y is a number satisfying 0≦y≦1).         This provides a white light emitting device with high luminous         intensity and high color rendering.

It is also preferable to excite phosphors with a light source emitting light from near ultraviolet to visible light of short wavelength (300-420 nm), the phosphors including:

-   -   (a) oxynitride-based fluorescent material or nitride-based         fluorescent material and     -   (b) at least one phosphor selected from the group consisting of         (M1_(1−a)Eu_(a))₁₀(PO₄)₆Q₂ (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least         one element selected from among F, Cl, Br and I, and a is a         number satisfying 0.0001≦a≦0.5),     -   (M1_(1−a)Eu_(a))₂B₅O₉Q (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least         one element selected from among F, Cl, Br and I, and a is a         number satisfying 0.0001≦a≦0.5),     -   M3_(1−a)Eu_(a)MgAl₁₀O₁₇ (M3 represents at least one element         selected from among the group consisting of Ca, Ba, Sr and Zn,         and a is a number satisfying 0.0001≦a≦0.5),     -   (M1_(1−a)Eu_(a))₄Al₁₄O₂₅ (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, and a is a number         satisfying 0.0001≦a≦0.5 and 0.0001≦b≦0.5),     -   M3_(1−a)Eu_(a)Mg_(1−b)Mn_(b)Al₁₀O₁₇ (M3 represents at least one         element selected from among the group consisting of Ca, Ba, Sr         and Zn, and a is a number satisfying 0.0001≦a≦0.5 electrode 3 of         the light emitting element 10 is connected with an electrically         conductive wire 14 to the lead frame 13 b),     -   M1_(1−a)Eu_(a)Al₂O₄ (M1 represents at least one element selected         from among Mg, Ca, Ba, Sr and Zn, and a is a number satisfying         0.0001≦a≦0.5),     -   (Re_(1−x)Sm_(x))₃ (Al_(1−y)Ga_(y))₅O₁₂:Ce (Re represents at         least one kind of element selected from among Y, Gd and La, x is         a number satisfying 0≦x<1 and y is a number satisfying 0≦y≦1),         and     -   MGa₂S₄:Eu (M is at least one kind selected from among Sr, Ca,         Ba, Mg and Zn; X is at least one kind selected from among F, Cl,         Br and I).

By constructing a light emitting device with these fluorescent material and light source, light emitting device with superior temperature characteristics and excitation efficiency is provided. Also, this device shows a reduced color deviation even if the driving current density of light emitting element varies. Further, as color deviation caused by wavelength deviation of light emitting element can be reduced, the light emitting device can be manufactured with a high yield.

It is more preferable to excite phosphors with a light source emitting light from near ultraviolet to visible light of short wavelength (300-420 nm), the phosphors including:

-   -   (a) oxynitride-based fluorescent material and     -   (b) at least one phosphor selected from the group consisting of         (M1_(1−a)Eu_(a))₁₀(PO₄)₆Q₂ (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least         one element selected from among F, Cl, Br and I, and a is a         number satisfying 0.0001≦a≦0.5),     -   (M_(1−a)Eu_(a))₂B₅O₉Q (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least         one element selected from among F, Cl, Br and I, and a is a         number satisfying 0.0001≦a≦0.5),     -   M3_(1−a)Eu_(a)MgAl₁₀O₁₇ (M3 represents at least one element         selected from among the group consisting of Ca, Ba, Sr and Zn,         and a is a number satisfying 0.0001≦a≦0.5),     -   (M1_(1−a)Eu_(a))₄Al₁₄O₂₅ (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, and a is a number         satisfying 0.0001≦a≦0.5 and 0.0001≦b≦0.5),     -   M3_(1−a)Eu_(a)Mg_(1−b)Mn_(b)Al₁₀O₁₇ (M3 represents at least one         element selected from among the group consisting of Ca, Ba, Sr         and Zn, and a is a number satisfying 0.0001≦a≦0.5 electrode 3 of         the light emitting element 10 is connected with an electrically         conductive wire 14 to the lead frame 13 b) and     -   M1_(1−a)Eu_(a)Al₂O₄ (M1 represents at least one element selected         from among Mg, Ca, Ba, Sr and Zn, and a is a number satisfying         0.0001≦a≦0.5). This provides a white light emitting device with         high luminous intensity and high color rendering.

With such a constitution as described above, a light emitting diode capable of emitting wide range of color with high luminance can be made, so that the light emitting device that allows it to control the color tone vary easily and is excellent in mass productivity and in reliability can be provided.

A light emitting device of high efficiency multi-color emission can be made by combining oxynitride-based fluorescent material or nitride-based fluorescent material that is directly excited by the excitation light source and by other fluorescent material that is directly excited by the excitation light source. For example, a light emitting device that emits light over a wide range of color tones can be provided by using oxynitride-based fluorescent material, nitride-based fluorescent material, alkaline earth metal halogen apatite fluorescent material activated mainly with lanthanoid element such as Eu or transition metal element such as Mn, alkaline earth metal boric acid halide salt fluorescent material, alkaline earth silicate, rare earth oxysulfide, alkaline earth sulfide, alkaline earth thiogallate, alkaline earth silicon nitride, germanate, rare earth aluminate or rare earth silicate activated mainly with lanthanoid element such as Ce or organic material and organic complex activated mainly with lanthanoid element such as Eu.

FIG. 4 is a CIE chromaticity diagram showing the region of color tones that can be achieved by using the excitation source which emits ultraviolet ray. In FIG. 4, 41 denotes Ca₁₀(PO₄)₆Cl₂:Eu, 42 denotes BaSi₂O₂N₂:Eu, 43 denotes BaMgAl₁₀O₁₇:Eu,Mn, 44 denotes SrGa₂S₄:Eu, 45 denotes SrSi₂O₂N₂:Eu, 46 denotes CaSi₂O₂N₂:Eu, 47 denotes (Y,Gd)₃Al₅O₁₂:Ce, 48 denotes Sr₂Si₅N₈:Eu, 49 denotes Ca₂Si₅N₈:Eu, 50 denotes (Sr,Ca)₂Si₅N₈:Eu. FIG. 5 is a CIE chromaticity diagram showing the region of color tones that can be achieved by using an excitation source which emits blue light (420-490 nm). In FIG. 5, 51 denotes a light of λ=460 nm, 52 denotes BaSi₂O₂N₂:Eu, 53 denotes BaNgAl₁₀O₁₇:Eu,Mn, 54 denotes SrGa₂S₄:Eu, 55 denotes SrSi₂O₂N₂:Eu, 56 denotes CaSi₂O₂N₂:Eu, 57 denotes (Y,Gd)₃Al₅O₁₂:Ce, 58 denotes Ca₂Si₅N₈:Eu, 59 denotes Sr₂Si₅N₈:Eu, and 60 denotes (Sr,Ca)₂Si₅N₈:Eu.

As shown in FIG. 4, in case an excitation light source having principal emission peak at around 400 nm in the ultraviolet region is used, possible range of color reproduction is expanded by using two or more kinds of fluorescent material having peak emission wavelengths in the visible light region. The fluorescent material 11 is directly excited by the light from the excitation light source. In case an excitation light source that emits ultraviolet ray is used, since the excitation light source is difficult or impossible to visually recognize, the color of emitted light can be determined only by means of the color of the fluorescent material 11. Thus it is preferable to adjust the mix proportions of the fluorescent materials in order to obtain light emission of the desired color tone. Table 1 shows the chromaticity values of fluorescent materials when an excitation light source having principal emission peak at about 400 nm is used. TABLE 1 x y CaSi2O2N2:Eu 0.422 0.549 SrSi2O2N2:Eu 0.333 0.614 BaSi2O2N2:Eu 0.081 0.453 Ca2Si5N8:Eu 0.646 0.346 Sr2Si5N8:Eu 0.638 0.361 (Sr, Ca) 2Si5N8:Eu 0.663 0.321 Ca₁₀ (PO4) 6Cl2:Eu 0.138 0.059 BaMgAl10O17:Eu, Mn 0.145 0.666 SrGa2S4:Eu 0.283 0.680 BaGa2S4:Eu 0.143 0.517 (Y, Gd) 3Al5O12:Ce 0.472 0.486

As shown in FIG. 5, when an excitation light source that emits light in blue region with principal emission peak at about 460 nm is used, the fluorescent material that emits light in blue region becomes unnecessary and the tedious process of mixing the fluorescent materials in predetermined proportions can be omitted. Table 2 shows the chromaticity values of fluorescent materials when an excitation light source having principal emission peak at about 460 nm is used. TABLE 2 x y CaSi2O2N2:Eu 0.427 0.551 SrSi2O2N2:Eu 0.334 0.623 BaSi2O2N2:Eu 0.081 0.453 Ca2Si5N8:Eu 0.595 0.399 Sr2Si5NB:Eu 0.632 0.361 (Sr, Ca) 2Si5N8:Eu 0.646 0.346 BaMgAl10O17:Eu, Mn 0.169 0.731 SrGa2S4:Eu 0.279 0.690 (Y, Gd) 3Al5O12:Ce 0.456 0.527

FIG. 6 shows the excitation spectrum of YAG fluorescent material that has been used in the conventional light emitting devices, for comparison with oxynitride-based fluorescent material or nitride-based fluorescent material. As shown in FIG. 6, the YAG fluorescent material has maximum emission efficiency at around 460 nm, and can convert blue light from the excitation light source to light in yellow-green to yellow region with high efficiency. In the ultraviolet region from 370 nm to 400 nm, in contrast, emission efficiency is as low as less than 10% that of around 460 nm and most of the incident ultraviolet ray is reflected. As a result, light emission can hardly be achieved with the excitation light source that emits ultraviolet ray and the YAG fluorescent material only.

FIG. 7 is a CIE chromaticity diagram showing the region of color tones that can be achieved with a light emitting device which combines only a blue light emitting element and one kind of YAG fluorescent material. This is a light emitting device of the prior art that emits white light. Since this light emitting device generates white light by means of a fluorescent material that is excited by ultraviolet ray and emits blue light and YAG fluorescent material that is excited by the blue light and emits yellow light, it can generate color tones that lie on the straight line connecting blue and yellow on the chromaticity diagram. Therefore, it has been impossible to provide a light emitting device that emits light with multiple colors.

Now the fluorescent materials used in this embodiment will be described in detail below.

(Fluorescent Material)

Two or more kinds of directly excited fluorescent material containing oxynitride-based fluorescent material or nitride-based fluorescent material are used as the fluorescent material 11. The expression that a fluorescent material is directly excited means that it is excited mainly by the light from the excitation light source and, in case an excitation light source that has principal emission peak in ultraviolet region is used, efficiency of light emission is 60% of the maximum value in the visible region or higher. That a fluorescent material is not directly excited, on the other hand, means that it is hardly excited by the light from the excitation light source but is excited by primary light from other fluorescent material that is excited by the light from the excitation light source.

<Oxynitride-Based Fluorescent Material>

For the oxynitride-based fluorescent material, it is preferable to use alkaline earth metal oxynitride fluorescent material and it is more preferable to use alkaline earth metal silicon oxynitride fluorescent material. The alkaline earth metal oxynitride fluorescent material contains at least one kind of group II element selected from the group consisting of Be, Mg, Ca, Sr, Ba and Zn, at least one kind of group IV element selected from the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf and a rare earth element as activator R, and has crystal structure. Although these elements may be included in any combination, it is preferable that the oxynitride-based fluorescent material has such a composition as represented by general formula L_(X)M_(Y)O_(Z)N₍₍2/3)X+(4/3)Y−(2/3)Z):R or L_(X)M_(Y)Q_(T)O_(Z)N₍₍2/3)X+(4/3)Y+T−(2/3)Z):R. L is at least one kind of group II element selected from the group consisting of Be, Mg, Ca, Sr, Ba and Zn. M is at least one kind of group IV element selected from the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf. Q is at least one kind of group III element selected from the group consisting of B, Al, Ga and In. O is oxygen, N is nitrogen, and R is a rare earth element. Ranges of parameters are 0.5<X<1.5, 1.5<Y<2.5, 0<T<0.5 and 1.5<Z<2.5. High luminance is achieved when X, Y and Z are in the ranges above. Oxynitride-based fluorescent material of the general formula described above wherein X=1, Y=2 and Z=2 shows high luminance and is particularly preferable.

Composition is not limited to that described above, and any composition may be used.

Specifically, there can be used oxynitride-based fluorescent materials represented by CaSi₂O₂N₂:Eu, SrSi₂O₂N₂:Eu, BaSi₂O₂N₂:Eu, ZnSi₂O₂N₂:Eu, CaGe₂O₂N₂:Eu, SrGe₂O₂N₂:Eu, BaGe₂O₂N₂:Eu, ZnGe₂O₂N₂:Eu, Ca_(0.5)Sr_(0.5)Si₂O₂N₂:Eu, Ca_(0.5)Ba_(0.5)Si₂O₂N₂:Eu, Ca_(0.5)Zn_(0.5)Si₂O₂N₂:Eu, Ca_(0.5)Be_(0.5)Si₂O₂N₂:Eu, Sr_(0.5)Ba_(0.5)Si₂O₂N₂:Eu, Ca_(0.8)Mg_(0.2)Si₂O₂N₂:Eu, Sr_(0.8)Mg_(0.2)Si₂O₂N₂:Eu, Ca_(0.5)Mg_(0.5)Si₂O₂N₂:Eu, Sr_(0.5)Mg_(0.5)Si₂O₂N₂:Eu, CaSi₂B_(0.1)O₂N₂:Eu, SrSi₂B_(0.1)O₂N₂:Eu, BaSi₂B_(0.1)O₂N₂:Eu, ZnSi₂B_(0.1)O₂N₂:Eu, CaGe₂B_(0.01)O₂N₂:Eu, SrGe₂Ga_(0.01)O₂N₂:Eu, BaGe₂In_(0.01)O₂N₂:Eu, ZnGe₂Al_(0.05)O₂N₂:Eu, Ca_(0.5)Sr_(0.5)Si₂B_(0.3)O₂N₂:Eu, CaSi_(2.5)O_(1.5)N₃:Eu, SrSi_(2.5)O_(1.5)N₃:Eu, BaSi_(2.5)O_(1.5)N₃:Eu, Ca_(0.5)Ba_(0.5)Si_(2.5)O_(1.5)N₃:Eu, Ca_(0.5)Sr_(0.5)Si_(2.5)O_(1.5)N₃:Eu, Ca_(1.5)Si_(2.5)O_(2.5)N_(2.7):Eu, Sr_(1.5)Si_(2.5)O_(2.5)N_(2.7):Eu, Ba_(1.5)Si_(2.5)O_(2.5)N_(2.7):Eu, Ca_(1.0)Ba_(0.5)Si_(2.5)O_(1.5)N₃:Eu, Ca_(1.0)Sr_(0.5)Si_(2.5)O_(1.5)N₃:Eu, Ca_(0.5)Si_(1.5)O_(1.5)N_(1.7):Eu, Sr_(0.5)Si_(1.5)O_(1.5)N_(1.7):Eu, Ba_(0.5)Si_(1.5)O_(1.5)N_(1.7):Eu, Ca_(0.3)Ba_(0.2)Si_(2.5)O_(1.5)N₃:Eu and Ca_(0.2)Sr_(0.3)Si_(2.5)O_(1.5)N₃: Eu.

Color tone and luminance of oxynitride-based fluorescent material can be controlled by changing the proportions of O and N. Emission spectrum and intensity can also be controlled by changing the molar ratio of anion and cation (L+M)/(O+N). This can be achieved, for example, through desorption of N or O in vacuum, but is not limited to this method. The oxynitride-based fluorescent material may also include at least one kind of element selected from Li, Na, K, Rb, Cs, Mn, Re, Cu, Ag and Au. Emission efficiency such as quantum efficiency can be controlled by adding these elements. Other elements may also be included to such an extent that does not affect the property.

Part of the group II elements included in the oxynitride-based fluorescent material is substituted with the activator R. Molar ratio of the group II element plus activator R and the activator R is preferably such that (sum of group II element and activator R): (the activator R)=1:0.001−1:0.8. Denoting molar number of the group II element included in 1 mole of oxynitride-based fluorescent material as A and molar number of the activator R as B, molar ratio of the group II element plus activator R and the activator R is given as (A+B): B.

L is at least one kind of group II element selected from the group consisting of Mg, Ca, Sr, Ba and Zn or other element may be used individually, or the elements may be used in various combinations such as Ca and Sr, Ca and Ba, Sr and Ba, or Ca and Mg. Proportions of mixture of Sr and Ca can be changed as required. It is particularly preferable that L is at least one kind of group II element selected from the group consisting of Mg, Ca, Sr, Ba and Zn, and contains one of Ca, Sr and Ba as essential component.

M is at least one kind of group IV element selected from the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf. Si, Ge or other element may be used individually, or the elements may be used in various combinations such as Si and Ge, Si and C. In this way, low cost fluorescent material having high crystallinity can be obtained. It is preferable that M is at least one kind of group IV element selected from the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf, and contains Si as essential component.

The activator R is preferably a rare earth element. Specifically, R is Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu. Among these, R is preferably La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lr. Among these rare earth elements, Eu is particularly preferable. A mixture that contains Eu and at least one element selected from rare earth elements may also be used. The activator R is preferably at least two kinds selected from rare earth elements Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu, and contains Eu as essential component. Elements other than Eu act as co-activator. R preferably contains 70% by weight or more, more preferably 50% by weight or more of Eu.

It is preferable that the luminescence center contains europium Eu which is a rare earth element. Though description in this specification deals mainly with cases of using Eu, the present invention is not limited to this constitution, and co-activation with Eu may also be used. Europium has main energy levels, divalent and trivalent. Eu²⁺ is used as the activator for the fluorescent material based on alkali earth metal silicon nitrate. Eu²⁺ is easily oxidized and is commercialized in the trivalent form of Eu₂O₃.

Particularly the activator R preferably comprises Eu as first activator and at least one element selected from the group consisting of Y, Ce, Nd, Sm, Gd, Tb, Dy, Er, Tm, Yb and Lu as second activator. It is more preferable that the activator R comprises Eu as the first activator and at least one element selected from the group consisting of Dy, Tm and Yb as the second activator. The second activator has an effect of accelerating he growth of particles as well as the activating effect, and therefore improves the luminance of light emission.

Part of the group II elements included in the oxynitride-based fluorescent material is substituted with the first activator and the second activator. Proportion of the second activator is preferably in a range from 0.0005 to 0.1 in molar ratio to the sum of the group II elements, the first activator and the second activator. That is, (sum of group II elements, first activator R₁ and second activator R₂): (second activator R₂)=1:0.0005−1:0.1. In case the second activator is Yb, in particular, molar ratio of the second activator to the sum of the group II elements, the first activator and Yb is preferably in a range from 0.001 to 0.05. In case the second activator is Tm, molar ratio of the second activator to the sum of the group II elements, the first activator and Tm is preferably in a range from 0.001 to 0.05. In case the second activator is Dy, molar ratio of the second activator to the sum of the group II elements, the first activator and Dy is preferably in a range from 0.001 to 0.06.

Major components L and M of the base material may be provided in the form of the compound thereof. Metals, oxides, imide, amide, nitrides or various salts may be used as L and M. Alternatively, elements of the major components L and M may be mixed in advance and used.

Q is at least one kind of group III element selected from the group consisting of B, Al, Ga and In. Q may also be provided in the form of metal, oxide, imide, amide, nitride or various salts, such as B₂O₆, H₃BO₃, Al₂O₃, Al(NO₃)₃.9H₂O, AlN, GaCl₃, and InCl₃.

Nitride of L, nitride of M and oxide of M are mixed as the base material. Oxide of Eu is mixed as activator to the base material. Predetermined quantities of these components are metered and mixed to make a uniform mixture. Nitride of L, nitride of M and oxide of M to make the base material are preferably mixed in molar ratios of 0.25<nitride of L<1.75 (more preferably 0.5<nitride of L<1.5), 0.25<nitride of M<1.75 and 2.25<oxide of M<3.75. Predetermined quantities of these components are metered and mixed so that the composition of L_(X)M_(Y)O_(Z)N_(((2/3)X+(4/3)Y−(2/3)Z−α)):R or L_(X)M_(Y)Q_(T)O_(Z)N_(((2/3)X+(4/3)Y+T−(2/3)Z−α)):R is obtained.

The oxynitride-based fluorescent material preferably contains a trace of B and/or C. This enables it to reduce the duration of afterglow of the oxynitride-based fluorescent material. Concentration of B is preferably higher than 0 ppm, more preferably 5 ppm or higher and most preferably 10 ppm or higher, while being preferably 1000 ppm or lower, more preferably 500 ppm or lower and most preferably 400 ppm or lower. Too high a content of B decreases the luminance of light emission and insufficient content of B leads to longer afterglow.

Concentration of C is preferably higher than 0 ppm, more preferably 5 ppm or higher and most preferably 10 ppm or higher, while being preferably 500 ppm or lower, more preferably 300 ppm or lower and most preferably 200 ppm or lower. Too high a content of C decreases the luminance of light emission and insufficient content of C leads to longer afterglow.

Oxynitride-based fluorescent material will now be described below by way of specific examples.

[SrSi₂O₂N₂:Eu]

Examples of oxynitride-based fluorescent material using SrSi₂O₂N₂:Eu will be described. Table 3 and Table 4 show the light emission characteristics of SrSi₂O₂N₂:Eu of various proportions of Eu. TABLE 3 Ex = 400 nm Proportion Color Color Emission Energy Quantum of Eu tone tone luminance efficiency efficiency x x y Y (%) E (%) Q (%) Example 1 0.01 0.333 0.614 81.0 81.7 81.0 Example 2 0.015 0.340 0.612 87.2 87.8 87.3 Example 3 0.02 0.341 0.612 95.1 95.5 94.9 Example 4 0.025 0.345 0.609 97.3 97.5 96.9 Example 5 0.03 0.349 0.608 97.7 98.1 97.9 Example 6 0.035 0.356 0.604 100.0 100.0 100.0 Example 7 0.04 0.356 0.604 97.9 98.4 98.5 Example 8 0.045 0.363 0.600 97.4 97.7 97.9 Example 9 0.05 0.367 0.598 95.4 95.8 96.2 Example 10 0.07 0.378 0.590 89.0 90.1 91.2 Example 11 0.08 0.387 0.584 89.6 91.1 92.4 Example 12 0.1 0.394 0.579 87.3 89.5 91.4 Example 13 0.12 0.405 0.571 85.5 88.1 90.4 Example 14 0.14 0.416 0.562 84.8 88.8 91.5 Example 15 0.16 0.422 0.558 84.8 89.5 92.4 Example 16 0.18 0.425 0.556 79.9 84.3 87.0 Example 17 0.2 0.430 0.552 72.5 76.5 79.5 Example 18 0.22 0.438 0.546 71.7 76.3 79.5 Example 19 0.24 0.442 0.543 68.8 73.7 77.0 Example 20 0.26 0.446 0.539 61.1 66.2 69.2 Example 21 0.28 0.450 0.536 57.7 62.9 66.1 Example 22 0.3 0.449 0.537 48.3 52.9 55.4 Example 23 0.4 0.462 0.526 38.6 43.4 45.9 Example 24 0.5 0.471 0.519 31.0 35.7 38.0 Example 25 0.6 0.476 0.514 23.0 26.9 28.7 Example 26 0.7 0.482 0.508 16.6 20.2 21.8

TABLE 4 Ex = 460 nm Proportion Color Color Emission Energy Quantum of Eu tone tone luminance efficiency efficiency x x y Y (%) E (%) Q (%) Example 1 0.01 0.334 0.623 59.6 57.4 55.0 Example 2 0.015 0.339 0.620 67.0 64.6 62.2 Example 3 0.02 0.340 0.621 81.5 78.0 75.0 Example 4 0.025 0.343 0.618 83.2 79.8 77.0 Example 5 0.03 0.347 0.616 84.3 81.0 78.1 Example 6 0.035 0.352 0.614 94.1 89.8 86.7 Example 7 0.04 0.354 0.612 91.2 87.4 84.5 Example 8 0.045 0.358 0.610 96.3 92.2 89.2 Example 9 0.05 0.363 0.607 96.6 92.7 89.9 Example 10 0.07 0.375 0.597 97.1 94.0 92.0 Example 11 0.08 0.380 0.593 97.7 95.0 93.0 Example 12 0.1 0.390 0.586 97.4 95.4 94.2 Example 13 0.12 0.400 0.578 100.0 98.5 97.9 Example 14 0.14 0.408 0.571 99.6 99.1 98.7 Example 15 0.16 0.414 0.566 99.4 100.0 100.0 Example 16 0.18 0.417 0.564 95.2 95.9 96.0 Example 17 0.2 0.424 0.559 89.3 90.2 90.8 Example 18 0.22 0.430 0.555 91.5 93.4 94.2 Example 19 0.24 0.434 0.551 87.0 89.1 90.1 Example 20 0.26 0.438 0.547 78.2 81.0 82.1 Example 21 0.28 0.441 0.545 73.9 77.0 78.3 Example 22 0.3 0.441 0.545 61.4 63.6 64.6 Example 23 0.4 0.453 0.535 53.3 56.3 57.7 Example 24 0.5 0.460 0.529 43.7 46.9 48.4 Example 25 0.6 0.466 0.524 33.6 36.6 37.8 Example 26 0.7 0.471 0.518 23.4 26.5 27.6

Luminance of light emission, energy efficiency and quantum efficiency of the fluorescent materials of the examples are shown in relative values with respect to those of the fluorescent material of example 6 that has the highest values of luminance of light emission, energy efficiency and quantum efficiency, measured by irradiating the fluorescent materials 1 to 26 by means of an excitation light source that emits light of wavelength around 400 nm. Luminance of light emission of the examples are shown in relative values with respect to those of the fluorescent material 13 that has the highest value of luminance of light emission, measured by irradiating the fluorescent materials 1 to 26 by means of an excitation light source that emits light of wavelength around 460 nm. Energy efficiency and quantum efficiency of the examples are shown in relative values with respect to those of the fluorescent material 15 that has the highest values of energy efficiency and quantum efficiency, measured by irradiating of the fluorescent materials 1 to 26.

SrSi₂O₂N₂:Eu was produced as follows.

Sr₃N₂, Si₃N₄, SiO₂, and Eu₂O₃ were used as the stock materiasl which were crushed to particle size from 0.1 to 3.0 μm. Crushed materials of the quantities shown in table were weighed. Since a part of Sr is substituted by Eu, the composition becomes Sr_((1−X))Eu_(X)Si₂O₂N₂ (0<X<1). Predetermined quantities of Sr₃N₂, Si₃N₄, SiO₂, and Eu₂O₃ were mixed in nitrogen atmosphere in a globe box to make a uniform mixture.

Molar ratios of the elements included in the fluorescent material 5 are Sr:Si:O:Eu=0.97:2:2:0.03. Sr₃N₂, Si₃N₄, SiO₂, and Eu₂O₃ were weighed and mixed in these proportions. Sr concentration and mix proportion of Eu in the composition Sr_((1−X))Eu_(X)Si₂O₂N₂ of the fluorescent materials 1 to 26 were controlled so that the predetermined molar ratio could be obtained. Mix proportion of Eu shown in the table indicates the molar ratio of Eu.

Mixture of the compounds described above was put into a crucible made of boron nitride in ammonia atmosphere, and fired for about 5 hours at about 1500° C., thereby making the desired oxynitride-based fluorescent material. Theoretical composition of the oxynitride-based fluorescent material thus obtained is Sr_((1−X))Eu_(X)Si₂O₂N₂ (0<X<1) from the mix proportions of the stock materials.

Measurement of O and N contents in the oxynitride-based fluorescent material of the fluorescent material 5 showed that 15.3% by weight of O and 10.1% by weight of N were included. Weight ratio of O and N was O:N=1:0.66. The oxynitride-based fluorescent material shown in the table was fired in ammonia atmosphere in a crucible made of boron nitride. Use of a crucible made of a metal is not desirable. When a crucible made of Mo is used, the crucible will be eroded resulting in a deterioration in the light emission characteristics. Fluorescent materials 1 to 26 that have been fired are all crystalline powder or granular material having particle sizes roughly in a range from 1 to 10 μm.

Excitation spectra of the fluorescent materials 1 to 26 were measured. FIG. 8 shows the normalized excitation spectrum of SrSi₂O₂N₂:Eu. As can be seen from FIG. 8, the fluorescent materials are excited strongly in a wavelength region from 250 nm to 490 nm.

Results of exciting the fluorescent materials 1 to 26 with Ex=400 nm are shown in Table 3. The oxynitride-based fluorescent material of fluorescent material 1 emits light in yellow-green region with chromaticity coordinates of x=0.333 and y=0.614. The oxynitride-based fluorescent material of fluorescent material 6 emits light in yellow-green region with chromaticity coordinates of x=0.356 and y=0.604. As the proportion of Eu is increased, chromaticity coordinate x shifts toward the right and y shifts downward. Luminance of light emission gradually increased as the proportion of Eu was increased, showing the highest value with the composition of fluorescent material 6. As the proportion of Eu was increased further, luminance of light emission decreased. Quantum efficiency, on the other hand, gradually increased as the proportion of Eu was increased, showing the highest value with the composition of fluorescent material 6. As the proportion of Eu was increased further, quantum efficiency decreased. In the fluorescent materials 1 to 17, the oxynitride-based fluorescent material can emit light of the desired color tone while maintaining high luminance of light emission and high quantum efficiency.

Results of exciting the oxynitride-based fluorescent material of the fluorescent materials 1 to 26 with Ex=460 nm are shown in Table 4. This excitation wavelength was employed since Ex=460 nm is commonly used in blue light emitting devices. The oxynitride-based fluorescent material of fluorescent material 1 emits light in yellow-green region with chromaticity coordinates of x=0.334 and y=0.623. As the proportion of Eu is increased, chromaticity coordinate x shifts toward the right and y shifts downward. The oxynitride-based fluorescent material of fluorescent material 13 emits light in yellow-green region with chromaticity coordinates of x=0.400 and y=0.578. Luminance of light emission gradually increased as the proportion of Eu was increased, showing the highest value with the composition of fluorescent material 13. As the proportion of Eu was increased further, luminance of light emission decreased. Quantum efficiency, on the other hand, gradually increased as the proportion of Eu was increased, showing the highest value with the composition of fluorescent material 15. As the proportion of Eu was increased further, quantum efficiency decreased. In the fluorescent materials 2 to 21, the oxynitride-based fluorescent material can emit light of the desired color tone while maintaining high luminance of light emission and high quantum efficiency.

The oxynitride-based fluorescent material of the fluorescent materials 1 to 26 showed very good temperature characteristic which is given as relative luminance in percentage of luminance of light emission at 25° C. Particle size was measured by air permeation method called F.S.S.S.No. (Fischer Sub Sieve Sizer's No.). The fluorescent materials 1 to 26 showed temperature characteristic of 85% or higher at 100° C. and 55% or higher at 200° C.

X-ray diffraction images of the oxynitride-based fluorescent material described above all showed sharp diffraction patterns, proving that the fluorescent materials were crystalline compounds having ordered structure. These materials had orthorhombic crystal structure.

[CaSi₂O₂N₂:Eu]

Examples of oxynitride-based fluorescent material using CaSi₂O₂N₂:Eu will now be described. Table 5 and Table 6 show the light emission characteristics of CaSi₂O₂N₂:Eu of various proportions of Eu. TABLE 5 Ex = 400 nm Proportion Color Color Emission Energy Quantum of Eu tone tone luminance efficiency efficiency x x y Y (%) E (%) Q (%) Example 27 0.01 0.422 0.549 99.4 98.7 98.5 Example 28 0.02 0.428 0.546 100.0 100.0 100.0 Example 29 0.03 0.433 0.543 94.1 94.6 95.0 Example 30 0.06 0.444 0.536 76.5 78.7 79.6 Example 31 0.09 0.451 0.530 69.5 72.7 74.1 Example 32 0.12 0.456 0.526 72.7 77.2 78.8 Example 33 0.15 0.460 0.524 72.9 77.2 79.0 Example 34 0.2 0.464 0.522 77.1 81.7 83.7 Example 35 0.3 0.473 0.516 76.6 82.0 84.3 Example 36 0.4 0.485 0.506 67.8 76.0 79.0 Example 37 0.5 0.499 0.494 65.4 76.2 79.9 Example 38 0.6 0.502 0.492 45.1 51.7 53.9 Example 39 0.7 0.500 0.494 45.8 51.9 54.1 Example 40 0.8 0.497 0.496 26.9 30.2 31.4

TABLE 6 Ex = 460 nm Proportion Color Color Emission Energy Quantum of Eu tone tone luminance efficiency efficiency x x y Y (%) E (%) Q (%) Example 27 0.01 0.427 0.551 72.1 68.2 66.5 Example 28 0.02 0.431 0.549 82.1 78.0 76.4 Example 29 0.03 0.435 0.546 81.1 77.4 76.0 Example 30 0.06 0.442 0.541 72.1 70.0 69.2 Example 31 0.09 0.447 0.537 68.5 67.5 66.9 Example 32 0.12 0.450 0.533 74.6 74.2 73.9 Example 33 0.15 0.454 0.531 83.5 83.0 82.5 Example 34 0.2 0.457 0.529 95.0 94.4 94.0 Example 35 0.3 0.464 0.524 100.0 100.0 100.0 Example 36 0.4 0.475 0.514 86.0 89.6 90.6 Example 37 0.5 0.488 0.502 88.2 94.7 96.5 Example 38 0.6 0.492 0.500 58.3 61.9 63.1 Example 39 0.7 0.490 0.501 56.8 60.1 60.9 Example 40 0.8 0.486 0.505 33.9 35.5 35.9

Luminance of light emission, energy efficiency and quantum efficiency of the fluorescent materials of the examples are shown in relative values with respect to those of the fluorescent material of example 28 that has the highest values of luminance of light emission, energy efficiency and quantum efficiency, measured by irradiating the fluorescent materials 27 to 40 by means of an excitation light source emitting light of wavelength around 400 nm. Luminance of light emission, energy efficiency and quantum efficiency of the fluorescent materials of the examples are shown in relative values with respect to those of the fluorescent material of example 35 that has the highest values of luminance of light emission, energy efficiency and quantum efficiency, measured by irradiating the fluorescent materials 27 to 40 by means of an excitation light source emitting light of wavelength around 460 nm.

CaSi₂O₂N₂:Eu was produced as follows.

Ca₃N₂, Si₃N₄, SiO₂, and Eu₂O₃ were used as the stock materials which were processed in the predetermined molar ratios to produce the oxynitride-based fluorescent material of the fluorescent materials 27 to 40 in a process similar to that for the fluorescent material 1. Theoretical composition of the oxynitride-based fluorescent material thus obtained is Ca_((1−X))Eu_(X)Si₂O₂N₂ (0<X<1). A part of Ca is substituted by Eu. Mix proportion of Eu shown in the table indicates the molar ratio of Eu.

Measurement of O and N contents in the oxynitride-based fluorescent material of the fluorescent material 28 showed that 19.5% by weight of O and 17.5% by weight of N were included. Weight ratio of O and N was O:N=1:0.90. Fluorescent materials 27 to 40 that have been fired are all crystalline powder or granular material having particle sizes roughly in a range from 1 to 10 μm.

Excitation spectra of the oxynitride-based fluorescent materials 27 to 40 were measured. FIG. 9 shows the normalized excitation spectrum of oxynitride-based fluorescent material (CaSi₂O₂N₂:Eu). As can be seen from FIG. 9, the fluorescent materials are excited strongly in a wavelength region from 250 nm to 520 nm.

Results of exciting the oxynitride-based fluorescent material of the fluorescent materials 27 to 40 with Ex=400 nm are shown in Table 5. The oxynitride-based fluorescent material of fluorescent material 28 emits light in yellow-green region with chromaticity coordinates of x=0.428 and y=0.546. The oxynitride-based fluorescent material of fluorescent material 27 emits light in yellow-green region with chromaticity coordinates of x=0.422 and y=0.549. As the proportion of Eu is increased, chromaticity coordinate x shifts toward the right and y shifts downward. The fluorescent material 28 shows the highest values of luminance of light emission, energy efficiency and high quantum efficiency. In the fluorescent materials 27 to 37, the oxynitride-based fluorescent material can emit light of the desired color tone while maintaining high luminance of light emission and high quantum efficiency.

Results of exciting the oxynitride-based fluorescent material of the fluorescent materials 27 to 40 with Ex=460 nm are shown in Table 6. This excitation wavelength was employed since Ex=460 nm is commonly used in blue light emitting devices. The oxynitride-based fluorescent material of fluorescent material 35 emits light in yellow region with chromaticity coordinates of x=0.464 and y=0.524. As the proportion of Eu is increased, chromaticity coordinate x shifts toward the right and y shifts downward in the chromaticity diagram. As the proportion of Eu was increased, luminance of light emission, energy efficiency and quantum efficiency gradually increased, and the luminance of light emission showed the highest value with the composition of the fluorescent material 35. As the proportion of Eu was increased further, quantum efficiency decreased. In the fluorescent materials 27 to 39, the oxynitride-based fluorescent material can emit light of the desired color tone while maintaining high luminance of light emission and high quantum efficiency.

X-ray diffraction images of the oxynitride-based fluorescent material described above all showed sharp diffraction patterns, proving that the fluorescent material were crystalline compounds having ordered structure. These materials had orthorhombic crystal structure.

[BaSi₂O₂N₂:Eu]

Examples of oxynitride-based fluorescent material using BaSi₂O₂N₂:Eu will now be described. Table 7 and Table 8 show the light emission characteristics of BaSi₂O₂N₂:Eu of various proportions of Eu. TABLE 7 Ex = 400 nm Proportion Emission Color Color Peak Emission Energy Quantum of Eu peak tone tone intensity luminance efficiency efficiency x (nm) x y (nm) Y (%) E (%) Q (%) Example 41 0.01 495 0.090 0.458 100.3 90.8 96.6 96.0 Example 42 0.02 496 0.101 0.485 100.0 100.0 100.0 100.0 Example 43 0.03 497 0.116 0.507 90.1 102.3 96.0 96.5 Example 44 0.04 498 0.113 0.504 89.2 95.7 92.1 92.6 Example 45 0.05 499 0.132 0.521 83.6 102.9 92.9 94.1 Example 46 0.1 498 0.247 0.477 22.5 54.4 42.3 45.0 Example 47 0.15 518 0.289 0.556 8.4 40.3 23.7 25.5 Example 48 0.2 531 0.317 0.599 5.7 27.7 14.2 15.3

TABLE 8 Ex = 460 nm Proportion of Eu Emission peak Peak intensity x (nm) (nm) Example 41 0.01 495 95.2 Example 42 0.02 496 100.0 Example 43 0.03 498 94.2 Example 44 0.04 498 96.7 Example 45 0.05 499 93.3 Example 46 0.1 500 28.2 Example 47 0.15 504 9.1 Example 48 0.2 536 4.0

Peak emission intensity, luminance of light emission, energy efficiency and quantum efficiency of the fluorescent materials of the examples are shown in relative values with respect to those of the fluorescent material of example 42, measured by irradiating the fluorescent materials 41 to 48 by means of an excitation light source that emits light of wavelength around 400 nm. Peak emission intensities of the fluorescent materials are shown in relative values with respect to that of the fluorescent material 42, measured by irradiating the fluorescent materials 41 to 48 by means of an excitation light source that emits light of wavelength around 460 nm.

BaSi₂O₂N₂:Eu was produced as follows.

Ba₃N₂, Si₃N₄, SiO₂, and Eu₂O₃ were used as the stock materials which were processed in the predetermined molar ratios to produce the oxynitride-based fluorescent material of the fluorescent materials 41 to 48 in a process similar to that for the fluorescent material 1. Theoretical composition of the oxynitride-based fluorescent material thus obtained is Ba_((1−X))Eu_(X)Si₂O₂N₂ (0<X<1). A part of Ba is substituted by Eu. Mix proportion of Eu shown in the table indicates the molar ratio of Eu.

Measurement of O and N contents in the oxynitride-based fluorescent material of the fluorescent material 42 showed that 11.3% by weight of O and 10.6% by weight of N were included. Weight ratio of O and N was O:N=1:0.94. Fluorescent materials 41 to 48 that have been fired are all crystalline powder or granular material having particle sizes roughly in a range from 1 to 10 μm.

Excitation spectra of the oxynitride-based fluorescent material of the fluorescent materials 42 to 48 were measured. FIG. 10 shows the normalized excitation spectrum of oxynitride-based fluorescent material (BaSi₂O₂N₂:Eu). As can be seen from figure, the fluorescent materials are excited strongly in a wavelength region from 250 nm to 480 nm and beyond.

Results of exciting the oxynitride-based fluorescent material of the fluorescent materials 41 to 48 with Ex=400 nm are shown in Table 7. The oxynitride-based fluorescent material of fluorescent material 42 emits light in green region with chromaticity coordinates of x=0.101 and y=0.485. The oxynitride-based fluorescent material of fluorescent material 45 emits light in green region with chromaticity coordinates of x=0.132 and y=0.521. As the proportion of Eu is increased, chromaticity coordinate x shifts toward the right and y shifts upward. The fluorescent material 45 shows the highest value of luminance of light emission, while the fluorescent material 42 shows the highest values of energy efficiency and high quantum efficiency. In the fluorescent materials 41 and 45, the oxynitride-based fluorescent material can emit light of the desired color tone while maintaining high luminance of light emission and high quantum efficiency.

Results of exciting the oxynitride-based fluorescent material of the fluorescent materials 41 to 48 with Ex=460 nm are shown in Table 8. This excitation wavelength was employed since Ex=460 nm is commonly used in blue light emitting elements. The oxynitride-based fluorescent material of fluorescent material 42 has the highest peak intensity.

The oxynitride-based fluorescent material of the fluorescent materials 41 to 48 showed very good temperature characteristic. The fluorescent materials 41 to 48 showed temperature characteristic of 90% or higher at 100° C. and 65% or higher at 200° C. X-ray diffraction images of the oxynitride-based fluorescent material described above all showed sharp diffraction patterns, proving that the fluorescent material were crystalline compounds having ordered structure. These materials had orthorhombic crystal structure.

[BaSi₂O₂N₂:Eu supplemented with B]

Table 9 shows the performance of examples wherein B was added to BaSi₂O₂N₂:Eu (Nos. 1 to 10 of fluorescent materials 42). Luminance of light emission, energy efficiency and quantum efficiency of the fluorescent materials of the examples are shown in relative values with respect to those of the fluorescent material of example 42 No.1, measured by irradiating the fluorescent materials by means of excitation light sources that emit light of wavelengths around 400 nm and 460 nm. TABLE 9 EX = 400 nm EX = 460 nm Median Emission Color Color Emission Energy Quantum Emission Peak particle Concentration peak tone tone luminance efficiency efficiency peak intensity size of B (ppm) (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Example 42-1 <10 494 0.087 0.450 100.0 100.0 100.0 494 100.0 10.74 Example 42-2 25 494 0.082 0.445 96.6 96.1 96.0 494 96.6 11.49 Example 42-3 52 494 0.080 0.440 100.3 99.4 99.5 494 98.5 11.12 Example 42-4 94 494 0.085 0.444 103.5 101.3 101.4 494 92.6 9.69 Example 42-5 180 494 0.078 0.437 96.9 95.8 95.8 494 97.2 11.07 Example 42-6 290 495 0.091 0.455 108.1 100.9 101.3 494 87.8 9.61 Example 42-7 340 494 0.078 0.436 92.0 91.5 91.4 494 96.9 10.07 Example 42-8 1700 495 0.117 0.488 103.8 90.4 91.3 494 70.8 9.16 Example 42-9 3300 497 0.147 0.521 54.7 39.5 40.5 493 20.5 7.46 Example 42-10 6400 507 0.173 0.541 15.1 10.5 10.9 495 1.8 7.25

BaSi₂O₂N₂:Eu was produced as follows.

Ba₃N₂, Si₃N₄, SiO₂, Eu₂O₃ and H₃BO₃ were used as the stock materials which were processed in the predetermined molar ratios to produce the oxynitride-based fluorescent material of Nos.1 to 10 of the fluorescent materials 42 in a process similar to that for the fluorescent material 1. Theoretical composition of the oxynitride-based fluorescent material thus obtained is Ba_(0.98)Eu_(0.02)Si_(2−X)B_(X)O_(2+X)N_(2−X). Results of Nos.1 to 10 of the fluorescent materials 42 show that luminance of light emission when excited with Ex=400 nm and peak emission intensity when excited with Ex=460 nm decrease if the content of B is too high.

[BaSi₂O₂N₂:Eu, Ln]

As examples of fluorescent materials co-activated with Eu and other rare earth element will not be described by way of BaSi₂O₂N₂:Eu, Ln. Tables 10 to 20 show the light emission characteristics of BaSi₂O₂N₂ with various rare earth elements and Eu added as activators. Fluorescent materials Ln1 to Ln6 are examples of BaSi₂O₂N₂:Eu, Ln. Ln represents one kind of element selected from the group consisting of Yb, Tm, DY, Nd, Tb, Y, Sm, Er, Ce and Lu. Luminance of light emission, energy efficiency and quantum efficiency of the fluorescent materials are shown in relative values with respect to those of the fluorescent material Ln1, measured by irradiating the fluorescent materials Ln1 to Ln6 by means of an excitation light source that emits light of wavelength around 400 nm. Peak emission intensities of the fluorescent materials are shown in relative values with respect to that of the fluorescent material Ln1, measured by irradiating the fluorescent materials Ln1 to Ln6 by means of an excitation light source that emits light of wavelength around 460 nm. TABLE 10 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Yb1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Yb2 0.005 495 0.085 0.451 106.0 108.1 108.0 495 106.2 10.4 Yb3 0.01 494 0.079 0.446 102.8 105.3 105.1 495 107.5 11.5 Yb4 0.02 494 0.078 0.443 102.4 104.3 104.2 495 105.4 16.8 Yb5 0.04 494 0.077 0.445 91.6 91.6 91.7 495 99.7 18.1 Yb6 0.08 494 0.078 0.431 77.3 79.3 79.2 494 82.8 19.4

TABLE 11 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Tm1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Tm2 0.005 495 0.088 0.458 105.3 105.3 105.4 495 110.0 9.7 Tm3 0.01 495 0.079 0.449 102.5 102.5 104.4 495 112.1 11.1 Tm4 0.02 495 0.077 0.444 97.4 97.4 99.1 495 110.1 13.3 Tm5 0.04 494 0.079 0.437 85.4 85.4 86.7 494 96.1 13.6 Tm6 0.08 494 0.088 0.423 60.1 60.1 62.1 494 68.5 8.1

TABLE 12 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Dy1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Dy2 0.005 494 0.087 0.451 104.9 106.5 106.4 495 105.6 10.4 Dy3 0.01 494 0.082 0.444 105.5 108.2 108.0 495 107.5 11.5 Dy4 0.02 494 0.078 0.440 95.3 97.9 97.7 495 102.7 16.8 Dy5 0.04 494 0.078 0.440 96.5 98.2 98.2 495 104.6 18.1 Dy6 0.08 494 0.081 0.430 85.0 88.5 88.4 494 91.8 19.4

TABLE 13 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Nd1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Nd2 0.005 494 0.084 0.446 101.3 103.6 103.6 495 103.9 9.1 Nd3 0.01 494 0.078 0.440 97.5 99.9 99.6 495 100.8 10.3 Nd4 0.02 494 0.074 0.442 102.8 104.7 104.6 495 112.1 11.2 Nd5 0.04 495 0.074 0.445 102.5 102.6 102.7 495 112.4 14.8 Nd6 0.08 494 0.076 0.435 86.0 87.7 87.6 494 98.1 18.6

TABLE 14 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Gd1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Gd2 0.005 494 0.085 0.454 106.6 108.4 108.3 495 106.8 7.0 Gd3 0.01 494 0.077 0.444 105.1 108.6 108.2 495 107.5 9.2 Gd4 0.02 494 0.078 0.440 101.4 103.5 103.4 495 106.5 9.7 Gd5 0.04 494 0.081 0.441 92.3 92.6 92.7 495 100.6 11.8 Gd6 0.08 493 0.096 0.413 64.3 66.9 67.1 494 64.9 7.9

TABLE 15 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Tb1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Tb2 0.005 494 0.075 0.434 98.5 100.0 100.0 494 103.5 11.8 Tb3 0.01 494 0.076 0.435 95.8 100.1 99.9 494 103.6 11.9 Tb4 0.02 494 0.076 0.436 96.4 98.9 98.9 494 105.5 12.4 Tb5 0.04 494 0.079 0.438 97.5 98.2 98.2 495 107.8 16.5 Tb6 0.08 495 0.088 0.455 100.9 103.5 103.9 496 118.1 13.1

TABLE 16 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Y1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Y2 0.005 495 0.077 0.453 94.7 103.4 102.8 496 123.9 11.8 Y3 0.01 495 0.078 0.452 99.8 105.5 105.2 495 120.0 10.5 Y4 0.02 494 0.080 0.444 87.2 95.0 94.7 495 112.0 10.5 Y5 0.04 494 0.083 0.434 70.0 78.4 78.3 495 93.2 8.8 Y6 0.08 494 0.083 0.440 100.2 104.8 104.7 494 106.6 11.2

TABLE 17 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Sm1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Sm2 0.005 494 0.077 0.437 91.6 99.1 98.6 495 100.8 9.2 Sm3 0.01 494 0.075 0.438 96.5 102.5 102.0 495 105.4 9.4 Sm4 0.02 494 0.075 0.442 102.6 106.0 105.7 495 111.6 12.6 Sm5 0.04 495 0.075 0.449 96.8 97.0 97.0 495 105.5 18.1 Sm6 0.08 494 0.077 0.440 78.1 79.1 79.0 494 91.9 22.8

TABLE 18 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Er1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Er2 0.005 494 0.074 0.440 115.9 116.9 116.9 495 118.9 11.6 Er3 0.01 495 0.078 0.447 111.5 114.2 113.9 495 118.1 12.8 Er4 0.02 494 0.077 0.434 96.0 99.6 99.4 495 107.2 14.9 Er5 0.04 494 0.081 0.425 90.3 93.8 93.8 494 98.1 14.3 Er6 0.08 494 0.081 0.419 87.9 97.2 96.7 495 98.1 12.8

TABLE 19 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Ce1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Ce2 0.005 494 0.076 0.443 113.6 113.8 113.6 495 113.7 9.7 Ce3 0.01 494 0.077 0.440 97.2 101.3 101.0 495 111.6 10.6 Ce4 0.02 494 0.076 0.442 106.9 109.3 109.2 495 111.5 10.3 Ce5 0.04 494 0.078 0.442 99.0 99.9 99.9 495 110.5 15.0 Ce6 0.08 494 0.084 0.438 75.5 80.9 80.7 494 93.8 13.7

TABLE 20 EX = 400 nm EX = 460 nm Median Proportion Emission Color Color Emission Energy Quantum Emission Peak particle of Ln peak tone tone luminance efficiency efficiency peak intensity size y (nm) x y Y (%) E (%) Q (%) (nm) (nm) Dm Lu1 0 494 0.090 0.456 100.0 100.0 100.0 495 100.0 8.0 Lu2 0.005 494 0.074 0.436 102.5 104.1 104.0 494 108.0 13.4 Lu3 0.01 494 0.075 0.436 97.9 102.6 102.3 494 106.6 13.5 Lu4 0.02 494 0.077 0.427 86.0 89.7 89.5 494 95.8 14.4 Lu5 0.04 493 0.079 0.421 83.5 86.9 86.8 494 90.3 14.0 Lu6 0.08 494 0.086 0.440 96.0 102.1 102.2 495 110.2 12.9

Ba₃N₂, Si₃N₄, SiO₂, Eu₂O₃ and one kind selected from among the group consisting of Yb₂O₃, Tm₂O₃, Dy₂O₃, Nd₂O₃, Gd₂O₃, Tb₄O₇, Y₂O₃, Sm₂O₃, Er₂O₃, CeO₃, and Lu₂O₃ were used as the stock materials which were processed in the predetermined molar ratios to produce the oxynitride-based fluorescent material of the fluorescent materials Ln1 to Ln6 in a process similar to that for the fluorescent material 1. Theoretical composition of the oxynitride-based fluorescent material thus obtained is Ba_((0.08−y))Eu_(0.02)Ln_(y)Si₂O₂N₂.

Results of the fluorescent materials Ln1 to Ln6 show that particle size increases and luminance of light emission and peak intensity improve when the proportion of Ln increases. It can also be seen that luminance of light emission and peak intensity decrease when the proportion of Ln becomes too high.

<Method of Producing Oxynitride-Based Fluorescent Material>

(1) Method of Producing L_(X)M_(Y)O_(Z)N_(((2/3)X+(4/3)Y−(2/3)Z)):R

[SrSi₂O₂N₂:Eu]

Now the method of producing the oxynitride-based fluorescent material will be described in detail by way of SrSi₂O₂N₂:Eu. It should be noted that the present invention is not limited to this method. FIG. 11 shows the method of producing the oxynitride-based fluorescent material.

Nitride of Sr, nitride of Si, oxide of Si and oxide of Eu are mixed in predetermined proportions. Nitride of Sr, nitride of Si, oxide of Si and oxide of Eu are prepared beforehand. While it is preferable to refine these materials, commercialized materials may also be used.

First, nitride of Sr is crushed (P1). As the nitride of Sr, Sr₃N₂ may be used. Alternatively, compounds such as imide compound, amide compound or oxide may also be used. The Sr compound used as the stock material may include B, Ga or the like.

Then nitride of Si is crushed (P2). As the nitride of Si, Si₃N₄ is preferably used. Alternatively, simple substance, nitride, imide compound or amide compound may also be used, such as Si(NH₂)₂, Mg₂Si, Ca₂Si or SiC. While purity of Si in the stock material is preferably 3N or higher, it may include B, Ga or the like.

Then oxide of Si (SiO₂) is crushed (P3). As the oxide of Si, SiO₂ is preferably used. Commercialized material (Silicon Dioxide 99.9%, 190-09072 manufactured by Wako Pure Chemicals Industries, Ltd.) is used in this case.

Then oxide of Eu is crushed (P4). As the oxide of Eu, Eu₂O₂ is preferably used. Alternatively, nitride, imide compound or amide compound may also be used. Besides europium oxide, use of europium nitride is particularly preferable, because the product contains oxygen or nitride.

Nitride of Sr (Sr₃N₂), nitride of Si (Si₃N₄), oxide of Si (SiO₂) and oxide of Eu (Eu₂O₂) are weighed for predetermined molar ratios so as to obtain predetermined mix proportions, and are mixed (P5).

The mixture of nitride of Sr, nitride of Si, oxide of Si and oxide of Eu is put into a crucible and fired (P6). Firing the mixture produces the oxynitride-based fluorescent material having composition of SrSi₂O₂N₂:Eu (P7).

Reaction of producing the oxynitride-based fluorescent material by firing is represented by the reaction scheme 1. $\begin{matrix} \left. {{\left( \frac{1 - {2a}}{3} \right){Sr}_{3}N_{2}} + {\left( \frac{2 + {3a}}{6} \right){Si}_{3}N_{4}} + {\left( \frac{2 - {3a}}{2} \right){SiO}_{2}} + {{a{Eu}}_{2}O_{3}}}\rightarrow{{{Sr}_{({1 - {2a}})}{Eu}_{2a}{Si}_{2}O_{2}N_{2}} + {\frac{a}{3}N_{2}}} \right. & \left\lbrack {{Chemical}\quad{Formula}\quad 1} \right\rbrack \end{matrix}$ [CaSi₂O₂N₂ :Eu]

CaSi₂O₂N₂:Eu is produced similarly as follows. Nitride of Ca, nitride of Si, oxide of Si and oxide of Eu are mixed in predetermined proportions. Nitride of Ca, nitride of Si, oxide of Si and oxide of Eu are prepared beforehand. While it is preferable to refine these materials, commercialized materials may be used. Description herein begins with the process of producing nitrides of Ca and Si.

First, stock material Ca is crushed. While Ca is preferably supplied in the form of simple substance, compounds such as imide compound, amide compound or CaO may also be used. The stock material Ca may include B, Ga or the like. The stock material Ca is crushed in a glove box in argon atmosphere. Mean particle size of crushed Ca is preferably in a range from about 0.1 μm to 15 μm, but is not limited to this range. Purity of Ca is preferably 2N or higher, but is not limited to this level.

The stock material Ca is nitrided in nitrogen atmosphere. This reaction is represented by the reaction scheme 2. 3Ca+N₂→Ca₃N₂   [Chemical Formula 2]

Nitride of Ca can be made by nitriding Ca in nitrogen atmosphere at a temperature from 600 to 900° C. for 5 hours. Nitride of Ca is preferably of high purity, but commercialized material may also be used.

Nitride of Ca is crushed in a glove box in argon atmosphere or nitrogen atmosphere.

Stock material Si is crushed. While Si is preferably supplied in the form of simple substance, compounds such as nitride, imide compound, amide compound or the like may also be used, such as Si₃N₄, Si(NH₂)₂, Mg₂Si, Ca₂Si or SiC. While purity of stock material Si is preferably 3N or higher, it may include B, Ga or the like. Si is also crushed in a glove box in argon atmosphere or nitrogen atmosphere, similarly to the stock material Ca. Mean particle size of the Si compound is preferably in a range from about 0.1 μm to 15 μm.

The stock material Si is nitrided in nitrogen atmosphere. This reaction is represented by the reaction scheme 3. 3Si+2N₂→Si₃N₄   [Chemical Formula 3]

Silicon Si is also nitrided in nitrogen atmosphere at a temperature from 800 to 1200° C. for 5 hours thereby to obtain silicon nitride. Silicon nitride used in the present invention is preferably of high purity, but commercialized material may also be used.

Nitride of Si is crushed similarly.

For the oxide of Si (SiO₂), commercialized material (Silicon Dioxide 99.9%, 190-09072 manufactured by Wako Pure Chemicals Industries, Ltd.) is used.

The stock materials refine or produced as described above are weighed to predetermined molar ratios and mixed.

The mixture of nitride of Ca, nitride of Si, oxide of Si and oxide of Eu is put into a crucible and fired at about 1500° C. in ammonia atmosphere, thereby producing the oxynitride-based fluorescent material having composition of CaSi₂O₂N₂:Eu.

Reaction of producing the oxynitride-based fluorescent material by firing is represented by the reaction scheme 4. (⅓)Ca₃N₂+(⅓)Si₃N₄+SiO₂+aEu₂O₃→CaSi₂O₂N₂:Eu   [Chemical Formula 4]

The composition described above is a typical composition presumed from the proportions of mixing the materials, and a fluorescent material of a composition slightly different from the above composition has satisfactory properties for practical use. Composition of the fluorescent material obtained can be changed by changing the proportions of mixing the stock materials.

Firing can be done in a tubular furnace, compact furnace, induction furnace or metal furnace. While there is no limitation to the firing temperature, it is preferable to fire in a temperature range from 1200 to 1700° C., and more preferably from 1400 to 1700° C. Material to make the fluorescent material 11 is preferably fired in a crucible or boat made of boron nitride (BN). Besides a crucible made of boron nitride, a crucible made of alumina (Al₂O₃) may also be used. Reducing atmosphere is nitrogen atmosphere, nitrogen-hydrogen atmosphere, ammonia atmosphere, inert gas atmosphere such as argon or the like.

(2) Method of Producing L_(X)M_(Y)Q_(T)O_(Z)N_(((2/3)X+(4/3)Y+T−(2/3)Z)):R

Now the method of producing the oxynitride-based fluorescent material represented by L_(X)M_(Y)Q_(T)O_(Z)N_(((2/3)X+(4/3)Y+T−(2/3)Z)):R will be described by way of Sr_(X)Si_(Y)B_(T)O_(Z)N_(((2/3)X+(4/3)Y+T−(2/3)Z−α)):Eu as an example.

The method of producing Sr_(X)Si_(Y)B_(T)O_(Z)N_(((2/3)X+(4/3)Y−(2/3)Z−α)):Eu is similar to that for SrSi₂O₂N₂:Eu, but is different in that compound of B, H₃BO₃, is mixed with oxide of Eu in a dry process beforehand.

First, mixture of Eu and B is crushed. Mean particle size of the crushed mixture of Eu and B is preferably in a range from about 0.1 to 15 μm. Then similarly to the process of producing SrSi₂O₂N₂:Eu, nitride of Sr, nitride of Si, oxide of Si and oxide of Eu containing B are mixed and fired, thereby making the desired oxynitride-based fluorescent material.

Besides europium oxide, metal europium or europium nitride may also be used as the compound of Eu which is mixed with the compound of B. Imide compound or amide compound of Eu may also be used. While europium oxide is preferably of high purity, commercialized material may also be used. Compound of B is mixed in dry process, but wet process may also be employed. Since the mixture may be easily oxidized in some cases, it is preferable to mix the materials in Ar atmosphere, in nitrogen atmosphere or in a glove box.

Q in L_(X)M_(Y)Q_(T)O_(Z)N_(((2/3)X+(4/3)Y+T−(2/3)Z)):R may be Li, Na, K or the like instead of B, in which case a compound of such an element may be mixed with the compound of Eu instead of the compound of B. For example, such compounds may be used as LiOH.H₂O, Na₂CO₃, K₂CO₃, RbCl, Mg(NO₃)₂, CaCl₂.6H₂O, SrCl₂.6H₂O, BaCl₂.2H₂O, TiOO₄.H₂O, ZrO(NO₃)₂, HfCl₄, MnO₂, ReCl₅, Cu(CH₃COO)₂H₂O, AgNO₃, HAuCl₄.4H₂O, Zn(NO₃)₂.6H₂O, GeO₅, Sn (CH₃COO)₂.

<Nitride-Based Fluorescent Material>

Nitride-based fluorescent material is preferably alkaline earth silicate fluorescent material, and more preferably alkaline earth metal silicon oxynitride fluorescent material. For the alkaline earth metal silicon oxynitride fluorescent material, M₂Si₅N₈:Eu, MSi₇N₁₀:Eu, M_(1.8)Si₅O_(0.2)N:Eu, M_(0.9)Si_(7.0)O_(0.1)N₁₀:Eu (M is at least one element selected from Sr, Ca, Ba, Mg and Zn) may be used. The nitride-based fluorescent material preferably contains B in order to improve the luminance of light emission. Concentration of B (boron) is preferably in a range from 1 to 10000 ppm. Luminance of light emission can be improved more effectively by containing boron with concentration in this range.

The nitride-based fluorescent material is represented by a general formula L_(X)M_(Y)N_(((2/3)X+(4/3)Y)):R or L_(X)M_(Y)O_(Z)N_(((2/3)X+(4/3)Y−(2/3)Z)):R. L in this formula is at least one group II element selected from among the group consisting of Be, Mg, Ca, Sr, Ba and Zn. M is at least one group IV element selected from among the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf. R is at least one rare earth element selected from among the group consisting of Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er and Lu. X, Y and Z satisfy the relations 0.5≦X≦3, 1.5≦Y≦8 and 0<Z≦3. The nitride-based fluorescent material preferably contains B with concentration preferably in a range from 1 to 10000 ppm.

The nitride-based fluorescent material has a composition represented by general formula L_(X)M_(Y)N_(((2/3)X+(4/3)Y)):R or L_(X)M_(Y)O_(Z)N_(((2/3)X+(4/3)Y−(2/3)Z)):R wherein Mn or B is included with concentration from 1 to 10000 ppm. Boron may be added in the form of simple substance, boride, boron nitride, boron oxide, borate or the like.

L is at least one group II element selected from among the group consisting of Be, Mg, Ca, Sr, Ba and Zn. While Ca or Sr may be used individually, the elements may be used in combinations such as Ca and Sr, Ca and Mg, Ca and Ba or Ca, Sr and Ba, Such a composition may also be employed that contains either Ca or Sr and part of Ca or Sr is substituted by Be, Mg, Ba or Zn. When two or more elements are mixed, the proportions may be varied as required. Peak emission wavelength shifts to the longer side when Sr and Ca are mixed, compared to a case where either Sr or Ca is used. Peak emission wavelength shifts to the longer side when Sr and Ca are mixed with molar ratio of 7:3 or 3:7, compared to a case where only Sr or Ca is used. Peak emission wavelength shows maximum shift to the longer side when Sr and Ca are mixed with molar ratio of about 5:5.

M is at least one group IV element selected from among the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf. While Si may be used individually, combinations such as C and Si, Ge and Si, Zn and Si, Ge and Ti and Si may also be used. A part of Si may be substituted by C, Ge, Sn, Ti, Zr or Hf. When a mixture that contains Si as an indispensable element is used, the mix proportions may be varied as required. For example, 95% by weight of Si and 5% by weight of Ge may be mixed.

R is at least one kind of rare earth element selected from among the group consisting of Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb and Lu. While Eu may be used individually, combinations such as Ce and Eu, Pr and Eu, or La and Eu may also be used. Use of Eu as the activator, in particular, enables it to provide nitride-based fluorescent material that has peak emission wavelength in yellow to red region and excellent emission characteristics. Part of Eu may be substituted by other element for co-activation, so as to control the color tone and the emission characteristics. When a mixture that contains Eu as an indispensable element is used, the mix proportions may be varied as required. In the examples described below, europium Eu, a rare earth element, is manly used for the luminescence center. Europium has main energy levels, divalent and trivalent. Eu²⁺ is used as the activator for the fluorescent material based on alkaline earth metal silicon nitrate. Eu²⁺ is easily oxidized and is commercialized in the trivalent form of Eu₂O₃. However, it is difficult to obtain a satisfactory fluorescent material with the commercialized form of Eu₂O₃ because of excessive contribution of 0. Therefore, it is preferable to remove O from Eu₂O₃. For example, europium as simple substance or europium nitride is preferably used.

By adding boron, such effects can be achieved as acceleration of the diffusion of Eu²⁺ and improvements in luminance of light emission, energy efficiency and quantum efficiency. It is also made possible to increase the particle sizes and improve the emission characteristics. Similar effects can be achieved also by adding manganese. Composition of the nitride-based fluorescent material contains oxygen.

Specific examples of the nitride-based fluorescent material will now be described below. Excitation spectra of these nitride-based fluorescent materials will be described with reference to the drawings. FIG. 12 shows normalized excitation spectrum of nitride-based fluorescent material (Sr₂Si₅N₈:Eu). FIG. 13 shows normalized excitation spectrum of nitride-based fluorescent material (Ca₂Si₅N₈:Eu). FIG. 14 shows normalized excitation spectrum of nitride-based fluorescent material ((Ca, Sr)₂Si₅N₈:Eu).

[Ca_(0.97)Eu_(0.03))₂Si₅N_(8])

As an example of nitride-based fluorescent material, (Ca_(0.97)Eu_(0.03))₂Si₅N₈ will be described below. Table 21 shows the emission characteristics of (Ca_(0.97)Eu_(0.03))₂Si₅N₈ containing B with different concentrations. In Table 21, luminance of light emission and quantum efficiency are shown in relative values to the nitride-based fluorescent material of fluorescent material 49. Fluorescent materials 49 to 52 include Eu with concentration 0.03 times the molar concentration of Ca. TABLE 21 Concentration Color Color Emission Quantum of B tone tone luminance efficiency Example (ppm) x y (%) (%) 49 10 0.596 0.398 100 100 50 200 0.598 0.397 107 108 51 500 0.598 0.396 112 113 52 1000 0.598 0.396 110 112 (Ca_(0.97)Eu_(0.03))₂Si₅N₈ was made as follows.

First, stock material Ca was crushed to particle sizes from 1 μm to 15 μm, and was nitrided in nitrogen atmosphere. Then the nitride of Ca was crushed to particle sizes from 0.1 μm to 10 μm. 20 g of stock material Ca was weighted and was nitrided.

Similarly, stock material Si was crushed to particle sizes from 1 μm to 15 μm, and was nitrided in nitrogen atmosphere. Then the nitride of Si was crushed to particle sizes from 0.1 μm to 10 μm. 20 g of stock material Si was weighed and was nitrided.

Then Eu₂O₃ and H₃BO₃ were mixed in wet process. 20 g of Eu₂O₃ and a predetermined quantity of H₃BO₃ were weighed. After solving H₃BO₃, the solution was mixed with Eu₂O₃, and the mixture was dried. After drying, the mixture was fired in oxidation atmosphere at a temperature from 700 to 800° C. for 5 hours, thereby producing europium oxide with B added. The mixture of Eu and B was crushed to particle sizes from 0.1 μm to 10 μm.

Nitride of Ca, nitride of Si and the mixture of Eu and B were mixed in nitrogen atmosphere. Fluorescent materials 49 to 52 were prepared by adjusting the proportions of calcium nitride Ca₃N₂, silicon nitride Si₃N₄, and europium oxide Eu₂O₃ so that molar ratio of the elements becomes Ca:Si:Eu=1.94:5:0.06. Ca₃N₂, (molecular weight 148.26) and Si₃N₄ (molecular weight 140.31) were weighed and mixed with the mixture of Eu and B in the proportions described above. B was added in concentrations of 10 ppm, 200 ppm, 500 ppm and 1000 ppm.

The mixture was fired in a crucible in ammonia atmosphere by gradually raising the temperature from the room temperature and keeping at 1600° C. for about 5 hours and then gradually lowering the temperature to the room temperature. Element B that has been added generally remains in the fired material, but part of B may scatter during firing so that B is included with lower concentration in the final composition.

Luminance of light emission and quantum efficiency of the nitride-based fluorescent material of the fluorescent materials 49 to 52 are shown in relative values to those of the fluorescent material 49 in percentage. As can be seen from Table 21, both luminance of light emission and quantum efficiency showed high values when 10000 ppm or less B, especially 1 to 1000 ppm of B, was included.

Mean particle sizes of the fluorescent materials 49 to 52 were in a range from 6.3 to 7.8 μm. The fluorescent materials 49 to 52 included 0.5 to 1.2% by weight of oxygen. The nitride-based fluorescent materials of the fluorescent materials 49 to 52 were fired in a crucible made of boron nitride in ammonia atmosphere. The nitride-based fluorescent materials of the fluorescent materials 49 to 52 showed very good temperature characteristic. The nitride-based fluorescent material of the fluorescent material 51 showed temperature characteristic of 97% at 100° C. and 70% at 200° C. The nitride-based fluorescent materials of the fluorescent materials 49 to 52 have peak emission wavelengths at around 609 nm when excited by an excitation light source that emits light at 460 nm.

[(Sr_(0.97)Eu_(0.03))₂Si₅N₈]

As an example of nitride-based fluorescent material, (Sr_(0.97)Eu_(0.03))₂Si₅N₈ will be described below. Table 22 shows the emission characteristics of (Sr_(0.97)Eu_(0.03))₂Si₅N₈ containing B with different concentrations. In Table 22, luminance of light emission and quantum efficiency are shown in relative values to the nitride-based fluorescent material of fluorescent material 53. Fluorescent materials 53 to 58 include Eu with concentration 0.03 times the molar concentration of Sr. TABLE 22 Concentration Color Color Emission Quantum of B tone tone luminance efficiency Example (ppm) x y (%) (%) 53 10 0.618 0.375 100 100 54 100 0.619 0.374 104 107 55 200 0.620 0.373 105 109 56 500 0.618 0.376 106 105 57 1000 0.620 0.373 97 102 58 5000 0.625 0.368 95 110

Fluorescent materials 53 to 58 were made in substantially the same process as that for the fluorescent materials 49 to 52, except for using Sr instead of Ca used in the fluorescent materials 49 to 52 and firing at about 1350° C. unlike the fluorescent materials 49 to 52 that were fired at about 1600° C.

As can be seen from Table 22, both luminance of light emission and quantum efficiency showed high values when 10000 ppm or less B was included, particularly when B concentration was from 10 ppm to 5000 ppm. Mean particle sizes of the fluorescent materials 53 to 58 were in a range from 2.1 to 4.7 μm. Oxygen concentration was from 0.3 to 1.1% by weight.

Now examples with different firing temperature will be described below.

Table 23 shows the emission characteristics of (Sr_(0.97)Eu_(0.03))₂Si₅N₈ fired at a firing temperature different from that of the fluorescent materials 52 to 58. While the fluorescent materials 52 to 58 were fired at 1350° C., the fluorescent materials 59 to 63 were fired at about 1600° C. In Table 23, luminance of light emission and quantum efficiency are shown in relative values to the nitride-based fluorescent material of fluorescent material 59. Fluorescent materials 59 to 63 include Eu with concentration 0.03 times the molar concentration of Sr. TABLE 23 Concentration Color Color Emission Quantum of B tone tone luminance efficiency Example (ppm) x y (%) (%) 59 10 0.629 0.364 100 100 60 100 0.628 0.365 101 101 61 500 0.629 0.364 102 103 62 1000 0.628 0.365 98 98 63 5000 0.629 0.364 92 97

As can be seen from Table 23, both luminance of light emmision and quantum efficiency showed high values when 1000 ppm or less B was included, particularly when B concentration was from 10 ppm to 500 ppm. Mean particle sizes of the nitride-based fluorescent material of the fluorescent materials 59 to 63 were in a range from 3.2 to 3.9 μm.

<Method of Producing Nitride-Based Fluorescent Material>

Now the method of producing nitride-based fluorescent material Ca₂Si₅N₈:Eu that contains B will be described below, but the present invention is not limited to this method.

First, stock material Ca is crushed (P1l). The stock material Ca may be in the form of simple substance or compounds such as imide compound and amide compound.

The stock material Ca is nitrided in nitrogen atmosphere (P12). This reaction is represented by the reaction scheme 5. 3Ca+N₂→Ca₃N₂   [Chemical Formula 5]

Ca is nitrided in nitrogen atmosphere at a temperature from 600 to 900° C. for 5 hours, so as to obtain nitride of Ca. The nitride of Ca is then crushed (P13).

Meanwhile stock material Si is crushed (P14). The stock material Si may be supplied in the form of simple substance, nitride compound, imide compound or amide compound, such as Si₃N₄, Si(NH₂)₂ or Mg₂Si.

The stock material Si is nitrided in nitrogen atmosphere (P15). This reaction is represented by the reaction scheme 6. 3Si+2N₂→Si₃N₄   [Chemical Formula 6]

Si is also nitrided in nitrogen atmosphere at a temperature from 800 to 1200° C. for 5 hours, so as to obtain silicon nitride. The nitride of Si is then crushed (P16).

Then Eu₂O₃ and H₃BO₃ are mixed (P17). While europium oxide is used as the compound of Eu, metal europium or europium nitride may also be used. Imide compound or amide compound may also be used to supply Eu. Mixture of Eu₂O₃ and H₃BO₃ is fired in oxidizing atmosphere (P18). Mixture of Eu and B is crushed (P19). After crushing, nitride of Ca, nitride of Si and the mixture of Eu and B are mixed (P20). Processes P17 to P19 may be omitted so as to mix nitride of Ca, nitride of Si, Eu₂O₃ and H₃BO₃ in process P20.

Nitride of Ca, nitride of Si and the mixture of Eu and B are fired in ammonia atmosphere (P21), so as to make fluorescent material represented by Ca₂Si₅N₈:Eu containing B added thereto (P22). Reaction of forming this nitride-based fluorescent material by firing is represented by the reaction scheme 7. $\begin{matrix} \left. {{\frac{1.985}{3}{Ca}_{3}N_{2}} + {\frac{5}{3}{Si}_{3}N_{4}} + {\frac{0.015}{2}{Eu}_{2}O_{3}}}\rightarrow{{Ca}_{1.985}{Eu}_{0.015}{Si}_{5}N_{7.990}O_{0.0225}} \right. & \left\lbrack {{Chemical}\quad{Formula}\quad 7} \right\rbrack \end{matrix}$

Composition of the resultant fluorescent material can be changed by changing the mix proportions of the stock materials.

While firing can be carried out at temperatures from 1200 to 2000° C., firing temperature is preferably in a range from 1400 to 1800° C., in a reducing atmosphere that contains at least one kind selected from nitrogen, hydrogen, argon, carbon dioxide, carbon monoxide and ammonia. Firing may also be done in a reducing atmosphere other than the above.

The desired nitride-based fluorescent material can be obtained in the process described above.

<Other Fluorescent Material>

The fluorescent material 11 may also be made by combining an oxynitride-based fluorescent material and a nitride-based fluorescent material in such forms as alkaline earth metal halogen apatite fluorescent material, alkaline earth metal boric acid halide salt fluorescent material, alkaline earth metal aluminate fluorescent material, silicate of alkali earth element, rare earth oxysulfide, sulfide of alkaline earth element, alkaline earth thiogallate, alkaline earth silicon nitride or germanate that is activated mainly by lanthanoid element such as Eu or transition metal such as Mn, or rare earth aluminate or rare earth silicate activated mainly by lanthanoid element such as Ce, or at least one kind selected from organic material and organic complex activated mainly by lanthanoid element such as Eu. For example, the following fluorescent materials may be used, but the present invention is not limited to these examples.

Alkaline earth halogen apatite fluorescent materials activated mainly by lanthanoid element such as Eu or transition metal element such as Mn include M₅(PO₄)₃X:R (M is at least one kind selected from among Sr, Ca, Ba, Mg and Zn; X is at least one kind selected from among F, Cl, Br and I; and R is at least one kind selected from among Eu, Mn and combination of Eu and Mn).

Alkaline earth halogen apatite fluorescent materials activated mainly by lanthanoid element such as Eu or transition metal element such as Mn include M₁₀(PO₄)₆X₂:R(M is at least one kind selected from among Sr, Ca, Ba, Mg and Zn; X is at least one kind selected from among F, Cl, Br and I; and R is rare earth element containing Eu as indispensable element).

Alkaline earth metal boric acid halide salt fluorescent materials include M₂B₅O₉X:R (M is at least one kind selected from among Sr, Ca, Ba, Mg and Zn; X is at least one kind selected from among F, Cl, Br and I; and R is at least one kind selected from among Eu, Mn and combination of Eu and Mn).

Alkaline earth metal aluminate fluorescent materials include SrAl₂O₄:R, Sr₄Al₁₄O₂₅:R, CaAl₂O₄:R, BaMg₂Al₁₆O₂₇:R, BaMg₂Al₁₆O₁₂:R and BaMgAl₁₀O₁₇:R (R is at least one kind selected from among Eu, Mn and combination of Eu and Mn).

Rare earth oxysulfide fluorescent materials include La₂O₂S:Eu, Y₂O₂S:Eu and Gd₂O₂S:Eu.

Rare earth aluminate fluorescent materials activated mainly by lanthanoid element such as Ce include YAG fluorescent materials having garnet structure represented by formulae Y₃Al₅O₁₂:Ce, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce, Y₃(Al_(0.8)Ga_(0.2))₅O₁₂:Ce, (Y,Gd)₃(Al,Ga)₅O₁₂:Ce, Tb₃Al₅O₁₂:Ce, Y₃Al₅O₁₂:Ce, Pr.

Other fluorescent materials include ZnS:Ag, ZnS:Cu, ZnS:Mn, Zn₂GeO₄:Mn, MGa₂S₄:Eu (M is at least one kind selected from among Sr, Ca, Ba, Mg and Zn; X is at least one kind selected from among F, Cl, Br and I). MSi₇N₁₀:Eu, M_(1.8)Si₅O_(0.2)N₈:Eu and M_(0.9)Si₇O_(0.1)N₁₀:Eu (M is at least one kind selected from among Sr, Ca, Ba, Mg and Zn) may also be used.

The fluorescent materials described above may include, instead of, or in addition to Eu, at least one kind selected from among Tb, Cu, Ag, Au, Cr, Nd, Dy, Co, Ni, Ti, etc. Other than those described above, fluorescent materials having similar properties and effects may also be used.

For these fluorescent materials 10, such fluorescent materials that have emission spectra in yellow, red, green and blue regions and fluorescent materials that have emission spectra in intermediate colors of yellow, blue-green and orange regions may also be used. Light emitting devices that emit light of various colors can be made by combining such fluorescent materials as described above and oxynitride-based fluorescent material or nitride-based fluorescent material.

Fourth Embodiment

In this embodiment, the light emitting device use two or more kinds of direct-excitation fluorescent material (first fluorescent material) that are substantially directly excited by the light emitted from an excitation source having principal emission peak in a range from 250 nm to 420 nm and indirect-excitation fluorescent material (a second fluorescent material) that is excited by a part of light emitted by the two or more kinds of the direct-excitation fluorescent material. The two or more kinds of the direct-excitaion fluorescent material includes one or more kind of oxynitride-based fluorescent material or nitride-based fluorescent material having crystallinity. The indirect-excitation fluorescent material is preferably a YAG-based phosphor. Other points are similar as the Third Embodiment.

Specifically, as direct-excitation fluorescent material, (a) oxynitride-based fluorescent material or nitride-based fluorescent material, and

-   -   (b) at least one phosphor selected from the group consisting of         (M1_(1−a)Eu_(a))₁₀(PO₄)₆Q₂ (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least         one element selected from among F, Cl, Br and I, and a is a         number satisfying 0.0001≦a≦0.5),     -   (M1_(1−a)Eu_(a))₂B₅O₉Q (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, Q represents at least         one element selected from among F, Cl, Br and I, and a is a         number satisfying 0.0001≦a≦0.5),     -   M3_(1−a)Eu_(a)MgAl₁₀O₁₇ (M3 represents at least one element         selected from among the group consisting of Ca, Ba, Sr and Zn,         and a is a number satisfying 0.0001≦a≦0.5),     -   (M1_(1−a)Eu_(a))₄Al₁₄O₂₅ (M1 represents at least one element         selected from among Mg, Ca, Ba, Sr and Zn, and a is a number         satisfying 0.0001≦a≦0.5 and 0.0001≦b≦0.5),     -   M³ _(1−a)Eu_(a)Mg_(1−b)Mn_(b)Al₁₀O₁₇ (M3 represents at least one         element selected from among the group consisting of Ca, Ba, Sr         and Zn, and a is a number satisfying 0.0001≦a≦0.5 electrode 3 of         the light emitting element 10 is connected with an electrically         conductive wire 14 to the lead frame 13 b) and     -   M1_(1−a)Eu_(a)Al₂O₄ (M1 represents at least one element selected         from among Mg, Ca, Ba, Sr and Zn, and a is a number satisfying         0.0001≦a≦0.5) are used.

On the other hand, as the indirect-excitation fluorescent material, (c) (Re_(1−x)Sm_(x))₃(Al_(1−y)Ga_(y))₅O₁₂:Ce (Re represents at least one kind of element selected from among Y, Gd and La, x is a number satisfying 0≦x<1 and y is a number satisfying 0≦y≦1) is used.

This combination of fluorescent materials, combined with light emitting element has main emission peak in 250 to 420 nm, provide a white light emitting device with high luminous intensity and high color rendering.

Fifth Embodiment

In the light emitting device of the first and second embodiments, according to detail so far, the variation in the color of emitted light (color deviation) due to variation in the drive current of the light emitting element and the variation in the color of emitted light due to difference in the drive mode (particularly the difference between DC drive and pulse drive) can be suppressed to extremely low levels, by using a plurality of fluorescent materials of direct transition type.

Now more preferable embodiments will be described below that take into consideration the variation in color of emitted light due to causes other than variation in the drive current and difference in the drive mode.

In the light emitting device of the first to fourth embodiments, compositions of the plurality of fluorescent materials are preferably determined by taking into consideration the dependency of excitation efficiency on the excitation wavelength, so as to prevent color deviation due to variation in the wavelength.

In case the light emitting device, as in the first to fourth embodiment, is constituted from a plurality of fluorescent materials, if two fluorescent materials have different degrees of dependency of excitation efficiency on the excitation wavelength, blending ratio of light varies resulting in the variation of light color when the emission wavelength of the light emitting element varies.

However, color deviation due to variation in emission wavelength of the light emitting element can be prevented by setting the composition such that blending ratio of light is maintained always constant within the variable range of emission wavelengths of the light emitting element, so that excitation efficiencies of the plurality of fluorescent materials vary in the same way.

The mechanism of preventing color deviation will now be described below by taking an example in a specific composition of fluorescent material.

Peak emission wavelength of a semiconductor light emitting element shifts toward shorter wavelengths when the current supplied thereto increases as shown in FIG. 15. This is because increasing the current supply increases the current density and accordingly the band gap. Difference between the peak wavelength of the emission spectrum when the current density in the light emitting element is low and the peak wavelength of the emission spectrum when the current supply is increased is about 10 nm, for example, when the current is increased from 20 mA to 100 mA (FIG. 15).

On the other hand, while the peak wavelength of the emission spectrum of YAG fluorescent material having composition of Y₃(Al_(0.8)Ga_(0.2))₅O₁₂:Ce (FIG. 16) is about 448 nm, emission intensity upon excitation with light of wavelength 460 nm is 95% of the emission intensity upon excitation with light of wavelength 448 nm. Emission intensity of the YAG fluorescent material changes substantially linearly in a wavelength range from 448 nm to 460 nm.

On the other hand, while the peak wavelength of the emission spectrum of a nitride fluorescent material having composition of (Sr_(0.579)Ca_(0.291)Eu_(0.03))₂Si₅N₈ is about 450 nm, emission intensity upon excitation with light of wavelength 460 nm is 95% of the emission intensity upon excitation with light of wavelength 450 nm (FIG. 17). Emission intensity of this nitride fluorescent material also changes substantially linearly in a wavelength range from 448 nm to 460 nm.

In case a light emitting element that emits light with peak emission of 460 nm immediately after current has been supplied (for example, with a small current of around 20 mA) is selected, peak emission wavelength when the current supplied thereto is increased to 100 mA becomes about 450 nm. However, there is no difference in the proportion of excitation efficiency of the nitride fluorescent material and the YAG fluorescent material between the case of exciting with light of wavelength 460 nm and the case of exciting with light of wavelength 450 nm.

As a result, amount of change in the emission intensity becomes the same between the YAG fluorescent material and the nitride fluorescent material for a change in the emission wavelength of the light emitting element when the current supplied to the light emitting element is increased from 20 mA to 100 mA.

Therefore, even when the peak emission wavelength changes due to a change in the current supplied to the light emitting element, proportion of the emission intensity of the YAG fluorescent material and the emission intensity of the nitride fluorescent material can be maintained constant, thus preventing color deviation from occurring.

When the current supplied to the light emitting element is increased from 20 mA to 100 mA, for example, emission intensity of the light emitting element increases and the emission intensity of the YAG fluorescent material and the emission intensity of the nitride fluorescent material both increase, although proportion of the emission intensity between the YAG fluorescent material and the nitride fluorescent material is maintained constant. As a result, although emission intensity of the light emitting device as a whole increases, color deviation does not occur.

For example, Examples 15 and 16 to be described later are light emitting devices that are constituted by selecting fluorescent materials having luminescence center of direct transition type taking into consideration the dependency of excitation efficiency on the excitation wavelength. The examples 15 and 16 provides better light source with less color deviation and less variation in color rendering property for a change in the current density, compared to the light emitting device of Comparative Example 5 wherein the dependency of excitation efficiency on the excitation wavelength is not taken into consideration.

The above discussion on the cases of using two fluorescent materials holds true also for a case of using three or more fluorescent materials.

The light emitting device constituted as described above can provide illumination free of color deviation even when used as an adjustable illumination light source, with smaller difference in the color of emitted light between pulse drive and continuous emission.

Sixth Embodiment

In the first to fifth embodiments, color deviation due to temperature change can be prevented by determining the composition while taking the temperature dependency of the emission intensities of the fluorescent materials into consideration. In this embodiment, compositions of the fluorescent materials are determined so that changes in the emission intensity due to a change in the ambient temperature are substantially the same between of the fluorescent materials, in order to prevent color deviation from occurring when the temperature changes due to a change in the ambient temperature and the heat generated by the light emitting element. This is because, if the temperature dependency varies among the fluorescent materials, proportions of emission intensities between the fluorescent materials change with temperature, thus resulting in color deviation.

When the temperature rises, excitation efficiency of a fluorescent material generally decreases and the optical output power from the fluorescent material also decreases, of which decreasing rate is preferably smaller, as a matter of course.

In the first embodiment, the rate of the relative light emission output power decreasing when the ambient temperature changes by 1° C. is defined as the emission output power decreasing rate. Compositions of the fluorescent materials are determined so that the emission output power decreasing rates of two or more fluorescent materials are all 4.0×10⁻³ [a.u./° C.] or less, preferably 3.0×10⁻³ [a.u./° C.] or less, and more preferably 2.0×10⁻³ [au./° C.] or less. In terms of percentage, compositions of the fluorescent materials are determined so that the emission output power decreasing rates of two or more fluorescent materials are all 0.4 [%/° C.] or less, preferably 0.3 [%/° C.] or less, and more preferably 0.2 [%/° C.] or less. This makes it possible to further suppress the decrease of luminous flux [lm] of the entire light emitting device due to heat generation, in contrast to the prior art. Therefore, this embodiment has such a constitution as the emission output power decreasing rate is controlled within the range described above, and the emission output power decreasing rates of two or more fluorescent materials have substantially the same values. With this constitution, the fluorescent materials have substantially the same temperature characteristics of decreasing excitation efficiency with heating, so that the light emitting device can suppress the color deviation from occurring when the ambient temperature changes.

Comparison will be made between a device that employs excitation light in he near ultraviolet to visible region of short wavelength, for example, Example 1 to be described later and Comparative Example 6.

In Example 1, fluorescent materials that undergo relatively less decrease in luminance when the temperature rises, such as La₃Al₅O₁₂:Ce and Ca₂Si₅N₈:Eu. Comparative Example 6 is a fluorescent material having luminescence center of direct transition type, SrGa₂S₄:Eu or CaS:Eu having relatively less decrease in luminance when the temperature rises is used. Due to this difference, the light emitting device of Example 1 provides better light source with less color deviation and less variation in color rendering property, compared to the light emitting device of Comparative Example 6.

Seventh Embodiment

The light emitting device of the seventh embodiment is of surface mount type, of which components are similar to those of the first embodiment (FIG. 18). A light emitting element 101 may be constituted from a nitride semiconductor light emitting element that emits ultraviolet ray. The light emitting element 101 may also be constituted from a nitride semiconductor light emitting element that emits blue light. The following description will take the light emitting element 101 that emits ultraviolet ray as an example. The light emitting element 101 is a nitride semiconductor light emitting element that has light emitting layer made of InGaN semiconductor having peak emission wavelength of about 370 nm. More specifically, the LED has such a constitution of single quantum well structure as n-type GaN layer made of undoped nitride semiconductor, a GaN layer that makes an n-type contact layer having Si-doped n-type electrode, an n-type GaN layer made of undoped nitride semiconductor, an n-type AlGaN layer made of nitride semiconductor and an InGaN layer that makes a light emitting layer are formed on a sapphire substrate. Formed on the light emitting layer are a p-type cladding layer made of Mg-doped AlGaN and a p-type contact layer made of Mg-doped GaN. A buffer layer is formed on the sapphire substrate by growing GaN at a low temperature. The p-type semiconductor is annealed at a temperature of 400° C. or higher after forming the layer. The p-type and n-type contact layers are exposed by etching the nitride semiconductor on the same side of the sapphire substrate. A strip of n electrode is formed on the n-type contact layer that has been exposed, the light transmitting p electrode is formed from a thin metal film over substantially the entire surface of the p-type contact layer that remains without being cut off, and the pedestal electrode is formed parallel to the n electrode on the light transmitting p electrode by sputtering.

A package 105 of the light emitting device of the seventh embodiment is made of Kovar, and comprises a middle portion where a recess is formed and a flange-like base portion disposed around the middle portion. The base portion has lead electrodes 102 made of Kovar inserted therein while being insulated from the surrounding and hermetically sealed on both side of the recess. The package 105 and the lead electrode 102 are coated with Ni/Ag layer on the surface thereof.

The LED chip 101 is die-bonded by means of Ag-Sn alloy in the recess of the package 105. With this constitution, all components of the light emitting device can be made of inorganic materials, so that the light emitting device shows remarkably high reliability even when the LED chip 101 emits ultraviolet ray or short-wavelength light.

Electrodes of the LED chip 101 that has been die-bonded and the lead electrodes 102 are electrically connected by means of Ag wires 104. After thoroughly removing moisture from the recess of the package, a lid 106 made of Kovar having a glass window 107 is placed at the center of the package and sealed by seam-welding.

Formed on the glass window 107 is a color conversion layer 109 that contains nitride-based fluorescent material such as Ca₂Si₅N₈:Eu or (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce and YAG fluorescent material. The color conversion layer 109 is formed by preparing a slurry comprising 90% by weight of nitrocellulose and 10% by weight of y-alumina to which fluorescent material 108 made of nitride fluorescent material is mixed, applying the slurry to the back surface (the surface that oppose the recess) of the light transmitting window 107, and heating it at 220° C. for 30 minutes to harden.

In the surface mount type light emitting device of the seventh embodiment constituted as described above, the light emitting element and the fluorescent materials can be combined similarly to the case of the first embodiment, resulting in similar effect as those of the first embodiment.

In the light emitting device of the seventh embodiment, the fluorescent material 108 may be disposed at various positions relative to the light emitting element 101. For example, the fluorescent material 108 may be included in the molding material that covers the light emitting element 101. Alternatively, the light emitting element 101 and the fluorescent material 108 may be disposed at positions spaced from each other, or the fluorescent materiall 108 may also be placed directly on the light emitting element 101.

In the seventh embodiment, the fluorescent material 108 may be affixed by using various coating member (binder) such as organic resin or inorganic material such as glass. A coating member to be described in this embodiment may be applied to the first embodiment. The coating member 109 may serve as a binder that fastens the fluorescent material 108 onto the light emitting element 101 or the window 107. In case the coating member (binder) is to be made of an organic material, specific material is preferably a transparent resin that has high weatherability such as epoxy resin, acrylic resin and silicone. Silicone is particularly preferable because of high reliability and the capability to improve the diffusion of the fluorescent material 108.

When an inorganic material having thermal expansion coefficient similar to that of the window 107 is used for the coating member (binder) 109, it has a favorable effect of satisfactorily bonding the fluorescent material 108 to the window 107. Specifically, sedimentation process, sol-gel method, spraying or the like may be employed. For example, a slurry made by mixing the fluorescent material 108, Silanol (Si(Oet)₃OH) and ethanol may be used in such a way as the slurry is discharged from a nozzle and heated at 300° C. for 3 hours so as to turn Silanol into SiO₂ and cause the fluorescent material to adhere onto a desired position.

An inorganic binder may also be used as the coating member (binder) 109. The binder is the so-called low-melting point glass, which preferably consists of very small particles, does not substantially absorb light in the ultraviolet to visible region and is very stable in the coating member (binder) 109.

In case the fluorescent material of large particles is affixed to the coating member (binder) 109, it is preferable to use a binder consisting of ultra-fine powder, even if it has a high melting point, such as silica, alumina, pyrophosphate of alkaline earth metal of small particle size obtained by sedimentation process, or orthophosphate. These binders may be used individually or in mixture with each other.

Method of applying the binder will now be described. In order to achieve sufficient binding effect, the binder is preferably crushed in a vehicle in wet process and used in the form of slurry. The vehicle refers to a high-viscosity liquid prepared by dissolving a small amount of caking additive in an organic solvent or deionized water. An inorganic vehicle can be obtained, for example, by dissolving 1 wt % of nitrocellulose as the caking agent in butyl acetate used as the organic solvent. The fluorescent material 11, 108 are added to the binder slurry prepared as described above, so as to make the coating liquid. Slurry content in the coating liquid may be determined so that proportion of the caking additive included in the slurry to the content of fluorescent material in the coating liquid is in a range from about 1 to 3 wt %. In order to prevent significant decrease in the luminous flux, content of the binder is preferably smaller. The coating liquid is applied to the back surface of the window 107, and is dried by exposing it to warm or hot air. Last, the coat is baked at a temperature from 400 to 700° C. so as to evaporate the vehicle. Thus the fluorescent material layer is affixed by the binder at a desired place.

Eighth Embodiment

The eighth embodiment is a cap-type light emitting device constituted from components similar to those of the first embodiment (FIG. 19). For the light emitting element 10, for example, a light emitting element that has principal emission peak wavelength at 365 nm in the ultraviolet region is used. The light emitting device is made by covering the surface of the molding member 15 with the cap 16 made of light transmitting resin wherein the fluorescent material (not shown) is dispersed.

The cup for mounting the light emitting element 10 therein is provided on the mount lead 13 a, and the light emitting element 10 is die-bonded at substantially the center on the bottom of the cup. While the fluorescent material 11 is provided on top of the cup so as to cover the light emitting element 10, this may be omitted since direct influence of heat generated by the light emitting element 10 is not expected when the fluorescent material 11 is not provided on top of the cup.

The cap 16 distributes the fluorescent material uniformly in the light transmitting resin. The light transmitting resin that contains the fluorescent material is formed in such a shape that fits the shape of the molding member 15 of the light emitting device 1. Alternatively, the light transmitting resin that contains the fluorescent material may be put into a mold, then the light emitting device 1 may be squeezed into the mold. Material used to make the light transmitting resin of the cap 16 may be a transparent resin that has good temperature characteristics and high weatherability such as epoxy resin, urea resin and silicone resin, silica sol, glass or inorganic binder. Besides the materials described above, a thermosetting resin such as melanin resin or phenol resin may also be used. Thermoplastic resins such as polyethylene, polypropylene, polyvinyl chloride and polystyrene and thermoplastic rubbers such as styrene-butadiene copolymer and segmented polyurethane may also be used. Along with the fluorescent material 11, a diffusing agent, barium titanate, titanium oxide, aluminum oxide or the like may be included. An photostabilizer and/or colorant may also be included. For the fluorescent material used in the cap 16, Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce or (Sr,Ca)₂Si₅N₈:Eu may be used. For the fluorescent material 11 used in the cup of the mount lead 13 a, Ca₁₀(PO₄)₆Cl₂:Eu may be used. However, since the fluorescent material is used in the cap 16, such a constitution may also be employed as Ca₁₀(PO₄)₆Cl₂:Eu or the like is included in the cap 16 and the cup of the mount lead 13 a contains only the coating member 12.

In the light emitting device constituted as described above, light emitted by the light emitting element 10 excites Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce, (Sr,Ca)₂Si₅N₈:Eu or the like of the fluorescent material 11. (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce is excited by blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu. Thus white light is emitted through the cap 16 surface to the outside as a result of blending of light emitted by the fluorescent material 11.

EXAMPLES

Now examples of the fluorescent materials and the light emitting device according to the present invention will be described by way of examples, but the present invention is not limited by these examples.

Temperature characteristic is as relative luminance in percentage of luminance of light emission at 25° C. Particle size is a value measured by air permeation method called F.S.S.S.No. (Fischer Sub Sieve Sizer's No.).

In the examples described below, pulse drive was carried out by supplying the power in pulses of frequency 200 Hz, pulse width 50 μsec and duty ratio of 1%. Both pulse drive and DC drive were carried out at ambient temperature of 25° C.

Response characteristics of the fluorescent materials used in the Examples and Comparative Examples are shown in Table 24. TABLE 24 Light emitting Drive current Fluorescent element density material nm A/cm² Response time Ca₁₀(PO₄)₆Cl₂:Eu 400 DC drive 50.0 about 50 μsec or shorter Ca₂B₅O₉Cl:Eu 400 DC drive 50.0 about 50 μsec or shorter BaMgAl₁₀O₁₇:Eu 400 DC drive 50.0 about 50 μsec or shorter SrAl₂O₄:Eu 400 DC drive 50.0 about 50 μsec or shorter Lu₃Al₅O₁₂:Ce 400 DC drive 50.0 about 50 μsec or shorter (Y, Gd)₃Al₅O₁₂:Ce 400 DC drive 50.0 about 50 μsec or shorter Ca₂Si₅N₈:Eu 400 DC drive 50.0 about 50 μsec or shorter Sr₂Si₅N₈:Eu 400 DC drive 50.0 about 50 μsec or shorter (Sr, Ca)₂Si₅N₈:Eu 400 DC drive 50.0 about 50 μsec or shorter LiEuW₂O₈ 400 DC drive 50.0 about 50 μsec or shorter BaSi₂O₂N₂:Eu 400 DC drive 50.0 about 50 μsec or shorter (Sr, Ca)Si₂O₂N₂:Eu 400 DC drive 50.0 about 50 μsec or shorter SrGa₂S₄:Eu 400 DC drive 50.0 about 50 μsec or shorter CaS:Eu 400 DC drive 50.0 about 50 μsec or shorter BaMg₂Al₁₆O₂₇:Eu, Mn 400 DC drive 50.0 3 msec or higher Gd₂O₂S:Eu 400 DC drive 50.0 about 2 msec La₂O₂S:Eu 400 DC drive 50.0 about 1 msec ZnS:Ag 365 DC drive 50.0 0.3 msec or higher ZnS:Cu 365 DC drive 50.0 0.5 msec or higher ZnS:Mn 365 DC drive 50.0 0.5 msec or higher

The fluorescent materials were evaluated by measuring the response time from the time when the supply of drive current is started to the time when the emission of light from the fluorescent material has stabilized, using a light emitting element having principal emission wavelength of 400 nm or 365 nm. Drive current density was 50 A/cm². Among the fluorescent materials shown in Table 24, those having response time of 1 msec or longer shows color deviation when the drive current is changed and are unable to provide light emitting device that emits light stably as will be shown in conjunction with the Comparative Examples.

Examples 1 to 16, Comparative Examples 1 to 6

As examples 1 to 16, light emitting devices were made by using the fluorescent materials and the light emitting elements shown in Tables 25 to 27. TABLE 25 First Second Third Light fluorescent fluorescent fluorescent emitting material material material element nm Example 1 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅O₁₂:Ce Ca₂Si₅N₈:Eu 365 Example 2 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅ Sr₂Si₅ 365 Example 3 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅ (Sr, Ca) ₂Si₅ 365 Example 4 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅ Ca₂Si₅ 400 Example 5 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅ Sr₂Si₅ 400 Example 6 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅ (Sr, Ca) ₂Si₅ Example 7 Ca₁₀(PO₄)₆Cl₂:Eu SrAl₂O₄:Eu Ca₂Si₅N₈:Eu 365 Example 8 Ca₂B₅O₉Cl:Eu Y₃(Al, Ga)₅O₁₂:Ce (Sr, Ca)₂Si₅N₈:Eu 365 Example 9 Ca₂B₅O₉Cl:Eu Lu₃Al₅O₁₂:Ce Ca₂Si₅N₈:Eu 365 Example 10 BaMgAl₁₀O₁₇:Eu (Sr, Ca)Si₂O₂N₂:Eu Sr₂Si₅N₈:Eu 365

TABLE 26 First Second Second Third Light fluorescent fluorescent fluorescent fluorescent emitting material material (1) material (2) material element nm Example 11 Ca₁₀(PO₄)₆Cl₂:Eu BaSi₂O₂N₂:Eu (Y,Gd)₃Al₅O₁₂:Ce (Sr,Ca)₂Si₅N₈:Eu 365 nm Example 12 Ca₁₀(PO₄)₆Cl₂:Eu Sr₄Al₁₄O₂₅:Eu Lu₃Al₅O₁₂:Ce (Sr,Ca)₂Si₅N₈:Eu 400 nm Example 13 Ca₁₀(PO₄)₆Cl₂:Eu BaSi₂O₂N₂:Eu (Sr,Ca)Si₂O₂N₂:Eu (Sr,Ca)₂Si₅N₈:Eu 365 nm Example 14 Ca₁₀(PO₄)₆Cl₂:Eu BaSi₂O₂N₂:Eu (Sr,Ca)Si₂O₂N₂:Eu (Sr,Ca)₂Si₅N₈:Eu 400 nm

The light emitting devices of Examples 11 to 14 were made by using two kinds of fluorescent materials (denoted as the second fluorescent material (1) and (2) in Table 3) for the second fluorescent material. TABLE 27 First Second Third Light fluorescent fluorescent fluorescent emitting material material material element Example — Y₃(Al, Ga)₅O₁₂:Ce Ca₂Si₅N₈:Eu 460 nm 15 Example BaSi₂O₂N₂: Y₃(Al, Ga)₅O₁₂:Ce (Sr, Ca)₂Si₅N₈: 460 nm 16 Eu Eu

The light emitting devices shown in Table 28 were made as the Comparative Examples. TABLE 28 First Second Third Light fluorescent fluorescent fluorescent emitting material material material element Comparative Ca₁₀(PO₄)₆Cl₂:Eu BaMg₂Al₁₆O₂₇:Eu, Mn Ca₂Si₅N₈:Eu 365 nm Example 1 Comparative Ca₁₀(PO₄)₆Cl₂:Eu BaMg₂Al₁₆O₂₇:Eu, Mn Gd₂O₂S:Eu 365 nm Example 2 Comparative Ca₁₀(PO₄)₆Cl₂:Eu SrAl₂O₄:Eu Gd₂O₂S:Eu 365 nm Example 3 Comparative (Sr, Ca, Ba)₅(PO₄) ₃Cl:Eu BaMg₂Al₁₆O₂₇:Eu, Mn La₂O₂S:Eu 400 nm Example 4 Comparative — (Y, Gd) ₃Al₅O₁₂:Ce — 460 nm Example 5 Comparative Ca(PO₄)₆Cl₂:Eu SrGa₂S₄:Eu CaS:Eu 400 nm Example 6

Results of evaluating Examples 1 to 16 and Comparative Examples 1 to 6 for the drive current density, chromaticity coordinate values and color rendering property are shown in Tables 6 and 7. TABLE 29 Drive current Chromaticity Color rendering density A/cm² coordinate values x/y property Ra Example DC drive 2.0 0.348/0.349 84.2 1 DC drive 50.0 0.348/0.349 84.3 Example DC drive 2.0  0.33/0.331 85.9 2 DC drive 50.0 0.33/0.33 86.1 Example DC drive 2.0 0.329/0.34  87.1 3 DC drive 50.0 0.329/0.34  87.2 Example DC drive 2.0 0.334/0.325 84.8 4 DC drive 50.0 0.334/0.324 84.9 Pulse drive 2.0 0.333/0.325 85.1 Pulse drive 50.0 0.336/0.327 84.6 Example DC drive 2.0 0.337/0.321 85.6 5 DC drive 50.0 0.337/0.32  85.5 Pulse drive 2.0 0.337/0.321 85.9 Pulse drive 50.0 0.339/0.322 85.1 Example DC drive 2.0 0.338/0.336 88.1 6 DC drive 50.0 0.338/0.336 88 Pulse drive 2.0 0.338/0.337 88.5 Pulse drive 50.0  0.34/0.338 87.6 Example DC drive 2.0 0.333/0.323 86.5 7 DC drive 50.0 0.328/0.315 85.1 Example DC drive 2.0 0.348/0.337 90.1 8 DC drive 50.0 0.349/0.337 90.1 Example DC drive 2.0 0.346/0.358 84.5 9 DC drive 50.0 0.345/0.357 84.8 Example DC drive 2.0 0.305/0.318 88.1 10 DC drive 50.0 0.306/0.316 87.1 Example DC drive 2.0 0.324/0.358 85.2 11 DC drive 50.0 0.323/0.356 85.4 Example DC drive 2.0 0.349/0.359 94.4 12 DC drive 50.0 0.349/0.356 94 Example DC drive 2.0 0.348/0.364 85.3 13 DC drive 50.0 0.349/0.363 85.2 Example DC drive 2.0 0.330/0.358 82 14 DC drive 50.0 0.333/0.358 83.6 Example DC drive 2.0 0.335/0.345 87.3 15 DC drive 50.0 0.333/0.343 89 Example DC drive 2.0 0.334/0.340 92.7 16 DC drive 50.0 0.331/0.337 93.2

TABLE 30 Chromaticity Color Drive current coordinate rendering density values property A/cm2 x/y Ra Comparative DC drive 2.0 0.326/0.326 82.1 Example 1 DC drive 50.0 0.326/0.25  57.1 Pulse drive 2.0 0.319/0.356 88.6 Pulse drive 50.0 0.316/0.335 85 Comparative DC drive 2.0 0.343/0.333 40.5 Example 2 DC drive 50.0 0.226/0.227 u.a. Pulse drive 2.0 0.402/0.349 35.3 Pulse drive 50.0 0.349/0.341 42.5 Comparative DC drive 2.0 0.333/0.339 77.4 Example 3 DC drive 50.0 0.245/0.303 u.a. Pulse drive 2.0 0.378/0.339 61.2 Pulse drive 50.0 0.321/0.321 71.7 Comparative DC drive 2.0 0.285/0.285 43.1 Example 4 DC drive 50.0 0.262/0.198 28.1 Comparative DC drive 2.0 0.320/0.330 78.2 Example 5 DC drive 50.0 0.311/0.311 81.1 Comparative DC drive 2.0 0.306/0.333 78.5 Example 6 DC drive 50.0 0.296/0.333 88.5

Comparison of Examples 1 to 16 and the Comparative Examples show that, in the light emitting devices of Examples 11 to 16 wherein only the fluorescent material of direct transition types were used, difference between DC drive and pulse drive produced extremely small changes in the color tone and color rendering property and extremely small changes in the color tone and color rendering property due to the change in the drive current density, while light emitting devices of the Comparative Examples that contains fluorescent material of indirect transition type showed significant changes in the color tone and color rendering property.

FIG. 20 shows the emission spectra of the light emitting devices of Examples 1 to 3, and FIG. 21 shows the emission spectra of the light emitting devices of Examples 11 to 13. In FIG. 20, Examples 1 to 3 are denoted with reference numerals 61 to 63, respectively. In FIG. 21, Examples 11 to 13 are denoted with reference numerals 64 to 66, respectively.

Examples 17 to 28, Comparative Examples 7 to 11

As examples 17 to 28, light emitting devices were made by using the fluorescent materials and the light emitting elements shown in Table 32. These light emitting devices were evaluated for the emission color characteristics when operated under the driving conditions and drive current density shown Table 32.

The results are shown in Table 32.

For the comparison with Examples 17 to 28, light emitting devices of Comparative Examples 7 to 11 were made (with the fluorescent materials and the light emitting elements shown in Tables 31), and evaluated. Results of evaluation are shown in Table 32 along with the results of the examples. TABLE 31 Second Second Third Third Light First fluorescent fluorescent fluorescent fluorescent fluorescent emitting material material (1) material (2) material (1) material (2) element (nm) Example 17 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅O₁₂:Ce (Sr,Ca)₂Si₅N₈:Eu — — 365 Example 18 Ca₁₀(PO₄)₆Cl₂:Eu Sr₄Al₁₄O₂₅:Eu Lu₃Al₅O₁₂:Ce (Sr.Ca)₂Si₅N₈:Eu — 400 Example 19 Ca₁₀(PO₄)₆Cl₂:Eu BaSi₂O₂N₂:Eu (Y,Gd)₃Al₅O₁₂:Ce (Sr.Ca)₂Si₅N₈:Eu — 460 Example 20 Ca₁₀(PO₄)₆Cl₂:Eu Lu₃Al₅O₁₂:Ce (Sr.Ca)₂Si₅N₈:Eu — — 400 Example 21 Ga₂B₅O₉Cl:Eu Y₃(Al,Ga)₅O₁₂:Ce (Sr.Ca)₂Si₅N₈:Eu — — 365 Example 22 Ca₁₀(PO₄)₆Cl₂:Eu Y₃(Al,Ga)₅O₁₂:Ce (Sr.Ca)₂Si₅N₈:Eu — — 400 Example 23 Ga₂B₅O₉Cl:Eu Lu₃Al₅O₁₂:Ce (Sr.Ca)₂Si₅N₈:Eu — — 400 Comparative — (Y,Gd)₃Al₅O₁₂:Ce — — — 460 Example 7 Comparative (Sr,Ca,Ba)₅(PO₄)₃Cl:Eu BaMg₂Al₁₆O₂₇:Eu,Mn La₂O₂S:Eu — — 400 Example 8 Example 24 BaSi₂O₂N₂:Eu Y₃(Al,Ga)₅O₁₂:Ce — (Sr.Ca)₂Si₅N₈:Eu — 450 Example 25 (Sr,Ca,Ba)₂SiO₄:Eu Lu₃Al₅O₁₂:Ce — (Sr.Ca)₂Si₅N₈:Eu — 450 Example 26 Sr₄Al₁₄O₂₅:Eu Lu₃Al₅O₁₂:Ce — (Sr.Ca)₂Si₅N₈:Eu — 450 Example 27 Sr₄Al₁₄O₂₅:Eu Y₃(Al,Ga)₅O₁₂:Ce — (Sr.Ca)₂Si₅N₈:Eu — 450 Example 28 Sr₄Al₁₄O₂₅:Eu Y₃(Al,Ga)₅O₁₂:Ce — (Y,Gd)₃Al₅O₁₂:Ce (Sr.Ca)₂Si₅N₈:Eu 450 Comparative — (Y,Gd)₃Al₅O₁₂:Ce — — — 460 Example 9 Comparative SrGa₂S₄:Eu — — CaS:Eu — 450 Example 10 Comparative SrGa₂S₄:Eu Sr₄Al₁₄O₂₅:Eu — CaS:Eu Sr₂Si₅N₈:Eu 450 Example 11

TABLE 32 Ambient temperature Ambient temperature Ambient temperature Drive 25° C. 75° C. 125° C. current Chromaticity Color Chromaticity Color Chromaticity Color density coordinates rendering coordinates rendering coordinates rendering 25° C. → 125° C. (A/cm²) x/y property Ra x/y property Ra x/y property Ra Δx/Δy Example 17 Pulse 0.312/0.323 86.0 0.313/0.325 86.7 0.317/0.326 88.2 +0.005/+0.003 drive 6.0 Example 18 Pulse 0.298/0.313 95.0 0.295/0.310 94.9 0.298/0.277 88.5  ±0.00/−0.036 drive 6.0 Example 19 Pulse 0.331/0.356 81.2 0.328/0.341 80.7 0.333/0.350 80.0 +0.002/−0.006 drive 6.0 Example 20 Pulse 0.338/0.333 90.7 0.336/0.330 88.3 0.331/0.328 87.0 −0.007/−0.005 drive 6.0 Example 21 Pulse 0.346/0.336 89.5 0.359/0.345 90.0 0.336/0.334 92.7  −0.01/−0.002 drive 6.0 Ambient temperature Ambient temperature Ambient temperature Drive 0° C. 70° C. 140° C. current Chromaticity Color Chromaticity Color Chromaticity Color density coordinates rendering coordinates rendering coordinates rendering 0° C. → 140° C. (A/cm²) x/y property Ra x/y property Ra x/y property Ra Δx/Δy Example 22 Pulse 0.300/0.288 80.0 0.305/0.290 83.1 0.308/0.290 85.6 +0.008/−0.002 drive 10.0 Example 23 Pulse 0.292/0.299 86.8 0.301/0.304 88.6 0.313/0.313 91.9 +0.021/+0.014 drive 10.0 Comparative Pulse 0.280/0.295 77.3 0.275/0.288 80.4 0.286/0.293 68.2 +0.006/−0.002 Example 7 drive 10.0 Comparative Pulse 0.289/0.326 68.0 0.361/0.450 56.3 0.419/0.351 34.1 +0.130/+0.025 Example 8 drive 10.0 Drive current Chromaticity Color rendering density (A/cm²) coordinates x/y property Ra Example 24 DC drive 20.0 0.346/0.366 93.8 Example 25 DC drive 20.0 0.340/0.330 95.2 Example 26 DC drive 20.0 0.359/0.349 97.0 Example 27 DC drive 20.0 0.346/0.363 90.7 Example 28 DC drive 20.0 0.342/0.297 90.5 Comparative Example 9 DC drive 20.0 0.346/0.354 78.9 Comparative Example 10 DC drive 20.0 0.340/0.348 65.8 Comparative Example 11 DC drive 20.0 0.330/0.330 78.8

As will be clear from Table 32, the light emitting devices of Examples 17 to 28 have better color rendering property than the light emitting devices of Comparative Examples 7 to 11. Even when the ambient temperature rises, the light emitting devices of Examples 17 to 28 maintain high color rendering property and show less color deviation due either to temperature change or to the change in the drive current density, thus combining high color rendering property, excellent temperature characteristic and stability against color deviation due change in the drive current density.

Now Examples 29 to 35 of the light emitting device according to the present invention will be described in detail below. FIG. 1 shows a bullet-shaped light emitting device of Examples 29 to 35 and Comparative Examples.

Example 29

The example 29 is the light emitting device according to the present invention. FIG. 22 shows the emission spectrum of the light emitting device of Example 29.

The light emitting device of Example 29 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 365 nm. The fluorescent material 11 uses Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce or (Sr,Ca)₂Si₅N₈:Eu. Among these, Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu are directly excited by ultraviolet ray emitted by the semiconductor light emitting element 10, except for (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce. (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce, on the other hand, in the ultraviolet region around 365 nm, emission efficiency is as low as less than 5% that of the peak excitation wavelength, and most of the incident ultraviolet ray is reflected.

Ultraviolet ray emitted by the semiconductor light emitting element 10 enters Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu of the fluorescent material 11 and excites it. Ca₁₀(PO₄)₆Cl₂:Eu emits blue light, BaSi₂O₂N₂:Eu emits green light and (Sr,Ca)₂Si₅N₈:Eu emits red light. Blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu excites (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce to emit yellow-green light. BaSi₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu are excited not only by the ultraviolet ray emitted by the semiconductor light emitting element 10 but also by part of the blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu. With this constitution, light emitted by four kinds of fluorescent material 11 is blended to produce white light. Ultraviolet ray emitted by the semiconductor light emitting element 10 is invisible to the eye and does not affect the color of emitted light. Even when the emission wavelength of the semiconductor light emitting element 10 varies due to a change in the drive current density, it is invisible to the eye and does not affect the color of emitted light. The light emitting device of Example 29 has high color rendering property, and is therefore capable of providing a light emitting device particularly high special color rendering index (R9) that indicates the red component and emitting light with high color rendering property.

Table 33 shows the light emission characteristics of the light emitting device of Example 29. TABLE 33 Color tone Color temperature General color x y Tcp (K) rendering index Ra 0.324 0.360 5850 85.4 Color rendering property R1 R2 R3 R4 R5 R6 R7 R8 93.6 92.4 78.5 79.7 93.1 90.8 80.4 74.6 Color rendering property R9 R10 R11 R12 R13 R14 R15 50.4 80.2 84.5 84.2 95.3 87.1 84.2

A light emitting device that emits light of desired color tone can be provided by changing the proportions of the four kinds of fluorescent materials 11.

Example 30

The example 30 is the light emitting device according to the present invention. FIG. 23 shows the emission spectrum of the light emitting device of Example 30.

The light emitting device of Example 30 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 400 nm. The fluorescent material 11 uses Ca₁₀(PO₄)₆Cl₂:Eu, Sr₄Al₁₄O₂₅:Eu, Lu₃Al₅O₁₂:Ce and (Sr,Ca)₂Si₅N₈:Eu. Among these, Ca₁₀(PO₄)₆Cl₂:Eu, Sr₄Al₁₄O₂₅:Eu and (Sr,Ca)₂Si₅N₈:Eu are directly excited by ultraviolet ray emitted by the semiconductor light emitting element 10, except for Lu₃Al₅O₁₂: Ce.

Ultraviolet ray emitted by the semiconductor light emitting element 10 enters Ca₁₀(PO₄)₆Cl₂:Eu, Sr₄Al₁₄O₂₅:Eu and (Sr,Ca)₂Si₅N₈:Eu of the fluorescent material 11 and excites it. Ca₁₀(PO₄)₆Cl₂:Eu emits blue light, Sr₄Al₁₄O₂₅:Eu emits blue-green light and (Sr,Ca)₂Si₅N₈:Eu emits red light. Blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu excites Lu₃Al₅O₁₂:Ce to emit yellow-green light. (Sr,Ca)₂Si₅N₈:Eu is excited not only by the ultraviolet ray emitted by the semiconductor light emitting element 10 but also by part of the blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu. With this constitution, light emitted by four kinds of fluorescent material 11 is blended to produce white light. The light emitting device of Example 30 has high color rendering property, and is therefore capable of providing a light emitting device particularly high special color rendering index (R9) that indicates the red component and emitting light with high color rendering property.

Table 34 shows the light emission characteristics of the light emitting device of Example 30. TABLE 34 Color tone Color temperature General color x y Tcp (K) rendering index Ra 0.351 0.357 4785 94.0 Color rendering property R1 R2 R3 R4 R5 R6 R7 R8 98.7 96.0 94.2 91.8 96.3 94.6 90.7 89.9 Color rendering property R9 R10 R11 R12 R13 R14 R15 84.1 93.1 94.0 85.2 97.4 97.5 95.6

A light emitting device that emits light of desired color tone can be provided by changing the proportions of the four kinds of fluorescent materials 11.

Example 31

The example 31 is the light emitting device according to the present invention. FIG. 24 shows the emission spectrum of the light emitting device of Example 31.

The light emitting device of Example 31 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 400 nm. The fluorescent material 11 uses Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce and (Sr,Ca)₂Si₅N₈:Eu. Among these fluorescent materials, Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu are directly excited by light from ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10, except for (Y_(0.8)Gd_(0.2)) Al₅O₁₂: Ce. (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce, in contrast, hardly emits light near 400 nm and reflects most of incident light.

The light from ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 enters Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu of the fluorescent material 11 which are then excited. Ca₁₀(PO₄)₆Cl₂:Eu emits blue light, BaSi₂O₂N₂:Eu emits green light and (Sr,Ca)₂Si₅N₈:Eu emits red light. Blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu excites (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce so as to emit yellow-green light. BaSi₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu are excited not only by the light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 but also by part of the blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu. With this constitution, light emitted by four kinds of fluorescent material 11 is blended to produce white light. The light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 is difficult to visually recognize and therefore does not affect the color of light emitted by the light emitting device. Even when the color tone of the excitation light emitted by the semiconductor light emitting element 10 varies due to a change in the drive current density, it is difficult to visually recognize and therefore does not affect the color of emitted light. The light emitting device of Example 31 has high color rendering property, and is therefore capable of providing a light emitting device particularly high special color rendering index (R9) that indicates the red component and emitting light with high color rendering property.

Table 35 shows the light emission characteristics of the light emitting device of Example 31. TABLE 35 Color tone Color temperature General color x y Tcp (K) rendering index Ra 0.342 0.365 5172 84.0 Color rendering property R1 R2 R3 R4 R5 R6 R7 R8 90.2 84.3 74.3 86.3 87.9 76.3 83.9 89.0 Color rendering property R9 R10 R11 R12 R13 R14 R15 92.1 57.4 85.0 65.4 87.0 84.7 93.7

A light emitting device that emits light of desired color tone can be provided by changing the proportions of the four kinds of fluorescent materials 11.

Example 32

The example 32 is the light emitting device according to the present invention. FIG. 25 shows the emission spectrum of the light emitting device of Example 32.

The light emitting device of Example 32 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 400 nm. The fluorescent material 11 uses Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu, (Sr,Ca)Si₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu. These fluorescent materials are all directly excited by the ultraviolet ray emitted by the semiconductor light emitting element 10.

The light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 enters Ca₁₀(PO₄)₆Cl₂:Eu, BaSi₂O₂N₂:Eu, (Sr,Ca)Si₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu of the fluorescent material 11 and excites them. Ca₁₀(PO₄)₆Cl₂:Eu emits blue light, BaSi₂O₂N₂:Eu emits green light, (Sr,Ca)₂Si₅N₈:Eu emits yellow-red light and (Sr,Ca)₂Si₅N₈:Eu emits red light. BaSi₂O₂N₂:Eu, Sr,Ca)Si₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu are excited not only by the light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 but also by part of the blue light emitted by Ca₁₀(PO₄)₆Cl₂:Eu. With this constitution, the visible light emitted by four kinds of fluorescent material 11 is blended to produce white light. Since all the four kinds of fluorescent material 11 are excited by the light emitted by the semiconductor light emitting element 10, high emission efficiency is obtained. The light emitting device of Example 32 has high color rendering property, and is capable of providing a light emitting device particularly high special color rendering index (R9) that indicates the red component and emitting light with high color rendering property.

Table 36 shows the light emission characteristics of the light emitting device of Example 32. TABLE 36 Color tone Color temperature General color x y Tcp (K) rendering index Ra 0.346 0.368 5009 84.3 Color rendering property R1 R2 R3 R4 R5 R6 R7 R8 97.9 87.8 74.8 81.9 94.1 82.0 78.7 77.3 Color rendering property R9 R10 R11 R12 R13 R14 R15 65.8 69.2 85.9 75.1 94.2 85.5 91.1

A light emitting device that emits light of desired color tone can be provided by changing the proportions of the four kinds of fluorescent materials 11.

Example 33

The example 33 is the light emitting device according to the present invention. FIG. 26 shows the emission spectrum of the light emitting device of Example 33.

The light emitting device of Example 33 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 460 nm. The fluorescent material 11 uses BaSi₂O₂N₂:Eu, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce and (Sr,Ca)₂Si₅N₈:Eu. These fluorescent materials are all directly excited by the blue light emitted by the semiconductor light emitting element 10.

The blue light emitted by the semiconductor light emitting element 10 enters BaSi₂O₂N₂:Eu, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce and (Sr,Ca)₂Si₅N₈:Eu and excites them. BaSi₂O₂N₂:Eu emits green light, (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce emits yellow-green light and (Sr,Ca)₂Si₅N₈:Eu emits red light. The light emitted by the semiconductor light emitting element 10 and light emitted by the three kinds of the fluorescent material 11 are blended to produce white light. Since all the three kinds of fluorescent material 11 are excited by the light emitted by the semiconductor light emitting element 10, high emission efficiency is obtained. The light emitting device of Example 33 has high color rendering property, and is capable of providing a light emitting device having particularly high special color rendering index (R9) that indicates the red component and emitting light with high color rendering property.

Table 37 shows the light emission characteristics of the light emitting device of Example 33. TABLE 37 Color tone Color temperature General color x y Tcp (K) rendering index Ra 0.334 0.340 5400 92.7 Color rendering property R1 R2 R3 R4 R5 R6 R7 R8 96.6 94.8 90.5 93.8 95.7 91.6 89.8 89.0 Color rendering property R9 R10 R11 R12 R13 R14 R15 83.0 88.7 96.4 81.0 96.8 94.4 93.4

A light emitting device that emits light of desired color tone can be provided by changing the proportions of the three kinds of fluorescent materials 11.

Example 34

The example 34 is the light emitting device according to the present invention.

The light emitting device of Example 34 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 400 nm. The fluorescent material 11 uses (Sr,Ca)Si₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu. These fluorescent materials are directly excited by the light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10.

The light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 enters (Sr,Ca)Si₂O₂N₂:Eu and (Sr,Ca)₂Si₅N₈:Eu and excites them. (Sr,Ca)Si₂O₂N₂:Eu emits yellow light, and (Sr,Ca)₂Si₅N₈:Eu emits red light. Light emitted by the two kinds of fluorescent material 11 is blended to produce light of desired color. The light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 is difficult to visually recognize and therefore does not significantly affect the color of light emitted by the light emitting device. Even when the color tone of the excitation light emitted by the semiconductor light emitting element 10 varies due to a change in the drive current density, it is difficult to visually recognize and therefore does not affect the color tone of light emitted by the light emitting device. The light emitting device of Example 34 has chromaticity values of (x, y)=(0.582, 0.426), which represents yellow light used in traffic signals. In the prior art, AlInGaP has been used for the LED that emits yellow light of traffic signal, but the LED based on AlInGaP suffers significant color deviation depending on the ambient temperature. The light emitting device of Example 34, in contrast, is not subject to color deviation due to the ambient temperature.

Example 35

The example 35 is the light emitting device according to the present invention.

The light emitting device of Example 35 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 365 nm. The fluorescent material 11 uses BaSi₂O₂N₂:Eu and Ca₂Si₅N8:Eu. These fluorescent materials are directly excited by the ultraviolet ray emitted by the semiconductor light emitting element 10.

The light in the ultraviolet to visible region of short wavelengths emitted by the semiconductor light emitting element 10 enters BaSi₂O₂N₂:Eu and Ca₂Si₅N₈:Eu of the fluorescent material 11 and excites them. BaSi₂O₂N₂:Eu emits green light and Ca₂Si₅N₈:Eu emits yellow-red light. Light emitted by the two kinds of fluorescent material 11 is blended to produce light of desired color. The light emitting device of Example 35 has chromaticity values of (x, y)=(0.405, 0.404). The light emitting device of Example 35 can be used for decorative display and other applications.

Comparative Example 12

A light emitting device of Comparative Example 12 will be described below. FIG. 27 shows the emission spectrum of the light emitting device of Comparative Example 12.

The light emitting device of Comparative Example 12 uses the semiconductor light emitting element 10 that emits light with principal emission peak wavelength around 365 nm. The fluorescent material 11 uses Ca₁₀(PO₄)₆Cl₂:Eu and (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce. Ca₁₀(PO₄)₆Cl₂:Eu is directly excited by the ultraviolet ray emitted by the semiconductor light emitting element 10. (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce, on the other hand, in the ultraviolet region around 365 nm, emission efficiency is as low as less than 5% that of the peak excitation wavelength, and most of the incident ultraviolet ray is reflected.

Ultraviolet ray emitted by the semiconductor light emitting element 10 enters Ca₁₀(PO₄)₆Cl₂:Eu of the fluorescent material 11 and excites it. Ca₁₀(PO₄)₆Cl₂:Eu emits blue light and (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce is excited by the blue light and emits yellow-green light. When the fluorescent material 11 is excited by ultraviolet ray of wavelength 365 nm, Ca₁₀(PO₄)₆Cl₂:Eu shows chromaticity values of (x, y)=(0.138, 0.059 and (Y_(0.8)Gd_(0.2))₃Al₅O₁₂:Ce that is excited by the light emitted by Ca₁₀(PO₄)₆Cl₂:Eu shows chromaticity values of (x, y)=(0.456, 0.527). With this constitution, the visible light emitted by the two kinds of fluorescent material 11 is blended to produce white light. This light emitting device can generate color tones that lie on the straight line connecting blue and yellow on the chromaticity diagram, unable to provide a multi-color light emitting device. The light emitting device of Comparative Example 12 has very low special color rendering index (R9) that indicates the red component and cannot provide a light emitting device having high color rendering property.

Table 38 shows the light emission characteristics of the light emitting device of Comparative Example 12. TABLE 38 Color tone Color temperature General color x y Tcp (K) rendering index Ra 0.352 0.357 4759 79.5 Color rendering property R1 R2 R3 R4 R5 R6 R7 R8 77.5 87.7 90.7 72.8 75.4 78.9 86.3 66.9 Color rendering property R9 R10 R11 R12 R13 R14 R15 10.6 64.4 65.6 48.3 80.4 94.6 91.1

The light emitting device of the present invention can be used for ordinary illumination such a fluorescent lamp, traffic signal, automobile lighting, backlight for liquid crystal, display, etc., and particularly as white and multi-color light emitting device employing semiconductor light emitting element. 

1. A light emitting device that emits light of various colors by blending lights emitted by two or more kinds of fluorescent material which are substantially directly excited by the light emitted by an excitation source having principal emission peak in a range from 250 nm to 500 nm, wherein each of said two or more kinds of fluorescent material are direct transition type:
 2. A light emitting device comprising a light emitting element that emits light with principal emission peak in near ultraviolet to blue region and fluorescent material, wherein said fluorescent material comprises two or more kinds of fluorescent material each have a luminescence center of direct transition type.
 3. The light emitting device according to claim 2, wherein said light emitting element emits light with principal emission peak in a range from near ultraviolet to short-wave-lengths region of visible light and said fluorescent material comprises three or more kinds of fluorescent material that emit light with peak emission wavelength in visible light region.
 4. The light emitting device according to claim 1, wherein said fluorescent material comprises two or more kinds selected from among the group consisting of alkaline earth metal halogen apatite fluorescent material activated with at least Eu, alkaline earth metal boric acid halide salt fluorescent material activated with at least Eu, alkaline earth metal aluminate fluorescent material activated with at least Eu, rare earth metal aluminate fluorescent material having garnet structure and activated with at least Ce, alkaline earth metal silicon oxynitride fluorescent material activated with at least Eu or Ce, alkaline earth metal silicate fluorescent material activated with at least Eu and alkaline earth metal silicon nitride fluorescent material activated with at least Eu.
 5. The light emitting device according to claim 3, wherein said fluorescent material comprises: a first fluorescent material that emits light with one or more peak emission wavelength in blue-purple to blue region; a second fluorescent material that emits light with one or more peak emission wavelength in blue-green to green-yellow region; and a third fluorescent material that emits light with one or more peak emission wavelength in yellow to red region.
 6. The light emitting device according to claim 5, wherein said first fluorescent material comprises at least one kind selected from among the group consisting of alkaline earth metal halogen apatite fluorescent material, alkaline earth metal boric acid halide salt fluorescent material and alkaline earth metal aluminate fluorescent material each activated with at least Eu.
 7. The light emitting device according to claim 5, wherein said second fluorescent material comprises: (a) rare earth aluminate fluorescent material having garnet structure activated with at least Ce and (b) at least one kind selected from among the group consisting of alkaline earth metal aluminate fluorescent material activated with at least Eu, alkaline earth metal silicon oxynitride fluorescent material activated with at least Eu or Ce, and alkaline earth silicate fluorescent material.
 8. The light emitting device according to claim 5, wherein said third fluorescent material comprises an alkaline earth metal silicon nitride fluorescent material activated with at least Eu.
 9. The light emitting device according to claim 1, wherein said light emitting element has principal emission peak wavelength in blue region and said fluorescent material includes YAG fluorescent material.
 10. A light emitting device that emits light of various colors by using two or more kinds of fluorescent material, which are substantially directly excited by the light emitted by an excitation source having principal emission peak in ultraviolet to visible region, so as to blend the light emitted by the two or more kinds of fluorescent material, wherein said two or more kinds of fluorescent material include at least one kind of oxynitride-based fluorescent material or nitride-based fluorescent material.
 11. The light emitting device according to claim 10, wherein said excitation light source has principal emission peak in a range from 250 nm to 420 nm.
 12. The light emitting device according to claim 10, wherein said excitation light source has principal emission peak in a range from 420 nm to 500 nm and said two or more kinds of fluorescent material include at least one kind of oxynitride-based fluorescent material.
 13. The light emitting device according to claim 10, wherein light emitting efficiency of said two or more kinds of fluorescent material when excited with the light from the excitation light source is 60% or more of the maximum light emission efficiency over the entire wavelength region.
 14. The light emitting device according to claim 10, wherein said two or more kinds of fluorescent material show maximum light emission efficiency in a range from 250 nm to 550 nm when excited by light.
 15. The light emitting device according to claim 10, wherein said oxynitride-based fluorescent material includes at least one kind of group II element selected from among the group consisting of Be, Mg, Ca, Sr, Ba and Zn, at least one kind of group IV element selected from among the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf and a rare earth element that is an activator R.
 16. The light emitting device according to claim 10, wherein said nitride-based fluorescent material comprises at least one kind of group II element selected from among the group consisting of Be, Mg, Ca, Sr, Ba and Zn, at least one kind of group IV element selected from among the group consisting of C, Si, Ge, Sn, Ti, Zr and Hf and a rare earth element that is an activator R.
 17. The light emitting device according to claim 10, which further comprises a second fluorescent material that is excited by part of light from said two or more kinds of fluorescent material so that light from said two or more kinds of fluorescent material and light from said second fluorescent material are blended so as to emit light of various colors.
 18. The light emitting device according to claim 10, wherein said second fluorescent material is aluminate fluorescent material that includes a rare earth element that is an activator R.
 19. The light emitting device according to claim 10, wherein said excitation light source is a light emitting element.
 20. The light emitting device according to claim 1, wherein said light emitting device has two or more emission peaks in the visible light region and at least two peak emission wavelengths of the two or more emission peaks are in complementary colors to each other.
 21. The light emitting device according to claim 1, wherein said light emitting element emits light of substantially constant color when current density supplied thereto varies.
 22. The light emitting device according to claim 1, wherein said light emitting element emits white light.
 23. The light emitting device according to claim 1, wherein said light emitting device has a general color rendering index of 80 or higher. 